• Energy Research
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Abstract In recent years, distributed energy systems (DESs) have been recognized as a promising option for sustainable development of future energy systems, and their application has increased rapidly with supportive policies and financial incentives. With growing concerns on global warming and depletion of fossil fuels, design optimization of DESs through economic assessments for short-run benefits only is not sufficient, while application of exergy principles can improve the efficiency in energy resource use for long-run sustainability of energy supply. The innovation of this paper is to investigate exergy in DES design to attain rational use of energy resources including renewables by considering energy qualities of supply and demand. By using low-temperature sources for low-quality thermal demand, the waste of high-quality energy can be reduced, and the overall exergy efficiency can be increased. The goal of the design optimization problem is to determine types, numbers and sizes of energy devices in DESs to reduce the total annual cost and increase the overall exergy efficiency. Based on a pre-established DES superstructure with multiple energy devices such as combined heat and power and PV, a multi-objective linear problem is formulated. In modeling of energy devices, the novelty is that the entire available size ranges and the variation of their efficiencies, capital and operation and maintenance costs with sizes are considered. The operation of energy devices is modeled based on previous work on DES operation optimization. By minimizing a weighted sum of the total annual cost and primary exergy input, the problem is solved by branch-and-cut. Numerical results show that the Pareto frontier provides good balancing solutions for planners based on economic and sustainability priorities. The total annual cost and primary exergy input of DESs with optimized configurations are reduced by 21–36% as compared with conventional energy supply systems, where grid power is used for the electricity demand, and gas-fired boilers and electric chillers fed by grid power for thermal demand. A sensitivity analysis is also carried out to analyze the influence of energy prices and energy demand variation on the optimized DES configurations.

# Genetic background and thermal regime influence adaptation to novel environment in the seed beetle, Callosobruchus maculatus [https://doi.org/10.5061/dryad.f1vhhmgz7](https://doi.org/10.5061/dryad.f1vhhmgz7) The data contained in these two data files (bodymass.csv and lifehistory.csv) contain data on body mass, development time, lifetime reproductive success, and age-specific reproduction of two populations of *Callosobruchus maculatus* that evolved under fluctuating or constant thermal regimes and were subsequently assayed under fluctuating or thermal regimes. ## Description of the data and file structure bodymass.csv contains information on: * Pop: Population (either USA or LEIC). * Treatment: Note that C = Constant Regime Constant Environment; I = Fluctuating Regime Fluctuating Environment; CIA = Constant Regime Fluctuating Environment; ICA = Fluctuating Regime Constant Environment. The transformation for this occurs in the code. * Rep: Replicate number. * Sex: Sex of individual (M or F). * Day: Always 22. * VCMass: Chamber mass (g). * VCBeet.Mass: Chamber w/ beetle (g). * Beet.Mass: Beetle mass (g). lifehistory.csv contains information on: * Pop: Population (either USA or LEIC). * Treat: Treatment; note that C = Constant Regime Constant Environment; I = Fluctuating Regime Fluctuating Environment; CIA = Constant Regime Fluctuating Environment; ICA = Fluctuating Regime Constant Environment. The transformation for this occurs in the code. * Rep: Replicate. * Pair.Date: Date paired. * VC: Chamber ID. * DayEgg: Egg day. * DateEgg: Date of first egg lay. * DateMeasure: Date of measurement for offspring. * DT: Development Time. * Males/Female/Total: Number of offspring that are Male/Female/Combined Total. * Comments: Comments made during data collection. ## Code/Software Code used to run the analysis and produce the graphs is located on GitHub via https://github.com/EIvimeyCook/Fluctuating\_Beetles or via Zenodo with the DOI, https://zenodo.org/doi/10.5281/zenodo.10118422. Climate change is associated with the increase in both mean and variability of thermal conditions. Therefore, the use of more realistic fluctuating thermal regimes is the most appropriate laboratory method for predicting population responses to thermal heterogeneity. However, the long- and short-term implications of evolving under such conditions are not well understood. Here, we examined differences in key life history traits among populations of seed beetles (Callosobruchus maculatus) that evolved under either constant control conditions or in an environment with fluctuating daily temperatures. Specifically, individuals from two distinct genetic backgrounds were kept for 19 generations at one of two temperatures, a constant temperature (T=29°C) or a fluctuating daily cycle (Tmean=33°C, Tmax=40°C, and Tmin=26°C), and were assayed either in their evolved environment or in the other environment. We found that beetles that evolved in fluctuating environments but were then switched to constant 29°C conditions had far greater lifetime reproductive success compared to beetles that were kept in their evolved environments. This increase in reproductive success suggests that beetles raised in fluctuating environments may have evolved greater thermal breadth than control condition beetles. In addition, the degree of sexual dimorphism in body size and development varied as a function of genetic background, evolved thermal environment, and current temperature conditions. These results highlight not only the value of incorporating diel fluctuations into climate research but also suggest that populations that experience variability in temperature may be better able to respond to both short- and long-term changes in environmental conditions.

Abstract Fostering the global development of low-carbon technology is crucial to mitigating greenhouse gas emissions. This paper analyzes the effect of energy-efficiency policies on lighting patenting between 1992 and 2007, using data for 19 OECD countries. We examine levels of energy-efficiency RDD however, the technology-push policy does not. These findings suggest that demand-pull policies can help to transform international markets for low-carbon technology innovation, and they underscore the importance of the often-overlooked international dimension of domestic energy-efficiency policies. To the extent that our findings are generalizable, our research suggests that governance processes that strengthen energy performance standards and steady investment in RD&D could spur energy innovation in industrialized nations across the world.

Abstract The European Energy Efficiency Building Directive 2002/91/CE, as well as other acts and funding programs, strongly promotes the adoption of passive strategies for buildings, in order to achieve indoor thermal comfort conditions above all in summer, so reducing or avoiding the use of air conditioning systems. In this paper, the energy performances achievable using an earth-to-air heat exchanger for an air-conditioned building have been evaluated for both winter and summer. By means of dynamic building energy performance simulation codes, the energy requirements of the systems have been analysed for different Italian climates, as a function of the main boundary conditions (such as the typology of soil, tube material, tube length and depth, velocity of the air crossing the tube, ventilation airflow rates, control modes). The earth-to-air heat exchanger has shown the highest efficiency for cold climates both in winter and summer. The possible coupling of this technology with other passive strategies has been also examined. Then, a technical-economic analysis has been carried out: this technology is economically acceptable (simple payback of 5–9 years) only in the cases of easy and cheap moving earth works; moreover, metallic tubes are not suitable. Finally, considering in summer a not fully air-conditioned building, only provided with diurnal ventilation coupled to an earth-to-air heat exchanger plus night-time ventilation, the possible indoor thermal comfort conditions have been evaluated.

Marine diatoms have recently gained much attention as they are expected to be a promising resource for sustainable production of bioactive compounds such as carotenoids and biofuels as a future clean energy solution. To develop photosynthetic cell factories, it is important to improve diatoms for value-added products. In this study, we utilized UVC radiation to induce mutations in the marine diatom Phaeodactylum tricornutum and screened strains with enhanced accumulation of neutral lipids and carotenoids. Adaptive laboratory evolution (ALE) was also used in parallel to develop altered phenotypic and biological functions in P. tricornutum and it was reported for the first time that ALE was successfully applied on diatoms for the enhancement of growth performance and productivity of value-added carotenoids to date. Liquid chromatography-mass spectrometry (LC-MS) was utilized to study the composition of major pigments in the wild type P. tricornutum, UV mutants and ALE strains. UVC radiated strains exhibited higher accumulation of fucoxanthin as well as neutral lipids compared to their wild type counterpart. In addition to UV mutagenesis, P. tricornutum strains developed by ALE also yielded enhanced biomass production and fucoxanthin accumulation under combined red and blue light. In short, both UV mutagenesis and ALE appeared as an effective approach to developing desired phenotypes in the marine diatoms via electromagnetic radiation-induced oxidative stress.

Abstract North Pacific ocean desert (NPOD) refers to the subtropical North Pacific Ocean of low chlorophyll-a (Chl-a) concentrations, as the largest ocean desert globally. Studies have suggested a development of NPOD over recent decades based on limited evidences from in-field measurements and yet elusive mechanism. In this study, we characterize intensity, area and position of the NPOD from year 1998 to 2018, and investigate its control by the coherent climate processes, based on an available, longest satellite observations of Chl-a concentration. Our results suggested that NPOD oligotrophication and expansion processes were correlated with warming upper oceans in most part of the NPOD, except for the SW NPOD area where the Chl-a variations were linked with regional change in sea surface heights. Moreover, based on our analysis, insignificant shift but only NW-SE variability of the NPOD mean position was likely controlled by the Pacific decadal oscillation processes.

Abstract Mountain lakes are often situated in protected natural areas, a feature that leads to their role as sentinels of global environmental change. Despite variations in latitude, mountain lakes share many features, including their location in catchments with steep topographic gradients, cold temperatures, high incident solar and ultraviolet radiation (UVR), and prolonged ice and snow cover. These characteristics, in turn, affect mountain lake ecosystem structure, diversity, and productivity. The lakes themselves are mostly small, and up until recently, have been characterized as oligotrophic. This paper provides a review and update of the growing body of research that shows that sediments in remote mountain lakes archive regional and global environmental changes, including those linked to climate change, altered biogeochemical cycles, and changes in dust composition and deposition, atmospheric fertilization, and biological manipulations. These archives provide an important record of global environmental change that pre-dates typical monitoring windows. Paleolimnological research at strategically selected lakes has increased our knowledge of interactions among multiple stressors and their synergistic effects on lake systems. Lakes from transects across steep climate (i.e., temperature and effective moisture) gradients in mountain regions show how environmental change alters lakes in close proximity, but at differing climate starting points. Such research in particular highlights the impacts of melting glaciers on mountain lakes. The addition of new proxies, including DNA-based techniques and advanced stable isotopic analyses, provides a gateway to addressing novel research questions about global environmental change. Recent advances in remote sensing and continuous, high-frequency, limnological measurements will improve spatial and temporal resolution and help to add records to spatial gaps including tropical and southern latitudes. Mountain lake records provide a unique opportunity for global scale assessments that provide knowledge necessary to protect the Earth system.

Polycyclic aromatic hydrocarbons (PAHs) are airborne pollutants that are deposited on soils. As climate change is already altering temperature and solar radiation, the global warming is suggested to impact the environmental fate of PAHs. This study was aimed at evaluating the effect of climate change on the PAH photodegradation in soils. Samples of Mediterranean soils were subjected to different temperature and light radiation conditions in a climate chamber. Two climate scenarios were considered according to IPCC projections: 1) a base (B) scenario, being temperature and light intensity 20°C and 9.6W/m(2), respectively, and 2) a climate change (CC) scenario, working at 24°C and 24W/m(2), respectively. As expected, low molecular weight PAHs were rapidly volatilized when increasing both temperature and light intensity. In contrast, medium and high molecular weight PAHs presented different photodegradation rates in soils with different texture, which was likely related to the amount of photocatalysts contained in both soils. In turn, the hydrogen isotopic composition of some of the PAHs under study was also investigated to verify any degradation process. Hydrogen isotopes confirmed that benzo(a)pyrene is degraded in both B and CC scenarios, not only under light but also in the darkness, revealing unknown degradation processes occurring when light is lacking. Potential generation pathways of PAH photodegradation by-products were also suggested, being a higher number of metabolites formed in the CC scenario. Consequently, in a more or less near future, although humans might be less exposed to PAHs, they could be exposed to new metabolites of these pollutants, which might be even more toxic.