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On the theory of anodic levelling: behaviour of macroprofiles

descriptionPublicationkeyboard_double_arrow_right Article , Journal 01 Oct 1987Publisher:Elsevier BVJournal:Electrochimica Acta, volume 32, pages 1,435-1,441 (issn: 0013-4686,

Authors: C. Clerc; D. Landolt;

doi: 10.1016/0013-4686(87)85082-x

On the theory of anodic levelling: behaviour of macroprofiles

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Abstract

Abstract The rate of anodic levelling of macroprofiles under mass-transport control is studied analytically and by the finite element method (FEM) using the Nernst diffusion-layer approach. It is found that the rate of anodic levelling of macroprofiles is always slower than that of microprofiles and depends on the geometrical parameters e 0 , δ, λ representing, respectively, the profile height, the diffusion-layer thickness and the profile wavelength. On sinusoidal profiles when e 0 /δ → ∞, the rate of levelling tends towards zero.

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École Polytechnique Fédérale de Lausanne EPFL
Switzerland

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