• Energy Research
• Embargo close
• NL close
• GB close
• Aurora Universities Network close

Lake sediments provide a record of atmospheric Pb deposition and changes in Pb isotope composition. To our knowledge, such an approach has not previously been performed in The Netherlands or linked to national air monitoring data. Results are presented for Pb content and isotope composition of (137)Cs dated lake sediments from 2 Dutch urban lakes. Between 1942 and 2002A.D. anthropogenic atmospheric Pb deposition rates in the two lakes varied from 12±2 to 69±16μgcm(-2)year(-1). The rise and fall of leaded gasoline is clearly reflected in the reconstructed atmospheric Pb deposition rates. After the ban on leaded gasoline, late 1970s/early 1980s, atmospheric Pb deposition rates decreased rapidly in the two urban lakes and the relative contributions of other anthropogenic Pb sources - incinerator ash (industrial Pb) and coal/galena - increased sharply. Atmospheric Pb deposition rates inferred from the lake record a clear relationship with nearby measured annual mean air Pb concentrations. Based on this relationship it was estimated that air Pb concentrations between 1942 and 2002A.D. varied between 5 and 293ng/m(3).

Contemporary global politics is characterized by an increasing trend toward experimental forms of governance, with an emphasis on private governance. A plurality of private standards, codes of conduct and quality assurance schemes currently developed particularly, though not exclusively, by TNCs replace traditional intergovernmental regimes in addressing profound global environmental and socio-economic challenges ranging from forest deforestation, fisheries depletion, climate change, to labor and human rights concerns. While this trend has produced a heated debate in science and politics, surprisingly little attention has been paid on the effects of private governance on questions of distribution and justice. This is highly problematic. At the beginning of the twenty-first century global inequalities are greater than ever before, while rapid economic, social, political, and environmental changes threaten to further derail sustainable development and humanitarian objectives. If private governance creates or intensifies some of the pressing global inequalities (e.g., food security), and alleviates others (e.g., environmental degradation), from a business ethics perspective, we need to know which aspects need to be strengthened and where appropriate interventions are necessary and desirable. This paper proposes a framework to examine and classify the distributive outcomes of private governance institutions through the lenses of one particular approach to distributive justice, the capability approach. Empirically, it focuses on agrifood one area where the controversy regarding the distributive concerns of private governance are particularly pronounced. © 2013 Springer Science+Business Media Dordrecht.

Private rule-setting organizations increasingly design, implement, and monitor rules and standards that prescribe behavior in the global governance for sustainability. In this article we develop criteria against which we evaluate the output legitimacy of these organizations along two dimensions on the basis of their acceptance by different constituencies. The internal dimension refers to the acceptance of the organization's rules and standards by the relevant target group, and is assessed on the basis of standard uptake and compliance. The external dimension signifies the ability of the organization to have broader political and socio-economic impact that reaches beyond the target group, and is evaluated on the basis of structural, cognitive, and regulatory effects. With reference to the Marine Stewardship Council and Friend of the Sea, our analysis illustrates that while claims by private organizations to output legitimacy are not unfounded in sustainability governance, they can also be contested when considered in a global context. © 2014 Taylor & Francis.

The global forest carbon (C) stock is estimated at 662 Gt of which 45% is in soil organic matter. Thus, comprehensive understanding of the effects of forest management practices on forest soil C stock and greenhouse gas (GHG) fluxes is needed for the development of effective forest-based climate change mitigation strategies. To improve this understanding, we synthesized peer-reviewed literature on forest management practices that can mitigate climate change by increasing soil C stocks and reducing GHG emissions. We further identified soil processes that affect soil GHG balance and discussed how models represent forest management effects on soil in GHG inventories and scenario analyses to address forest climate change mitigation potential. Forest management effects depend strongly on the specific practice and land type. Intensive timber harvesting with removal of harvest residues/stumps results in a reduction in soil C stock, while high stocking density and enhanced productivity by fertilization or dominance of coniferous species increase soil C stock. Nitrogen fertilization increases the soil C stock and N2O emissions while decreasing the CH4 sink. Peatland hydrology management is a major driver of the GHG emissions of the peatland forests, with lower water level corresponding to higher CO2 emissions. Furthermore, the global warming potential of all GHG emissions (CO2, CH4 and N2O) together can be ten-fold higher after clear-cutting than in peatlands with standing trees. The climate change mitigation potential of forest soils, as estimated by modelling approaches, accounts for stand biomass driven effects and climate factors that affect the decomposition rate. A future challenge is to account for the effects of soil preparation and other management that affects soil processes by changing soil temperature, soil moisture, soil nutrient balance, microbial community structure and processes, hydrology and soil oxygen concentration in the models. We recommend that soil monitoring and modelling focus on linking processes of soil C stabilization with the functioning of soil microbiota. This review has been supported by the grant Holistic management practices, modelling and monitoring for European forest soils – HoliSoils (EU Horizon 2020 Grant Agreement No 101000289) and the Academy of Finland Fellow project (330136, B. Adamczyk). In addition to the HoliSoils consortium partners, Dr. Abramoff contributed on this study and her work was supported by the United States Department of Energy, Office of Science, Office of Biological and Environmental Research. Oak Ridge National Laboratory is managed by UT-Battelle, LLC, for the United States Department of Energy under contract DE-AC05-00OR22725.

Films of colloidal quantum dots (QDs) show great promise for application in optoelectronic devices. Great advances have been made in recent years in designing efficient QD solar cells and LEDs. A very important aspect in the design of devices based on QD films is the knowledge of their absolute energy levels. Unfortunately, reported energy levels vary markedly depending on the employed measurement technique and the environment of the sample. In this report, we determine absolute energy levels of QD films by electrochemical charge injection. The concomitant change in optical absorption of the film allows quantification of the number of charges in quantum-confined levels and thereby their energetic position. We show here that the size of voids in the QD films (i.e., the space between the quantum dots) determines the amount of charges that may be injected into the films. This effect is attributed to size exclusion of countercharges from the electrolyte solution. Further, the energy of the QD levels depends on subtle changes in the QD film and the supporting electrolyte: the size of the cation and the QD ligand length. These nontrivial effects can be explained by the proximity of the cation to the QD surface and a concomitant lowering of the electrochemical potential. Our findings help explain the wide range of reported values for QD energy levels and redefine the limit of applicability of electrochemical measurements on QD films. Finally, the finding that the energy of QD levels depends on ligand length and counterion size may be exploited in optimized designs of QD sensitized solar cells.

Photovoltachromic devices combine photovoltaic and electrochromic behaviours to enable adjustable transparency glazing, where the photovoltaic component supplies the power to drive the coloration.

Due to a scarcity of observations and its long memory of uncertain past climate, the Antarctic Ice Sheet remains a largely unknown factor in the prediction of global sea level change. As the history of the ice sheet plays a key role in its future evolution, in this study we model the Antarctic Ice Sheet from the Last Glacial Maximum (21 kyr ago) until the year 2100 with the ice-dynamical model ANICE. We force the model with different temperature, surface mass balance and sea-level records to investigate the importance of these different aspects for the evolution of the ice sheet. Additionally, we compare the model output from 21 kyr ago until the present with observations to assess model performance in simulating the total grounded ice volume and the evolution of different regions of the Antarctic Ice Sheet. Although there are some clear limitations of the model, we conclude that sea-level change has driven the deglaciation of the ice sheet, whereas future temperature change and the history of the ice sheet are the primary cause of changes in ice volume in the future. We estimate the change in grounded ice volume between its maximum (around 15 kyr ago) and the present-day to be between 8.4 and 12.5 m sea-level equivalent and the contribution of the Antarctic Ice Sheet to the global mean sea level in 2100, with respect to 2000, to be −22 to 63 mm.