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LaCrO_3の熱膨張性と導電性に及ぼすTi置換の影響 ; Influence of Ti Substitution on the Thermal Expansion and Electrical Conductive Properties of LaCrO3

LaCrO_3の熱膨張性と導電性に及ぼすTi置換の影響 ; Influence of Ti Substitution on the Thermal Expansion and Electrical Conductive Properties of LaCrO3

Abstract

Linear thermal expansion and electrical conductivity of titanium substituted LaCrO_3 have been studied as ceramic interconnect materials in high-temperature solid oxide fuel cells. The transition temperature from orthorhombic to rhombohedral symmetry has a tendency to increase with decreasing Ti content in the perovskites. At Ti content ≧0.2, the phase transition was not observed in the temperature range from room temperature to 1273 K. Average linear thermal expansion coefficient of the Ti substituted perovskites increased with increasing Ti content and approaches that of 8 mol%Y_2O_3 stabilized ZrO_2 electrolyte. Electrical conductivity of the lanthanum chromites decreased with increasing Ti content.

Country
Japan
Keywords

LaCrO_3, Solid oxide Fuel cell, Electrical conductivity, Activation energy, Ti, Thermal expansion, Interconnector

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Related to Research communities
Energy Research