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Abstract Three-dimensional (3D) metal halide perovskite solar cells (PSCs) have a power conversion efficiency that is now comparable with conventional silicon solar cells. For PSC applications to succeed in the market, long-term reliability under open-air conditions is essential. Recent experiments have shown that two-dimensional (2D) perovskites seem to exhibit good stability due to the presence of hydrophobic organic spacers, but 2D PSCs are incapable of generating and transporting a large amount of charge due to their extended optical bandgaps. Mixed dimensional perovskites with dimension lies between 2D and 3D recently became a promising candidate to sustain long-term stability and high performances concurrently to address this obstacle. The current research article presents the finding of simulation-based studies performed on novel device architecture consisting of ITO/Nb-Ti2O3/3D Perovskite/2D Perovskite/Spiro-OMeTAD/Au. Using optical simulation features of SCAPS, absorption of light is computed in the proposed device. The computational results show that the thickness of the 2D perovskite layer badly affects the solar cell parameters. A thin 2D perovskite behaves as a capped coating that avoids the deterioration of 3D perovskite in open-air environments. The effect of a multivalent defect in the 3D perovskite layer is mathematically modelled, and their impact on overall performance parameters are analyzed. The findings are compared to the same configuration results, except where the absorber layer’s multivalent defect has been substituted by a neutral defect of the same defect density of about (1011 cm−3). Results show that the multivalent defect leads to an underestimation of the efficiency by 4.2%.

Photoprotective mechanisms of cyanobacteria are characterized by several features associated with the structure of their water-soluble antenna complexes - the phycobilisomes (PBs). During energy transfer from PBs to chlorophyll of photosystem reaction centers, the "energy funnel" principle is realized, which regulates energy flux due to the specialized interaction of the PBs core with a quenching molecule capable of effectively dissipating electron excitation energy into heat. The role of the quencher is performed by ketocarotenoid within the photoactive orange carotenoid protein (OCP), which is also a sensor for light flux. At a high level of insolation, OCP is reversibly photoactivated, and this is accompanied by a significant change in its structure and spectral characteristics. Such conformational changes open the possibility for protein-protein interactions between OCP and the PBs core (i.e., activation of photoprotection mechanisms) or the fluorescence recovery protein. Even though OCP was discovered in 1981, little was known about the conformation of its active form until recently, as well as about the properties of homologs of its N and C domains. Studies carried out during recent years have made a breakthrough in understanding of the structural-functional organization of OCP and have enabled discovery of new aspects of the regulation of photoprotection processes in cyanobacteria. This review focuses on aspects of protein-protein interactions between the main participants of photoprotection reactions and on certain properties of representatives of newly discovered families of OCP homologs.

Abstract Background The aim of this paper is to reconsider the necessity for the green transition and the key preconditions for the implementation of a circular economy in Western Balkan countries. With the objective of the research in mind, the method of analysis and synthesis was applied to determine (1) regulatory and institutional prerequisites for the green transition; (2) the need for the Western Balkan countries to redefine the model of sustainable economic growth towards the green transition; (3) the development opportunities for recovery defined in the Green Agenda for the Western Balkans; and (4) the possibility of implementing the circular economy in the Western Balkans. Main text The main findings of the research indicate that: (1) the countries of the Western Balkan region, following the example of the EU, should define a national strategic approach to the green transition with an accompanying action plan and regulatory framework; (2) the biggest challenge of the green transition is the reform of the energy sector and the restructuring of the energy-intensive economy; (3) the countries have untapped potential in renewable energy sources and report the improvement of energy efficiency; (4) the circular economy can boost the green transition, because the countries of the region have a five-time lower value of resource productivity than the average of the EU, while the generation of waste (excluding major mineral wastes) per GDP unit is lower compared to the EU; (5) cross-sectoral governance should be more coordinated. Conclusions The green transition might be a development opportunity for the Western Balkans, which should enable sustainable economic growth as well as energy security and environmental protection. However, the implementation of the Green Agenda is not easy, because the region faces the problem of underdeveloped regulatory and institutional capacities that might provide not only the base for long-term planning but also financial resources for the efficient implementation of projects. In addition, it is essential to understand the principles of the Green Agenda and the interaction of all activities that should enable the achievement of defined goals.

A field experiment was conducted during 1993–1995 to study the effect of industrial effluent on the initial growth of Azadirachta indica A. Juss. (Neem) in arid region. The effluent released from textile industry had high pH, EC, SAR and RSC. Various treatments were: irrigation with effluent only (W1), effluent mixed with canal water at 1:1 ratio (W2), gypsum‐treated effluent (W3), gypsum‐treated soil (W4) and wood ash‐treated soil (W5). W5 was the best treatment where neem attained 218 cm height, 118 cm crown diameter and 11.2 cm collar circumference at 28 months of age; followed by W1 treatment, where trees were on an average 186 cm tall and had 104 cm crown diameter and 9.4 cm collar circumference. Growth of the seedlings was the poorest in W2treatment. Increase in biomass accumulation over W2 treatment (1.89 kg tree−1) was 3.6 fold in W5, 2.1 fold in W1, 2.0 fold in W4 and 1.4 fold in W3 treatments. Though effluent application increased soil organic matter, electrical conductivity and in some cases pH also, but gypsum‐ and wood ash‐ treated soil ameliorated the pH by 0.25 units in comparison to the initial data. These results suggest that industrial wastewater can be effectively used to boost up establishment and growth of Neem (Azadirachta indica) in arid zone. Addition of wood ash improves the rate of growth. Irrigation with industrial effluent caused slight increase in electrical conductivity and decline in the soil pH. Santrauka Eksperimentas vyko 1993–1995 m. siekiant ištirti pramoninių nuotekų poveikį Azadirachta indica A. Juss. (Neem) sodinukų augimo pradžiai sausringuose regionuose. Tekstilės pramonės išleidžiamų nuotekų didelės pH rodiklio reikšmės, elektrinis laidumas, natrio adsorbcijos santykis ir natrio karbonato liekana. Tiriant taikyti įvairūs dirvožemio apdorojimo būdai: drėkinta tik nuotekomis (W1 ), nuotekos maišytos su kanalo vandeniu santykiu 1:1 (W2 ), nuotekos veiktos gipsu (W3 ), į dirvožemį dėta gipso (W4 ) ir dirvožemis tręštas medienos pelenais (W5 ). Efektyviausias buvo W5 apdorojimo būdas. 28 mėnesių augalai siekė 218 cm aukštį, jų vainiko skersmuo buvo 118 cm, žiedo perimetras – 11,2 cm. Stebint W1 apdorojimo tipą, medžiai buvo vidutiniškai 186 cm aukščio, vainikas – 104 cm skersmens, žiedai 9,4 cm perimetro. Blogiausiai sodinukai augo apdorojant W2 būdu. Nors naudojant nuotekas dirvožemio organinių medžiagų kiekis, elektrinis savitasis laidumas ir kai kuriais atvejais pH reikšmė padidėjo, tačiau gipsu ir medienos pelenais apdorotame dirvožemyje pH padidėjo per 0,25 vienetus, palyginti su pirminiais duomenimis. Šie rezultatai rodo, kad pramoninės nuotekos gali būti efektyviai naudojamos Neem (Azadirachta indica) želdinti ir auginti sausose teritorijose. Medienos pelenai pagerino augimo spartą. Drėkinimas pramoninėmis nuotekomis lėmė nežymų elektrinio savitojo laidumo augimą ir dirvožemio pH sumažėjimą. Резюме Экспериментальное поле возделывалось в 1993–1995 гг. с целью изучить воздействие промышленных стоков на начало роста Azadirachta indica A. Juss. (Neem) в засушливых районах. В стоках от производства текстиля высоко значение pH, электропроводимость, соотношение адсорбции натрия и остаток карбоната натрия. Применялись разные способы обработки почвы: орошение только стоками (W1 ); смесью стоков с водой из канала в соотношении 1:1 (W2 ); стоками, обработанными гипсом (W3 ); обработка почвы гипсом (W4 ) и удобрение древесной золой (W5 ). Наиболее эффективным способом оказалась обработка древесной золой. Высота растений в возрасте 28 месяцев составляла 218 см, венчик в поперечнике – 118 см, цветок – 11,2 см. После обработки почвы по типу W1 растения достигали 186 см в высоту, венчик в поперечнике – 104 см, цветок – 9,4 см. Наименее эффективным для растений способом оказалась обработка почвы по типу W2 . Несмотря на то, что при применении стоков количество органических веществ в почве, электропроводимость и в некоторых случаях значение pH увеличилось, однако при обработке почвы гипсом и древесной золой pH увеличилось более чем на 0,25 единиц по сравнению с начальными данными. Эти результаты показали, что промышленные стоки могут эффективно применяться для озеленения и выращивания Neem (Azadirachta indica) на засушливых территориях. Древесная зола ускоряла рост растений. Орошение промышленными стоками способствовало незначительному увеличению электропроводимости и уменьшению в почве pH.

Purpose This paper aims to propose a liquidity management solution for Islamic financial institutions (IFIs) that concurs with sustainable development and financial stability. Design/methodology/approach The study is a qualitative research. It uses the exploratory research methodology, specifically the content analysis approach, to gather primary data and identify and interpret relevant secondary data and Sharīʿah concepts. The purpose is to develop a liquidity management solution for IFIs. The proposal is based on the Unleveraged Green Investment Trust (UGIT) model, which is consistent with Basel III regulatory requirements. In developing the UGIT model, the exploratory research was complemented by a case study to examine the UGIT solution for the particular case of renewable energy. Findings The model demonstrates how financial innovation can meet both financial stability and sustainable development objectives, thereby achieving the spirit of Islamic finance. The structure further highlights the importance of regulatory and fiscal frameworks to enhance liquidity management and investor appeal for green financial instruments. Originality/value This study suggests a structure of UGIT to enable IFIs to meet their liquidity management needs while promoting sustainable development.

AbstractThe production of Z boson pairs in proton–proton ($${\mathrm{p}} {\mathrm{p}} $$ p p ) collisions, $${{\mathrm{p}} {\mathrm{p}} \rightarrow ({\mathrm{Z}}/\gamma ^*)({\mathrm{Z}}/\gamma ^*) \rightarrow 2\ell 2\ell '}$$ p p → ( Z / γ ∗ ) ( Z / γ ∗ ) → 2 ℓ 2 ℓ ′ , where $${\ell ,\ell ' = {\mathrm{e}}}$$ ℓ , ℓ ′ = e or $${{\upmu }}$$ μ , is studied at a center-of-mass energy of 13$$\,\text {TeV}$$ TeV with the CMS detector at the CERN LHC. The data sample corresponds to an integrated luminosity of 137$$\,\text {fb}^{-1}$$ fb - 1 , collected during 2016–2018. The $${\mathrm{Z}} {\mathrm{Z}} $$ Z Z production cross section, $$\sigma _{\text {tot}} ({\mathrm{p}} {\mathrm{p}} \rightarrow {\mathrm{Z}} {\mathrm{Z}} ) = 17.4 \pm 0.3 \,\text {(stat)} \pm 0.5 \,\text {(syst)} \pm 0.4 \,\text {(theo)} \pm 0.3 \,\text {(lumi)} \text { pb} $$ σ tot ( p p → Z Z ) = 17.4 ± 0.3 (stat) ± 0.5 (syst) ± 0.4 (theo) ± 0.3 (lumi) pb , measured for events with two pairs of opposite-sign, same-flavor leptons produced in the mass region $${60< m_{\ell ^+\ell ^-} < 120\,\text {GeV}}$$ 60 < m ℓ + ℓ - < 120 GeV is consistent with standard model predictions. Differential cross sections are also measured and agree with theoretical predictions. The invariant mass distribution of the four-lepton system is used to set limits on anomalous $${\mathrm{Z}} {\mathrm{Z}} {\mathrm{Z}} $$ Z Z Z and $${{\mathrm{Z}} {\mathrm{Z}} \gamma }$$ Z Z γ couplings.