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The monitoring of a waste separation process in the nuclear power industry is considered. Recent advances in gamma ray emission and electrical impedance tomography mean that it is now feasible to unite these two modalities into a novel dual-modality monitoring method. This paper considers a simple model problem for the identification of a boundary between two distinct waste streams in a semi-continuous rotation separator. The simplicity of the problem affords the opportunity to demonstrate the general feasibility of the approach whilst avoiding unnecessary complications.

Biodiesel is a fuel generally consisting of a mixture of fatty acid methyl esters (FAMEs) which is used in alternative or in combination with petroleum diesel for its environmental benefits. Biodiesel is conveniently manufactured from vegetable oils by transesterification of triglycerides with methanol. However, the process brings about the concurrent formation of glycerol, which may become an oversupplied chemical if biodiesel production keeps growing. A novel biodiesel-like material (abbreviated as DMC-BioD) was developed by reacting soybean oil with dimethyl carbonate (DMC), which avoided the co-production of glycerol. The main difference between DMC-BioD and biodiesel produced from vegetable oil and methanol (MeOH-biodiesel) was the presence of fatty acid glycerol carbonate monoesters (FAGCs) in addition to FAMEs. In the following study, details regarding synthesis and composition of DMC-BioD are provided along with physical properties relevant for its use as a fuel. In addition, the production of potential pyrogenic contaminants was investigated by analytical pyrolysis and compared with those from MeOH-biodiesel, and the model compounds tristearin, triolein, trilinolein and oleic acid glycerol carbonate ester (OAGC). The presence of FAGCs influenced both fuel and flow properties, while the distribution of main pyrogenic compounds, including polycyclic aromatic hydrocarbons (PAHs), was little affected. Benefits and drawbacks of DMC as a candidate transmethylating reagent for producing biofuel from renewable resources and alternative co-products (glycerol carbonate and glycerol dicarbonate) are discussed.

There is a widely believed myth that replacing the use of fossil fuels largely by renewable forms of energy is, with a possible exception of nuclear power, critically dependent on the development of appropriate new technologies. Accordingly, it is held that decarbonizing straight away is particularly difficult and expensive. There was a time when this idea had an element of reality, but this is no longer the case. Unfortunately, belief in this myth is shared by those in positions of influence. This paper serves to document that this presumed reality no longer holds, although the misconception may have been based on fact in the past. Whilst the survey of the available technology offered concentrates on electricity supply, it also documents that manufacture of synthetic fuels via hydrogen obtained by electrolysis of water and CO2 integrates smoothly with electricity grid stabilization as well as reducing the CO2 content of the atmosphere. The likely price and cost development in the energy market is also reviewed. In addition the role of CCS, in practice mainly capture from the air and industrial processes other than power generation is reviewed against the background of the cost effective generation of electricity by harvesting renewable forms of energy.

Aeroengine manufacturers must continuously develop new high-performance engines, in terms of both specific fuel consumption and pollutant emissions. During the combustion of kerosene, CO 2 and lower amounts of SO 2 , CO, NO x and hydrocarbons are produced; those gases are directly or indirectly responsible for greenhouse effect. Large emission of NO x is produced by engines during the aircraft operation in airport. In the near future, the target in Europe for the aviation sector provides a reduction of SO% of NO x and 50% of CO 2 . For this reason, the hybrid-electric propulsion systems (HEPS) are becoming a viable alternative propulsion technology in the field of aviation, useful to guarantee a massive reduction of pollution. In the paper, the authors analyze and simulate a hybrid turbine/electric engine for a passengers regional aircraft, comparing the results in terms of pollutant and fuel consumption with the conventional thermal engine ones.

Abstract Bioenergy crops are one of the renewable energy options available to decarbonise the energy sector in Scotland and help to achieve the overall planned target of 80% reduction in greenhouse gas (GHG) emissions by 2050. A process-based model for poplar and willow developed for simulating the effect of different environmental and management options on growth and biomass yield was used to estimate the GHG abatement potential (GHG-AP) under different crop management options in Scotland. The model results of annual wood yield did not show a strong relation with any of the environmental factors except that of initial soil organic carbon (SOC) content. Increasing plant density and decreasing harvest frequency increased GHG-AP. Application of N-fertilizers at a rate of 50–100 kg N ha−1 resulted in the buildup of carbon in soils with less than 180 Mg C ha−1. However, in soils with greater SOC contents, annual emissions resulting from N fertilizer application were greater than the carbon saving through marginal increases in wood yield and SOC changes. The best management scenario in terms of economic and environmental objectives depends on identifying an optimum plant density based on the site specific conditions with a fertilizer application of 20–100 kg ha−1 y−1 and a five year harvest interval. Even under the best economic scenarios, SRC willow and poplar have a GHG-AP ranging from 9.9 to 11.6 and 8.8–10.0 Mg CO2 eq. ha−1 y−1, respectively. Under the best environmental scenarios this range increases to 10.5- 13.2 and 9–11.1 Mg CO2 eq. ha−1 y−1 for willow and poplar, respectively.

Abstract In arid areas, dry cooling technology is a preferable alternate of wet cooling mainly owing to the scarcity of abundant water supply. However, the supercritical CO2 power cycle still offers considerable thermal performance even at higher ambient temperature using dry cooling. The novelty of this work is the exhaustive designing of dry cooler for supercritical CO2 cycles (recompression and partial cooling) in concentrating solar power application. Prior to the design of tower, a preliminary analysis is conducted in achieving the optimum main compressor inlet temperature (33 °C-recompression and 40 °C-partial cooling) at which the cycle delivers the maximal efficiency. The comparison is performed at same higher and lower pressure and for the partial cooling, the intermediate pressure is optimized. At relatively higher compressor inlet temperatures (above 50 °C), the partial cooling achieves higher efficiency while at lower temperatures (30–49 °C), the recompression shows superior performance. An iterative nodal method is used for the air-cooled finned tube heat exchanger units that takes account of the dramatic variation in thermodynamic properties of CO2 with the bulk temperature. Kroger’s detailed methodology of designing dry cooler is adapted with the implementation of nodal approach for CO2 property variation. A dry cooling tower with 52.45 m height is essential for the recompression cycle, whereas the partial cooling requires two towers of the height of 35.4 m and 38.7 m. A thermal assessment is carried out on the dry cooler under various cycle fluid inlet temperatures and ambient temperatures. During hot and humid ambient conditions, lower compressor inlet temperatures (up to 53.1 °C) are obtained with the recompression cycle compared to partial cooling (up to 64.5 °C). In extreme climate condition of 50 °C air temperature, the recompression cycle provides superior thermal efficiency (46.5% against 45.5%). For future commercialization of dry cooled sCO2 power plant, the recompression cycle is preferred due to its superior performance and lower capital cost for cooling tower design and solar field. The work demonstrates the impact of dry cooling tower design strategy in the context of cycle thermal assessment under various working condition.

Abstract Comprehensive information about the concentrations, distribution, and modes of occurrence of elements in coal are important from the environmental and economic point of view. Although a great number of previous studies have investigated the geology of coalbed methane in the Qinshui Basin, only a few studies focused on the inorganic constituents in coal. More specifically, the mode of occurrences of valuable element Li in the No. 3 Coal is still unclear, although Li was found enriched. In this study, we present mineral characteristics, as well as multi-element data on the Permian No. 3 Coal from the Sucun and Gaohe Mines, Changzhi City, southern Qinshui Basin. The studied coals are characterized by low- to medium-ash yield (Ad = 5.72%- 28.18%, 12.34% on average), low volatile matter yield (Vdaf = 8.49–15.17%, 10.96% on average), suggesting a low volatile bituminous coal to semi-anthracite. NH4-illite and kaolinite are the main minerals in the coals detected by XRD, and trace amount of minerals calcite, dolomite, quartz, pyrite and diaspore can also be found. The major elements of the studied No. 3 coals are dominated by SiO2 and Al2O3, ranging 2.49–16.45 wt% and 2.13–12.9 wt% (on a whole-coal basis), respectively. Li is enriched in the No. 3 coals (5

Abstract A process based life cycle assessment of dimension stone production in the UK has been carried out according to PAS 2050. From a survey of eight production operations, on a cradle-to-site basis for UK destinations the carbon footprint of sandstone is 77 kgCO2e/tonne, that of granite is 107 kgCO2e/tonne and that of slate is 251 kgCO2e/tonne. These values are considerably higher for stone imported from abroad due to the impact of transport. Reducing the reliance on imported stone will contribute to emissions reduction targets as well as furthering the goals of sustainable development.

Recent problems about fossil fuels and environmental pollution carried to an even great interest about alternative energy sources and green-energy. Conversion of biomass in energy through biochemical and thermochemical process is one of the most promising and sustainable solution and, among thermochemical processes, pyrolysis is one of the most investigated. Different setting of parameters allow obtaining various types of pyrolysis processes, resulting in a different distribution in product yield. Before designing the simulation, Authors collected some literature data about existing biomass pyrolysis plant and products obtained through different kind of this process. Layout of simulation is based on a pilot-plant located in Caltagirone (Sicily). The simulation is developed in this paper through CHEMCAD software. The work has two aims: 1. Try to enhance percentage of bio-oil production modifying operative parameter; 2. Give a preliminary parameters and results to improve the process in a real plant. Authors show a synthesis of real pyrolysis plant showing type, steam and dimension of biomass and describing operative parameters as heating rate, residence time and maximum temperature reached during the process. Moreover, there is an overview of the entire production cycle, with a description of equipment such as type of reactor, heat exchangers and equipment of gas washing section, until obtaining of final products. Process is simulated in CHEMCAD through a K-Reactor block able to reproduce the reaction that occurs during pyrolysis. After products are discharged from the reactor, solid particles are collected in a tank whereas gas fraction carry on towards the other section of the plant to be treated. Through gas washing section and cooling process, condensable fraction is obtained and liquid phase is separated from gaseous fraction. To check reliability of results, the percentages of three products are compared with the ones collected through literature researches and there is a matching between them. Proceedings of the 26th European Biomass Conference and Exhibition, 14-17 May 2018, Copenhagen, Denmark, pp. 1131-1136