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The reversible dissociation/carbonation of metal carbonates, performed in fluidized bed reactors, is one of the most promising technological solution for thermochemical energy storage (TCES) in concentrating solar power plants (CSP). In this framework, the SrCO3/SrO system is receiving increasing interest due to its high energy density (4 GJ/m3) and working temperatures (up to 1200 ?C). As the more investigated CaCO3/CaO couple, also SrO undergoes a dramatic drop of reactivity over multiple carbonation/calcina- tion cycles due to sintering. Even though the potentiality of this system has already been proved by thermo-gravimetric analyses, its actual reaction performances in a fluidized bed are strongly dependent on the gas-solid contact efficiency and heat/mass transfer between the gaseous and solid phase. In this work, the cyclic carbonation/calcination of the SrO/SrCO3 system for TCES-CSP has been investigated by thermo-gravimetric analysis and, for the first time, in a lab-scale fluidized bed rig, thus providing useful applicative insights. A new Al2O3-stabilized composite has been synthesized, i.e. Al2O3 has been added to SrO/SrCO3 system as both sintering inhibitor and flow conditioner. In particular, composite materials with different Al2O3/SrO composition have been synthesized to investigate the ef- fect of the inhibitor amount on both the fluidizability and energy storage performances.

Lysophosphatidic acid species (LPA) are lipid bioactive signaling molecules that have been recently implicated in the modulation of emotional and motivational behaviors. The present study investigates the consequences of either genetic deletion or pharmacological blockade of lysophosphatidic acid receptor-1 (LPA1) in alcohol consumption.The experiments were performed in alcohol-drinking animals by using LPA1-null mice and administering the LPA1 receptor antagonist Ki16425 in both mice and rats.In the two-bottle free choice paradigm, the LPA1-null mice preferred the alcohol more than their wild-type counterparts. Whereas the male LPA1-null mice displayed this higher preference at all doses tested, the female LPA1-null mice only consumed more alcohol at 6% concentration. The male LPA1-null mice were then further characterized, showing a notably increased ethanol drinking after a deprivation period and a reduced sleep time after acute ethanol administration. In addition, LPA1-null mice were more anxious than the wild-type mice in the elevated plus maze test. For the pharmacological experiments, the acute administration of the antagonist Ki16425 consistently increased ethanol consumption in both wild-type mice and rats; while it did not modulate alcohol drinking in the LPA1-null mice and lacked intrinsic rewarding properties and locomotor effects in a conditioned place preference paradigm. In addition, LPA1-null mice exhibited a marked reduction on the expression of glutamate-transmission-related genes in the prefrontal cortex similar to those described in alcohol-exposed rodents.Results suggest a relevant role for the LPA/LPA1 signaling system in alcoholism. In addition, the LPA1-null mice emerge as a new model for genetic vulnerability to excessive alcohol drinking. The pharmacological manipulation of LPA1 receptor arises as a new target for the study and treatment of alcoholism.

Intention of this work is to investigate the opportunity and feasibility of energy efficient networking in Home and Building automation protocols. Wired HBAS have traditionally devoted a relatively little attention to this point, especially if compared to wireless networks. This paper will try to address the issue by evaluating the introduction of power state switching in a real scenario and proposing the concept of functional and spatial adjacency among packets.

Il volume contiene gli abstract dei lavori accettati per i contributi orali e i poster presentati a HYPOTHESIS XII

Castor (Ricinus communis L.) is an oilseed species, which in southern Italy is cultivated as annual during the spring-summer period under irrigation, but in most temperate areas such as those of eastern coast of Sicily, it could be grown as semiperennial with no irrigation, by the adoption of autumnal sowings. A field experiment was conducted in southeastern Sicily with the aim of assessing plant surviving, seed yield and oil quality of four castor genotypes originating from different geographical areas (two Sicilian, one Tunisian and one Brazilian). The favorable climatic conditions allowed the plant to survive during the fall-winter period. Seed yield reached 3.45 t ha-1 on average of the two years and seed oil content ranged from 45% (Tunisian cultivar) to 48% ('Local RG 2' Sicilian genotype). Oil yield reflected the variation in seed yield. Genetic diversity for fatty acid composition and saponification number, iodine value and cetane number was evidenced. When ricinoleic acid is not taken into account, the oil of all genotypes satisfied the E.U. standards for biodiesel. The ricinoleic acid was the lowest (79%) in the Sicilian 'Local RG 2' and the highest (89%) in the Tunisian one, revealing a greater suitability of oil of the first genotype for biodiesel. In turn, the oil of Tunisian genotype could be exploited in other bio-based industrial sectors. The study also demonstrated that in the southeastern coast of Sicily autumnal sowings might be advantageous for castor grown as semi-perennial crop, mainly since they allow saving irrigation water.

Emergency building, devoted to give rapid and effective housing solutions to catastrophic and unexpected events, relies on the basic principles of construction rapidity and reversibility as well as the use of alternative energy sources. The growing need for environmental impact reduction in the building sector represents for temporary housing - especially under emergency conditions - a priority requisite, since, after given time lapses, areas occupied with emergency settlements will have to be recovered to their original use. In this case, the buildings' service life does not correspond to the life cycle of their materials and components; as a consequence, design activities will have to assure the dismantability and reusability of structures for further service cycles, making the whole process reversible: from construction to 'zero waste' de-construction. This paper aims at defining design criteria for low-impact emergency dwellings, assessing at the same time their applicability to corrugated steel pipes, obtained by assembling galvanized curved sheets - commonly used for underpasses and conduits - for which different use possibilities have been investigated. In this view, the research program has led to the definition of modular dwelling solutions. Then, technical feasibility studies have been carried out in collaboration with the industrial sector, taking advantage of consolidated production lines for innovative use purposes. Along the different research stages, a methodology has been defined for the assessment of the fundamental sustainability criteria through different simulation procedures; among these, the evaluation of the life-cycle environmental impacts with SimaPRO software and the 3D modelling for the maximization of the construction/environment integration - also in relation to the use of PV modules - have produced interesting results.

The aim of this report is to demonstrate and evaluate the potential of tall wheatgrass (Elytrigia elongata) to avoid GHG emissions and obtain lower economic costs in marginal areas of Spain. Our research built scenarios based on experimental plots (2 and 3 years growth) in 3 locations of Spain with completely different climate conditions (provinces of Girona, Soria and Palencia). In our experiences, we achieved an adequate establishment and biomass production, and assumed a rank of biomass yields until the end of the life cycle that is usually accepted to be about 15 years in many other studies in United States, Argentina and Eastern Europe where tall wheatgrass is extensively cultivated in marginal areas for sheep livestock production. Using our experimental plots and statistical information for economic inputs costs, we built 5 different scenarios per region considering a large range of biomass yields of tall wheatgrass. The analysis included a comparison with annual grasses economic costs calculated for a wide range of biomass yields of a previous study. We estimated GHG emissions savings for tall wheatgrasses and used our previous study (which had GHG emissions savings as well). Savings were calculated replacing natural gas electricity with electricity from biomass combustion in real power plants in Spain. In a wide range of yields, the results suggest that marginal areas might present a better performance with tall wheatgrass compared to annual winter grasses (cereals whole plant cuttings), thus producing biomass yields with higher GHG savings and lower economic costs at the farm level. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 217-229

Capítulos en libros This paper introduces a methodology to assist generation companies to deal with planning decisions in a competitive framework. It is based on a two-stage representation of market equilibrium. A first level computes an approximate continuous Cournot equilibrium for the entire model horizon. The second one discretises this solution separately for each year. Some aspects of its practical implantation are discussed. info:eu-repo/semantics/publishedVersion

Artículos en revistas Multi-terminal High Voltage Direct Current (HVDC) using Voltage Source Converters (VSC-HVDC) is a promising technology which provides flexible control of active and reactive power and facilitates remote renewable energy integration, above all using long cables. This paper analyses an active power control strategy for multi-terminal VSC-HVDC systems tailored to enhance transient stability of hybrid AC/DC grids. The proposed strategy controls each VSC using frequency measurements of all terminals. Its performance is compared to a strategy in which each VSC is controlled using only local frequency measurements of the AC side, proving that the proposed strategy shows better performance, even taking into account reasonable communication delays. The paper also shows that the proposed strategy generally gives similar results to those obtained when each VSC is controlled using the speed of the centre of inertia (COI). The speed of the COI is a more comprehensive and richer figure than the one proposed in this paper but it is also much more complex to obtain. Simulation results with PSS/E of a test system have been used to illustrate the comparisons and the main contributions of the proposal. info:eu-repo/semantics/publishedVersion