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Article . 2012 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Production of hydrocarbons from fatty acids and animal fat in the presence of water and sodium carbonate: Reactor performance and fuel properties

Authors: Elmar Schlich; Mohammad M. Hossain; Bernd Weber; Andreas Frank; Diedrich Steffens; Gerhard Schilling; Ernst A. Stadlbauer; +1 Authors

Production of hydrocarbons from fatty acids and animal fat in the presence of water and sodium carbonate: Reactor performance and fuel properties

Abstract

Abstract The thermal degradation of free fatty acids and animal fat in a moving bed of sodium carbonate and 5 wt% of water were carried out at 430 ± 20 °C at a pilot scale plant. During start-up the loading rates for a 60:40 mixture of oleic and stearic acids were 10 kg/h resulting in a 69 ± 5% of bio-crude. The acidity index was remarkably low within a range of 0.64–0.80 mg KOH/g during 3 weeks of operation. The loading rates for animal fat were increased from 10 to 40 kg/h corresponding to a weight hourly space velocity of 0.03–0.1 h−1 over a period of 6 months. Heat transfer into the reactor was the limiting criterion. The main product with a yield of 65 ± 5% was bio-crude showing an acidity index of 0.5–1.8 mg KOH/g. The mean value for kinematic viscosity at 40 °C was 1.78 mm2/s. The net calorific value of bio-crude was 41.6 MJ/kg. Coke deposits on sodium carbonate were determined to be 5 ± 1%. The gaseous products ranged from 25 wt% to 30 wt%. The presence of CO2, H2, CH4, C2H6, C2H4 and C3 to C5 hydrocarbons as major components was established by gas chromatography. The gases were directly fed into an on-site gas line and used for heating purposes. The distillation curve of bio-crude from animal fat showed hydrocarbon based bio-fuels in the boiling ranges of gasoline and diesel. Upon rectification 66% of bio-diesel and 21% of bio-gasoline were obtained. This corresponds to a total yield of 43% bio-diesel and 14% bio-gasoline from animal fat. The bio-diesel had favorable low-temperature properties (cold filter plugging point = −18 °C) with oxidation stability between that of mineral oil based diesel and fatty acid methyl ester fuels. The gasoline fraction lacked low-boiling hydrocarbons as indicated by a vapor pressure of 26 kPa instead of 60-90 kPa (DIN EN 228). Thus, water-cooled condensers need to be improved for a full-scale plant. The results are discussed in terms of German specifications for standard fuels.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
21
Top 10%
Average
Average