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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Transport is an important source of air pollution and greenhouse gas emissions. Although the applications of information and communication technologies (ICTs) for transport, also known as intelligent transport systems, are seen as having great potential to help reduce emissions from road transport, their exact impact on CO2 emissions are uncertain for decision makers from government to industry. This uncertainty hinders the deployment of such applications. Therefore there is a need for a common evaluation approach to assess the CO2 impact of ICT measures in a systemic and realistic way. In this study, a methodology framework to evaluate the impact of ICT measures on CO2 emissions is explained. The methodology was developed within the European Union FP7 project Amitran. In particular, this study focuses on the outline and the framework architecture of the methodology as well as the required interfaces between the required models. The use of the methodology is demonstrated by applying it to a use case of dynamic traffic light systems. Finally, the efforts made to validate the methodology and make it accessible to users are explained.

Electric vehicles require sufficient public charging infrastructure. This in turn necessitates detailed information on charging demand. In this paper we present a four-step approach to estimating public charging demand of electric vehicles. Previous methods are limited in their ability to provide differentiated results and adapt to future developments. Therefore, we account for user groups (private, carsharing, commercial), technical developments (vehicles, infrastructure), infrastructure availability, and carsharing development (operational area, business models, autonomous vehicles). Our approach also considers the interactions between these factors and allows for scenario analysis yielding the quantity and spatial distribution of public charging demand. We demonstrate our approach for Berlin, Germany. We find that the majority of public charging demand results from carsharing. This demand is concentrated in the city center, even when carsharing is available citywide. Public charging demand for commercial users is relatively low and located outside the city center. For private users, public charging demand shifts to the city center with an increasing market penetration of electric vehicles and technological advancements (increased range, charging speed). Public demand from private users increases dramatically when private infrastructure is absent. Finally, public charging demand shifts to the city center when private users do not have private infrastructure.

In this reply to a comment on our paper , we first of all would like to thank the author of the comment for accentuating an important topic in the realm of the diffusion of electric vehicles (EVs), i.e., the impact of a transition from internal combustion engine vehicles (ICEVs) to EVs on carbon dioxide (CO2) emissions. We are confident that a discussion about the requirements and the consequences of such transition is an important one, which is why we welcome the comments on our paper.

This paper reports on a review of the European literature about the impacts of having an electrically-assisted bike available to use, together with results from a trial in the UK city of Brighton, where 80 employees were loaned an electrically-assisted bike for a 6–8 week period. In the Brighton trial, three-quarters of those who were loaned an e-bike used them at least once a week. Across the sample as a whole, average usage was in the order of 15–20 miles per week, and was accompanied by an overall reduction in car mileage of 20%. At the end of the trial, 38% participants expected to cycle more in the future, and at least 70%said that they would like to have an e-bike available for use in the future, and would cycle more if this was the case. This is consistent with the results of the European literature which shows that when e-bikes are made available, they get used; that a proportion of e-bike trips typically substitutes for car use; and that many people who take part in trials become interested in future e-bike use, or cycling more generally

Automation carries paradigm-shifting potential for urban transport and has critical sustainability dimensions for the future of our cities. This article examines the diverse environmental and energy-related dimensions of automated mobility at the city level by reviewing an emerging and increasingly diversified volume of literature for road, rail, water, and air passenger transport. The multimodal nature of this investigation provides the opportunity for a novel contribution that adds value to the literature in four distinctive ways. It reviews from a sustainability angle the state of the art underpinning the transition to a paradigm of automated mobility, identifies current knowledge gaps highlighting the scarcity of non-technical research outside the autonomous car's realm, articulates future directions for research and policy development, and proposes a conceptual model that contextualizes the automation-connectivity-electrification-sharing-multimodality nexus as the only way forward for vehicle automation to reach its pro-environmental and resource-saving potential.

Electrification is a potential solution for transport decarbonization and already widely available for individual and public transport. However, the availability of electrified commercial vehicles like waste collection vehicles is still limited, despite their significant contribution to urban emissions. Moreover, there is a lack of clarity whether electric waste collection vehicles can persist in real world conditions and which system design is required. Therefore, we introduce a multi-agent-based simulation methodology to investigate the technical feasibility and evaluate environmental and economic sustainability of an electrified urban waste collection. We present a synthetic model for waste collection demand on a per-link basis, using open available data. The tour planning is solved by an open-source algorithm as a capacitated vehicle routing problem (CVRP). This generates plausible tours which handle the demand. The generated tours are simulated with an open-source transport simulation (MATSim) for both the diesel and the electric waste collection vehicles. To compare the life cycle costs, we analyze the data using total cost of ownership (TCO). Environmental impacts are evaluated based on a Well-to-Wheel approach. We present a comparison of the two propulsion types for the exemplary use case of Berlin. And we are able to generate a suitable planning to handle Berlin’s waste collection demand using battery electric vehicles only. The TCO calculation reveals that the electrification raises the total operator cost by 16–30%, depending on the scenario and the battery size with conservative assumptions. Furthermore, the greenhouse gas emissions (GHG) can be reduced by 60–99%, depending on the carbon footprint of electric power generation.