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Abstract To achieve the EU climate and energy objectives, a transition towards a future sustainable energy system is needed. The integration of the huge potential for industrial waste heat recovery into smart energy system represents a main opportunity to accomplish these goals. To successfully implement this strategy, all the several stakeholders' conflicting objectives should be considered. In this paper an evolutionary multi-objective optimization model is developed to perform a sustainability evaluation of an energy system involving an industrial facility as the waste heat source and the neighbourhood as district heating network end users. An Italian case study of heat recovery from a steel casting facility shows how the model allows to properly select the district heating network set of users to fully exploit the available waste energy. Design directions such as the thermal energy storage capacity can be also provided. Moreover, the model enables the analysis of the trade-off between the stakeholders’ different perspectives, allowing to identify possible win-win solutions for both the industrial sector and the citizenship.

The electrical resistance of Ni 50 Ti 30 Hf 20 and Ni 50 Ti 40.5 Hf 9.5 alloys during Stress Assisted Two Way Memory Effect was investigated with the aim to deduce the relationship between electrical resistance and deformation across the transformation range. Results show an almost linear relationship although a crossing point between increasing and decreasing deformation may compromise the use of these alloys actuators.

Abstract AP1000® Generation III+ reactor bases its safety concept on passive systems, differently from the previous Generation II reactors. This fact has led the approximations and methodologies previously used for modeling active safety systems to be reviewed and adapted to simulate the physics of passive systems. Diverse studies about the AP1000 containment have demonstrated the difficulty to correctly model the occurring phenomenology. In this paper, an integral AP1000 3D containment GOTHIC model is presented, including the Passive Containment Cooling System (PCCS). The model includes the compartments inside and outside the metallic containment liner that influence the thermal–hydraulic behavior. The model is tested against a Large Break Loss of Coolant Accident (LBLOCA) to assess its thermal–hydraulic performance, assuming a PCS tank malfunction, what is a conservative hypothesis. The pressure and temperature evolution predicted by the 3D containment model is analyzed and compared with a single node Lumped Parameters model, allowing to evaluate some preliminary benefits of 3D modeling for containment safety analysis. The 3D containment model allows to predict the thermal evolution in each containment compartment capturing the heterogeneity of this phenomenon, with higher resolution than the lumped parameters models traditionally used in this kind of analyses. It allows to observe the thermohydraulic conditions locally at any time during the transient.

Short-term generation scheduling is an important function in daily operational planning of power systems. It is defined as optimal scheduling of power generators over a scheduling period while respecting various generator constraints and system constraints. Objective of the problem includes costs associated with energy production, start-up cost and shut-down cost along with profits. The resulting problem is a large scale nonlinear mixed-integer optimization problem for which there is no exact solution technique available. The solution to the problem can be obtained only by complete enumeration, often at the cost of a prohibitively computation time requirement for realistic power systems. This paper presents a hybrid algorithm which combines Lagrangian Relaxation (LR) together with Evolutionary Algorithm (EA) to solve the problem in cooperative and competitive energy environments. Simulation studies were carried out on different systems containing various numbers of units. The outcomes from different algorithms are compared with that from the proposed hybrid algorithm and the advantages of the proposed algorithm are briefly discussed.

Abstract Breastshot water wheels are gravity hydraulic machines employed in low head sites. The scope of this work is to test the performance of a breastshot water wheel with two geometric inflow configurations: a sluice gate at different openings and two vertical overflow weirs. With the sluice gate, the maximum efficiency of the plant is 75%, constant over a wide range of flow rates, while the efficiency with the weir is increasing in the same flow rate range. Therefore, the wheel with the weir can exploit higher water volumes, and also it performs better at high power input. In practical applications, the inflow configuration can be effectively controlled to optimize the operative working conditions of breastshot water wheels, depending on the external hydraulic ones. The experimental results are also discussed in dimensionless terms, in order to support engineers in the design of similar breastshot water wheels.

Previous work carried out for the last eight years resulted in the proposal of a complete system of dimensionless groups in order to represent the performance of different kinematic Stirling engine configurations. When looking for experimental support for the proposed model, some differences between the performances of several prototypes were observed. In this paper an equation is introduced to be applied to all known kinematic engines and to their whole range of performance. The coefficients appearing in this equation can be computed from temperature and geometrical dimensionless ratios and from experimental measurements at the maximum indicated power operating point. The meaning of those coefficients is interpreted and their usefulness to provide an engine performance overview is shown. The quasi-static simulation and the characteristic Mach number at the maximum indicated power operating point appear to be interesting criteria in order to evaluate the performance of prototypes.

Abstractπ‐Conjugated polyelectrolytes (CPEs) have been studied as interlayers on top of a separate hole transport layer (HTL) to improve the wetting, interfacial defect passivation, and crystal growth of perovskites. However, very few CPE‐based HTLs have been reported without rational molecular design as ideal HTLs for perovskite solar cells (PeSCs). In this study, the authors synthesize a triphenylamine‐based anionic CPE (TPAFS‐TMA) as an HTL for p‐i‐n‐type PeSCs. TPAFS‐TMA has appropriate frontier molecular orbital (FMO) levels similar to those of the commonly used poly(bis(4‐phenyl)‐2,4,6‐trimethylphenylamine) (PTAA) HTL. The ionic and semiconducting TPAFS‐TMA shows high compatibility, high transmittance, appropriate FMO energy levels for hole extraction and electron blocking, as well as defect passivating properties, which are confirmed using various optical and electrical analyses. Thus, the PeSC with the TPAFS‐TMA HTL exhibits the best power conversion efficiency (PCE) of 20.86%, which is better than that of the PTAA‐based device (PCE of 19.97%). In addition, it exhibits negligible device‐to‐device variations in its photovoltaic performance, contrary to the device with PTAA. Finally, a large‐area PeSC (1 cm2) and mini‐module (3 cm2), showing PCEs of 19.46% and 18.41%, respectively, are successfully fabricated. The newly synthesized TPAFS‐TMA may suggest its great potential as an HTL for large‐area PeSCs.

The aim of the present work was to develop 3D discrete element models capable of simulating the observed flow of glass beads (simple glass spheres) and maize grains (represented as a combination of spheres) during their discharge from a small model silo. A preliminary model for each material was constructed based on values for variables measured in the laboratory or taken from the literature. The ability of the models to predict the flow of these materials was then tested by comparing their results with observed discharge flows. Three variables were recorded for this: the mean bulk density at the end of the filling phase, the discharge rate and the flow pattern. The comparison of the results for the last of these variables required the discharge process be filmed using a high speed camera in order to more easily recognise the details of the flow. The preliminary model for the glass beads made very reasonable predictions, but that for the maize grains required calibration. This involved modifying the values of the friction properties of the material until a model capable of making acceptable predictions was obtained. The results obtained highlighted the influence of friction properties on the characteristics of the discharge flow. Finally, some of the numerical results provided by the models were analysed in order to describe the flow characteristics and the behaviour of the discharge rate in more detail.