The applicability of using 2-furfural (2-FAL) and methanol as aging markers for synthetic ester impregnated paper insulation was investigated through laboratory aging experiments at temperatures of 80, 100 and 120 °C. Methanol in the synthetic ester increased linearly with paper aging until degree of polymerisation (DP) reached 400. During this period concentration of methanol in oil was higher than that of 2-FAL, which proved the concept of using methanol to indicate early paper aging in the synthetic ester. However, the rate of methanol increase against the reduction of DP in the synthetic ester was about three times higher than that seen in mineral oil. This is due to a difference in the partitioning of the marker between oil and paper. Since the synthetic ester is more polar than the mineral oil, it attracted more methanol molecules from the paper, resulting in a higher concentration of methanol in oil for the same reduction of DP. In addition, a reduction in methanol was observed at the later stage of paper aging at 120 °C. This could be due to either a change in the partitioning between oil and paper, or an esterification reaction which consumes methanol in the system.