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Simulation and design of a three-stage metal hydride hydrogen compressor based on experimental thermodynamic data

Authors: Galvis E., A.R.; Leardini, Fabrice; Ares Fernández, José Ramón; Cuevas, F.; Fernández Ríos, José Fco.;

Simulation and design of a three-stage metal hydride hydrogen compressor based on experimental thermodynamic data

Abstract

Los investigadores de la UAM pertenecen al MIRE-Group A semi-empirical method was developed to design a three stage Metal Hydride Hydrogen Compressor (MHHC) through the determination of thermodynamic properties of several hydrides. As a first step, three AB2-type alloys that satisfy operation conditions were selected from published thermodynamic data entailing over 200 single plateau hydrides. These alloys were synthetized by arc melting and characterized by X-Ray Powder Diffraction (XRPD), Scanning Electron Microscopy (SEM) and Energy Dispersion X-ray spectroscopy (EDX). Absorption and desorption Pressure-composition-Isotherms (P-c-I) were determined between 23 and 80 C to characterize their thermodynamic properties. Subsequently, an algorithm that uses these experimental data and a real equation of state for gaseous H2 was implemented to simulate the volume, alloy mass, pressure and temperature of operation for each compressor stage, while optimizing the compression ratio and total number of compressed H2 moles. Optimal desorption temperatures for the three stages were identified within the range of 110e132 C. A system compression ratio (CR) of 92 was achieved. The number of H2 moles compressed, the alloy mass and volume of each stage depend linearly on the volume of the external tank in which the hydrogen is delivered

Countries
France, Spain
Keywords

[CHIM.MATE] Chemical Sciences/Material chemistry, Física, [CHIM.MATE]Chemical Sciences/Material chemistry, Hydride compressor, AB2 intermetallic hydrides, Hydride Compressor, Thermodynamics, Semi-Empirical Modeling, Semi-empirical modeling, AB2 Intermetallic Hydrides

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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    35
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
35
Top 10%
Top 10%
Top 10%
Green
bronze