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https://dx.doi.org/10.48550/ar...
Article . 2004
License: arXiv Non-Exclusive Distribution
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Viscosity of Suspensions of Hard and Soft Spheres

Authors: Phillies, George D. J.;

Viscosity of Suspensions of Hard and Soft Spheres

Abstract

From a reanalysis of the published literature, the low-shear viscosity of suspensions of hard spheres is shown to have a dynamic crossover in its concentration dependence, from a stretched exponential at lower concentrations to a power law at elevated concentrations. The crossover is sharp, with no transition region in which neither form applies, and occurs at a volume fraction (ca. 0.41) and relative viscosity (ca. 11) well below the sphere volume fraction and relative viscosity (0.494, 49, respectively) of the lower phase boundary of the hard sphere melting transition. For soft spheres -- taking many-arm star polymers as a model -- with increasing sphere hardness $��(��)$ shows a crossover from random-coil polymer behavior toward the behavior shown by true hard spheres.

8 pages, 10 figures Full Paper corresponding to the Note J Colloid Interface Science 248, 528=529 (2002)

Related Organizations
Keywords

Soft Condensed Matter (cond-mat.soft), FOS: Physical sciences, Condensed Matter - Soft Condensed Matter

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green