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Using recycled rubber crumbs as drainage layer in extensive green roofs have high potential to reduce the heating and cooling loads in buildings over traditional materials used as drainage layer, such as pozzolana gravel. However, the environmental impact due to the life cycle should be analyzed to assess its environmental benefit. This paper evaluates the environmental performance of green roofs in which the drainage layer is made of rubber crumbs, a recycled material the use of which is still experimental for this purpose. In this paper Life Cycle Assessment (LCA) is applied to compare the environmental impact of four constructive systems, two extensive green roofs without insulation layer and with different drainage materials, e a recycled material, rubber crumbs, and a conventional one, pozzolana gravel -, in front of two conventional flat roofs, with and without thermal insulation (polyurethane), built in an experimental set-up consisting of four monitored house-like cubicles, located in Mediterranean continental climate (Lleida, Spain). The LCA considered the production, construction, operational, and disposal phases of the roofs, according to UNE-EN 15643-2. The operational phase was carried out using data measured in the experimental set-up, considering heating and cooling energy consumptions in the winter and summer period, respectively.

Abstract This review summarizes and organizes the literature on life cycle assessment (LCA), life cycle energy analysis (LCEA) and life cycle cost analysis (LCCA) studies carried out for environmental evaluation of buildings and building related industry and sector (including construction products, construction systems, buildings, and civil engineering constructions). The review shows that most LCA and LCEA are carried out in what is shown as “exemplary buildings”, that is, buildings that have been designed and constructed as low energy buildings, but there are very few studies on “traditional buildings”, that is, buildings such as those mostly found in our cities. Similarly, most studies are carried out in urban areas, while rural areas are not well represented in the literature. Finally, studies are not equally distributed around the world.

Low temperature sensitive products transport and storage is an issue worldwide due to changes of the lifestyle population increase. Thermal energy storage (TES) is nowadays one of the most feasible solutions in facing the challenge of achieving energy savings. Many researchers have investigated energy efficiency of different cold units by applying TES systems using phase change materials (PCM). This paper provides an overview of the existing Spanish and European potential energy savings and CO2 mitigation by incorporating TES systems to cold storage and transportation systems. Data on energy savings were compiled from different case studies. Results depend on the scenarios studied and the extent of TES systems implementation; in the case of Europe for instance, yearly CO2 emissions may be cut down between 5% and 22% in reference to 2008 CO2 emissions from cold production considering that the proposed implementation of PCM TES in the case studies found in the literature is done.

The growing interest in forest biomass has made chipping increasingly popular all across Europe. Many operators have equipped for the purpose, but the large variety of working conditions found in the European forests makes it difficult to correctly estimate the productivity of each specific operation, leading to uncertainty in crucial decisions, such as: operation scheduling, price setting, machinery selection and acquisition. In 2001, the Italian National Council for Research (CNR) and the University of California (UC) developed a spreadsheet freeware capable of returning reliable estimates of chipping productivity and cost, on the basis of user-defined input data. The model is still available from the CNR website and is the object of frequent downloading and inquiries. Such model contains a set of predictive equations derived from the results of 102 field trials, conducted with 30 different machines, under a range of working conditions. In order to facilitate comparison with other estimates and to achieve methodological transparency, the equations are assembled into a simple Microsoft Excel workbook, and the costs are calculated with standard costing methods currently used in Forest and Agricultural Engineering. Since then CNR has continued to work on the subject, with the goal of updating and refining the model. Such work has included 45 validation tests and a separate study on the delay (idle) time typical for different chipping operation layouts. The study was concluded in 2009 and confirms that the model developed by CNR can provide reliable estimates of chipper productivity under a range of operational conditions. Authors believe that such a model can assist European foresters in keeping ahead with the growing biomass sector, thus helping them to seize an important business opportunity.

Enhanced or reduced pCO(2) (partial pressure of CO2) may affect the photosynthetic performance of marine microalgae since changes in pCO(2) can influence the activity of carbon concentrating mechanisms, modulate cellular RuBisCO levels or alter carbon uptake efficiency. In the present study we compared the photophysiology of the Antarctic diatom Chaetoceros brevis at two pCO(2) extremes: 750 ppmv (2x ambient) and 190 ppmv (0.5x ambient) CO2. Cultures were acclimated to four irradiance regimes: two regimes simulating deep or shallow vertical mixing, and two regimes mimicking limiting and saturating stable water column conditions. Then, growth rate, pigmentation, RuBisCO large subunit expression. RuBisCO activity, photosynthesis vs irradiance curves, effective quantum yield of PSII (F-v/F-m), and POC were measured. The four irradiance regimes induced a suite of photophysiological responses, ranging from low light acclimation to efficient photoprotection. Growth was reduced under the low constant and the deep mixing regime, compared to the shallow mixing and the stable saturating regime. Low stable irradiance resulted in higher light harvesting pigment concentrations, lower RuBisCO activity and a lower light saturation point (E-k) compared to the other irradiance regimes. Highest RuBisCO activity as well as P-max levels was measured in the shallow mixing regime, which received the highest total daily light dose. Photoprotection by xanthophyll cycling was observed under all irradiance regimes except the low stable irradiance regime, and xanthophyll cycle pool sizes were higher under the dynamic irradiance regimes. For the fluctuating irradiance regimes. E-v/E-m was hardly affected by previous excess irradiance exposure, suggesting minimal PSII damage. No significant differences between the two pCO(2) levels were found, with respect to growth, pigment content and composition, photosynthesis, photoprotection and RuBisCO activity, for all four irradiance regimes. Thus, within the range tested, pCO(2) does not significantly affect the photophysiological performance of C. brevis. (C) 2011 Elsevier B.V. All rights reserved.

The main objective of this paper is to study the possible use of D-mannitol as phase change material (PCM) for thermal energy storage. PCM are materials that have high phase change enthalpy and this thermophysical property gives them the ability to store energy as latent heat. D-mannitol is a material which has different morphological phases (polymorphism); here were studied b-form and d-form. Different polymorphic forms produce changes on melting point of D-mannitol. For this reason it is necessary to establish a suitable working temperature range for the use of D-mannitol as phase change material. The thermal characterization was performed with DSC analysis using 0.5 K min-1 slow-dynamic method. Polymorphism analysis of D-mannitol was analyzed to associate the thermal behavior obtained by DSC with a specific polymorphic phase. D-mannitol presented three different thermal behaviors: the first one had a melting peak at 167 oC, the second was a double melting peak at 155 oC and 166 oC, and the third a single peak at 155 oC. Due to irregular results, two working range were studied and through the thermal characterization, it was possible to define a working range where Dmannitol could be used as PCM for energy storage: this range is between 135 and 175 oC. Furthermore, it was possible to differentiate two crystalline phases of D-mannitol applying FT-IR analysis and to link them with thermal behavior observed in DSC. The percentage of times each thermal behavior is observed in DSC analysis was calculated. d-form is obtained 15.8% of analyzed cycles, the b-form appears 44.7% of times, and an intermediate transition between the two phases is found 39.5% of cycles.

Elevated environmental carbon dioxide (pCO2) levels have been found to cause organ damage in the early life stages of different commercial fish species, including Atlantic cod (Gadus morhua). To illuminate the underlying mechanisms causing pathologies in the intestines, the kidney, the pancreas and the liver in response to elevated pCO2, we examined related gene expression patterns in Atlantic cod reared for two months under three different pCO2 regimes: 380 μatm (control), 1800 μatm (medium) and 4200 μatm (high). We extracted RNA from whole fish sampled during the larval (32 dph) and early juvenile stage (46 dph) for relative expression analysis of 18 different genes related to essential metabolic pathways. At 32 dph, larvae subjected to the medium treatment displayed an up-regulation of genes mainly associated with fatty acid and glycogen synthesis (GYS2, 6PGL, ACoA, CPTA1, FAS and PPAR1b). Larvae exposed to the high pCO2 treatment upregulated fewer but similar genes (6PGL, ACoA and PPAR1b,). These data suggest stress-induced alterations in the lipid and fatty acid metabolism and a disrupted lipid homeostasis in larvae, providing a mechanistic link to the findings of lipid droplet overload in the liver and organ pathologies. At 46 dph, no significant differences in gene expression were detected, confirming a higher resilience of juveniles in comparison to larvae when exposed to elevated pCO2 up to 4200 μatm.

Abstract A heat pump coupled to thermal energy storage (TES) tanks is experimentally tested under simulated summer conditions and the results are presented in this paper. The cold TES tank is used for shifting the cooling load of a small house-like structure. The study evaluates the thermal behaviour of the TES tank for cold storage and the application of the system for space cooling. For the analysis, two different configurations of the tanks are compared: a water tank and a PCM tank. The PCM tank is filled with a commercial macro-encapsulated PCM, which has a phase change temperature of 10 °C. The results point out that the PCM tank is able to supply 14.5% more cold and to maintain the indoor temperature within comfort 20.65% longer than the water tank. However, it needs 4.55 times longer to charge the tank.