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Abstract Emissions and efficiency of a pellet boiler (40 kW) at nominal load were compared with emissions and efficiency at reduced load, while fired with six biomass pellets. The pellets include reed canary grass ( Phalaris arundinacea ), pectin waste from citrus shells ( Citrus reticulata ), sunflower husk ( Helianthus annuus ), peat, wheat straw ( Triticum aestivum ) and wood pellets. The measurements of emissions comprised of carbon monoxide (CO), nitrogen oxides (NO x ), sulphur oxides (SO x ) and flue dust mass concentrations (using DIN plus and isokinetic sampling techniques). Emissions varied as a function of operational loads, for each type of pellets. The CO emissions were insignificant with reed canary grass (RCG), citrus pectin waste (CPW) and straw pellets at nominal load, however, at reduced load same pellets emitted 1.9, 4.0 and 7.4 times higher CO than wood pellets, respectively. Peat pellets emitted maximum CO at nominal load (4221.1 mgNm −3 , 12.6 times higher than wood pellets) however; at reduced load CO emission was insignificant. The highest NO x emissions were reported with CPW, which were 3.4 and 4.6 times higher than wood pellets at nominal load and reduced load, respectively. Dust emissions were highest with sunflower husk and lowest with RCG pellets, at both operational modes. The best performance was reported with wood pellets, followed by RCG and pectin pellets, however, wood pellets combustion emitted 1.7 and 2.0 times higher dust DIN plus than RCG at nominal and reduced loads, respectively. Not only fuel specific combustion optimization but also operational load specific optimization is essential for efficient use of agro-pellets in this type of boilers.

Abstract Emissions and efficiency of a pellet boiler (40 kW) at nominal load were compared with emissions and efficiency at reduced load, while fired with six biomass pellets. The pellets include reed canary grass ( Phalaris arundinacea ), pectin waste from citrus shells ( Citrus reticulata ), sunflower husk ( Helianthus annuus ), peat, wheat straw ( Triticum aestivum ) and wood pellets. The measurements of emissions comprised of carbon monoxide (CO), nitrogen oxides (NO x ), sulphur oxides (SO x ) and flue dust mass concentrations (using DIN plus and isokinetic sampling techniques). Emissions varied as a function of operational loads, for each type of pellets. The CO emissions were insignificant with reed canary grass (RCG), citrus pectin waste (CPW) and straw pellets at nominal load, however, at reduced load same pellets emitted 1.9, 4.0 and 7.4 times higher CO than wood pellets, respectively. Peat pellets emitted maximum CO at nominal load (4221.1 mgNm −3 , 12.6 times higher than wood pellets) however; at reduced load CO emission was insignificant. The highest NO x emissions were reported with CPW, which were 3.4 and 4.6 times higher than wood pellets at nominal load and reduced load, respectively. Dust emissions were highest with sunflower husk and lowest with RCG pellets, at both operational modes. The best performance was reported with wood pellets, followed by RCG and pectin pellets, however, wood pellets combustion emitted 1.7 and 2.0 times higher dust DIN plus than RCG at nominal and reduced loads, respectively. Not only fuel specific combustion optimization but also operational load specific optimization is essential for efficient use of agro-pellets in this type of boilers.

Abstract This paper discusses the minimization of the fuel consumption of a gasoline engine through dynamic optimization. The minimization uses a mean value model of the powertrain and vehicle. This model has two state variables: the pressure in the engine intake manifold and the engine speed. The control input is the throttle valve angle. The model is identified on a universal engine dynamometer. Optimal state and control trajectories are calculated using Bock’s direct multiple shooting method, implemented in the software MUSCOD-II. The developed approach is illustrated both in simulation and experimentally for a generic test case where a vehicle accelerates from 1100 rpm to 3700 rpm in 30 s . The optimized trajectories yield minimal fuel consumption. The experiments show that a linear engine speed trajectory yields an extra fuel consumption of 13 % when compared to the optimal trajectory. It is shown that, with a simple model, a significant amount of fuel can be saved without loss of the fun-to-drive.

Abstract This paper discusses the minimization of the fuel consumption of a gasoline engine through dynamic optimization. The minimization uses a mean value model of the powertrain and vehicle. This model has two state variables: the pressure in the engine intake manifold and the engine speed. The control input is the throttle valve angle. The model is identified on a universal engine dynamometer. Optimal state and control trajectories are calculated using Bock’s direct multiple shooting method, implemented in the software MUSCOD-II. The developed approach is illustrated both in simulation and experimentally for a generic test case where a vehicle accelerates from 1100 rpm to 3700 rpm in 30 s . The optimized trajectories yield minimal fuel consumption. The experiments show that a linear engine speed trajectory yields an extra fuel consumption of 13 % when compared to the optimal trajectory. It is shown that, with a simple model, a significant amount of fuel can be saved without loss of the fun-to-drive.

Abstract Many countries committed themselves in the Kyoto protocol to reduce greenhouse gas (GHG) emissions. Some of these targeted emission reductions could result from a switch from coal-fired to gas-fired electricity generation. The focus in this work lies on Western Europe, with the presence of the European Union Emission Trading Scheme (EU ETS). For the switching to occur, several conditions have to be fulfilled. First, an economical incentive must be present, i.e. a sufficiently high European Union Allowance (EUA) price together with a sufficiently low natural gas price. Second, the physical potential for switching must exist, i.e. at a given load, there must remain enough power plants not running to make switching possible. This paper investigates what possibilities exist for switching coal-fired plants for gas-fired plants, dependent on the load level (the latter condition above). A fixed allowance cost and a variable natural gas price are assumed. The method to address GHG emission reduction potentials is first illustrated in a methodological case. Next, the GHG emission reduction potentials are addressed for several Western European countries together with a relative positioning of their electricity generation. GHG emission reduction potentials are also compared with simulation results. GHG emission reduction potentials tend to be significant. The Netherlands have a very widespread switching zone, so GHG emission reduction is practically independent of electricity generation. Other counties, like Germany, Spain and Italy could reduce GHG emissions significantly by switching. With an allowance cost following the switch level of a 50% efficient gas-fired plant and a 40% efficient coal-fired plant in the summer season (like in 2005), the global GHG emission reduction (in the electricity generating sector) for the eight modeled zones could amount to 19%.

Abstract Many countries committed themselves in the Kyoto protocol to reduce greenhouse gas (GHG) emissions. Some of these targeted emission reductions could result from a switch from coal-fired to gas-fired electricity generation. The focus in this work lies on Western Europe, with the presence of the European Union Emission Trading Scheme (EU ETS). For the switching to occur, several conditions have to be fulfilled. First, an economical incentive must be present, i.e. a sufficiently high European Union Allowance (EUA) price together with a sufficiently low natural gas price. Second, the physical potential for switching must exist, i.e. at a given load, there must remain enough power plants not running to make switching possible. This paper investigates what possibilities exist for switching coal-fired plants for gas-fired plants, dependent on the load level (the latter condition above). A fixed allowance cost and a variable natural gas price are assumed. The method to address GHG emission reduction potentials is first illustrated in a methodological case. Next, the GHG emission reduction potentials are addressed for several Western European countries together with a relative positioning of their electricity generation. GHG emission reduction potentials are also compared with simulation results. GHG emission reduction potentials tend to be significant. The Netherlands have a very widespread switching zone, so GHG emission reduction is practically independent of electricity generation. Other counties, like Germany, Spain and Italy could reduce GHG emissions significantly by switching. With an allowance cost following the switch level of a 50% efficient gas-fired plant and a 40% efficient coal-fired plant in the summer season (like in 2005), the global GHG emission reduction (in the electricity generating sector) for the eight modeled zones could amount to 19%.

Abstract A heterogeneous magnesium oxide catalyst is a good alternative for homogeneous catalysts for the transesterification of alkyl esters for the production of fine-chemicals as well as for the production of biodiesel. The transesterification of ethyl acetate with methanol was used as a model reaction to simulate fine-chemical production in a batch slurry reactor at industrial conditions. The transesterification of triolein with methanol to methyl oleate was chosen to simulate continuous production of biodiesel from rapeseed oil. A kinetic model based on a three-step ‘Eley–Rideal’ type of mechanism in the liquid phase was used in both process simulations. The transesterification reaction occurs between methanol adsorbed on a magnesium oxide free basic site and ethyl acetate or the glyceride from the liquid phase. Methanol adsorption is assumed to be rate-determining in both processes. Activity coefficients were required to account for the significant non-ideality of the reaction mixture in the simulations of both processes. The simulations indicate that a production of 500 tonnes methyl acetate per year can be reached at ambient temperature in a batch reactor of 10 m 3 containing 5 kg of MgO catalyst, and that a continuous production of 100,000 tonnes of biodiesel per year can be achieved at 323 K in a continuous stirred reactor of 25 m 3 containing 5700 kg of MgO catalyst. Although various assumptions and simplifications were made in these explorative simulations the assumptions concerning the reaction kinetics used, the results indicate that for both processes a heterogeneous magnesium oxide catalyst shows promising potential as a viable industrial scale alternative.

Abstract A heterogeneous magnesium oxide catalyst is a good alternative for homogeneous catalysts for the transesterification of alkyl esters for the production of fine-chemicals as well as for the production of biodiesel. The transesterification of ethyl acetate with methanol was used as a model reaction to simulate fine-chemical production in a batch slurry reactor at industrial conditions. The transesterification of triolein with methanol to methyl oleate was chosen to simulate continuous production of biodiesel from rapeseed oil. A kinetic model based on a three-step ‘Eley–Rideal’ type of mechanism in the liquid phase was used in both process simulations. The transesterification reaction occurs between methanol adsorbed on a magnesium oxide free basic site and ethyl acetate or the glyceride from the liquid phase. Methanol adsorption is assumed to be rate-determining in both processes. Activity coefficients were required to account for the significant non-ideality of the reaction mixture in the simulations of both processes. The simulations indicate that a production of 500 tonnes methyl acetate per year can be reached at ambient temperature in a batch reactor of 10 m 3 containing 5 kg of MgO catalyst, and that a continuous production of 100,000 tonnes of biodiesel per year can be achieved at 323 K in a continuous stirred reactor of 25 m 3 containing 5700 kg of MgO catalyst. Although various assumptions and simplifications were made in these explorative simulations the assumptions concerning the reaction kinetics used, the results indicate that for both processes a heterogeneous magnesium oxide catalyst shows promising potential as a viable industrial scale alternative.

Abstract In the present tutorial, solar energy conversion is described in the framework of endoreversible thermodynamics, i.e. a recently developed subset of irreversible thermodynamics. From a general thermo-chemical endoreversible engine, we deduce the photovoltaic, the photothermal and the photochemical solar energy converter, besides of a few other, non-solar devices.