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Abstract Fractures along interfaces between host rock and wellbore cement have long been identified as potential CO2 leakage pathways from subsurface CO2 storage sites. As a consequence, cement alteration due to exposure to CO2 has been studied extensively to assess wellbore integrity. Previous studies have focused on the changes to either chemical or mechanical properties of cement upon exposure to CO2-enriched brine, but not on the effects of loading conditions. This paper aims to correct this deficit by considering the combined effects of the fracture pathway and changing effective stress on chemical and mechanical degradation at conditions relevant to geologic carbon storage. Flow-through experiments on fractured cores composed of cement and tight sandstone caprock halves were conducted to study the alteration of cement due to exposure to CO2-enriched brine at 3, 7, 9, and 12 MPa effective stress. We characterized relevant reactions via solution chemistry; fracture permeability via changes to differential pressure; mechanical changes via micro-hardness testing, and pore structure changes via x-ray tomography. This study showed that the nature and the rates of the chemical reactions between cement and CO2 were not affected by the effective stress. The differences in the permeability responses of the fractures were attributed to interactions among the geometry of the flow path, the porosity increase of the reacted cement, and the mechanical deformation of reacted asperities. The suite of observed chemical reactions contributed to change in cement mechanical properties. Compared to the unreacted cement, the average hardness of the amorphous silica and depleted layers was decreased while the hardness of the calcite layer was increased. Tomographic imaging showed that preferential flow paths formed in some of the core-flood experiments, which had a significant impact on the permeability response of the fractured samples. We interpreted the observed permeability responses in terms of competition between dissolution of cement phases (leading to enhanced permeability) and mechanical deformation of reacted regions (leading to reduced permeability).

Short-term load forecasting is an essential instrument in power system planning, operation and control. Many operating decisions are based on load forecasts, such as dispatch scheduling of generating capacity, reliability analysis, and maintenance planning for the generators. Overestimation of electricity demand will cause a conservative operation, which leads to the start-up of too many units or excessive energy purchase, thereby supplying an unnecessary level of reserve. On the contrary, underestimation may result in a risky operation, with insufficient preparation of spinning reserve, causing the system to operate in a vulnerable region to the disturbance. In this paper, semi-parametric additive models are proposed to estimate the relationships between demand and the driver variables. Specifically, the inputs for these models are calendar variables, lagged actual demand observations and historical and forecast temperature traces for one or more sites in the target power system. In addition to point forecasts, prediction intervals are also estimated using a modified bootstrap method suitable for the complex seasonality seen in electricity demand data. The proposed methodology has been used to forecast the half-hourly electricity demand for up to seven days ahead for power systems in the Australian National Electricity Market. The performance of the methodology is validated via out-of-sample experiments with real data from the power system, as well as through on-site implementation by the system operator.

Heatwaves have potential health and safety implications for many workers, and heatwaves are predicted to increase in frequency and intensity with climate change. There is currently a lack of comparative evidence for the effects of heatwaves on workers' health and safety in different climates (sub-tropical and temperate). This study examined the relationship between heatwave severity (as defined by the Excess Heat Factor) and workers' compensation claims, to define impacts and identify workers at higher risk.Workers' compensation claims data from Australian cities with temperate (Melbourne and Perth) and subtropical (Brisbane) climates for the years 2006-2016 were analysed in relation to heatwave severity categories (low and moderate/high severity) using time-stratified case-crossover models.Consistent impacts of heatwaves were observed in each city with either a protective or null effect during heatwaves of low-intensity while claims increased during moderate/high-severity heatwaves compared with non-heatwave days. The highest effect during moderate/high-severity heatwaves was in Brisbane (RR 1.45, 95% CI: 1.42-1.48). Vulnerable worker subgroups identified across the three cities included: males, workers aged under 34 years, apprentice/trainee workers, labour hire workers, those employed in medium and heavy strength occupations, and workers from outdoor and indoor industrial sectors.These findings show that work-related injuries and illnesses increase during moderate/high-severity heatwaves in both sub-tropical and temperate climates. Heatwave forecasts should signal the need for heightened heat awareness and preventive measures to minimise the risks to workers.

A detailed pollen record from the Ocean Drilling Program Site 820 core, located on the upper part of the continental slope off the coast of northeast Queensland, was constructed to compare with the existing pollen record from Lynch's Crater on the adjacent Atherton Tableland and allow the production of a regional picture of vegetation and environmental change through the last glacial cycle. Some broad similarities in patterns of vegetation change are revealed, despite the differences between sites and their pollen catchments, which can be related largely to global climate and sea-level changes. The original estimated time scale of the Lynch's Crater record is largely confirmed from comparison with the more thoroughly dated ODP record. Conversely, the Lynch's Crater pollen record has assisted in dating problematic parts of the ODP record. In contrast to Lynch's Crater, which reveals a sharp and sustained reduction in drier araucarian forest around 38,000 yrs BP, considered to have been the result of burning by Aboriginal people, the ODP record indicates, most likely, a stepwise reduction, dating from 140,000 yrs BP or beyond. The earliest reduction shows lack of a clear connection between Araucaria decline and increased burning and suggests that people may not have been involved at this stage. However, a further decline in araucarian forest, possibly around 45,000 yrs BP, which has a more substantial environmental impact and is not related to a time of major climate change, is likely, at least partially, the result of human burning. The suggestion, from the ODP core oxygen isotope record, of a regional sea-surface temperature increase of around 4 degrees C between about 400,000 and 250,000 yrs BP, may have had some influence on the overall decline in Araucaria and its replacement by sclerophyll vegetation. (C) 2000 Elsevier Science B.V. All rights reserved.

AbstractHerein, we present ultrasmall delafossite‐type Mg‐doped CuCrO2 nanocrystals prepared by using hydrothermal synthesis and their first application as photocathodes in efficient p‐type dye‐sensitized solar cells. The short‐circuit current density (Jsc) is notably increased by approximately 27 % owing to the decreased crystallite size and the enhanced optical transmittance associated with Mg doping of the CuCrO2 nanocrystalline sample. An open‐circuit voltage (Voc) of 201 mV, Jsc of 1.51 mA cm−2, fill factor of 0.449, and overall photoconversion efficiency of 0.132 % have been achieved with the CuCr0.9Mg0.1O2 dye photocathode sensitized with the P1 dye under optimized conditions. This efficiency is nearly three times higher than that of the NiO‐based reference device, which is attributed to the largely improved Voc and Jsc. The augmentation of Voc and Jsc can be attributed to the lower valance band position and the faster hole diffusion coefficient of CuCr0.9Mg0.1O2 compared to those of the NiO reference, respectively, which leads to a higher hole collection efficiency.

Public transport systems in different parts of the world are currently undergoing a change characterised by the introduction of battery-powered electric buses in everyday operations. The introduction of electric buses brings new challenges such as high investment costs and technology concerns, as well as new forms of collaboration between both established and new actors. The aim of this paper is to disentangle different actors’ rationale for the transition, identifying underlying interests in and expectations of the electric bus system. With a focus on the Swedish context, we found that whilst common rationales exist, these are influenced by collective expectations and different underlying interests for the actor groups. We found that the interests of the actors are grounded in expectations of future developments, but also relate to the experience that the transition is occurring faster than previously anticipated. The results show a high degree of consensus regarding the transition to electric buses, although the actors have varying resources and action spaces with which to influence the transition, which is largely determined by the institutional and local context.

Electricity generation systems have traditionally been evaluated using only a limited number of economic or environmental indicators, for example capital investment, generation cost or carbon dioxide emissions. Moreover, the evaluations have generally been restricted to performance within the geographic boundary of the power station. This paper reports a sustainability assessment of power generation from Australian fossil fuels, notably black coal, brown coal and natural gas. A range of key sustainability indicators incorporating environmental, economic and social performance are included. The system boundary incorporates fuel extraction, fuel transport to the power station, generation of power, and transmission of electricity to the point of use. Most commonly employed existing technologies and some promising advanced technologies for power generation are considered. The cases of exporting Australian LNG and black coal to Japan for power generation in that country have also been considered. No one fuel or technology system was superior or inferior for every indicator. However the following generalizations can be made: Natural gas combined cycle systems have advantages for the majority of environmental and economic indicators, brown coal has an advantage in terms of value added, and black coal has relatively poor safety performance.

Slurry transportation is an essential process in numerous industrial applications, widely studied for its efficiency in material conveyance. Despite substantial research, the impact of pipe wall roughness on critical metrics such as pressure drop, specific energy consumption (SEC), and the Nusselt number remains relatively underexplored. This study provides a detailed analysis using a three-dimensional computational model of a slurry pipeline, with a 0.0549 m diameter and 3.8 m length. The model employs an Eulerian multiphase approach coupled with the RNG k-ε turbulence model, assessing slurry concentrations Cw = 40–60% (by weight). Simulations were conducted at flow velocities Vm = 1–5 m/s, with pipe roughness (Rh) ranging between 10 and 50 µm. Computational findings indicate that both pressure drop and SEC increase proportionally with roughness height, Vm, and Cw. Interestingly, the Nusselt number appears unaffected by roughness height, although it rises corresponds to Vm, and Cw. These insights offer a deeper understanding of slurry pipeline dynamics, informing strategies to enhance operational efficiency and performance across various industrial contexts.