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Editorial Complex Optimization and Simulation in Power Systems

Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

Upwelling processes bring nutrient-rich waters from the deep ocean to the surface. Areas of upwelling are often associated with high productivity, offering great economic value in terms of fisheries. The sensitivity of spring/summer-time coastal upwelling systems to climate change has recently received a lot of attention. Several studies have suggested that their intensity may increase in the future while other authors have shown decreasing intensity in their equatorward portions. Yet, recent observations do not show robust evidence of this intensification. The Senegalo-Mauritanian upwelling system (SMUS) located at the southern edge of the north Atlantic system (12°N–20°N) and most active in winter/spring has been largely excluded from these studies. Here, the seasonal cycle of the SMUS and its response to climate change is investigated in the database of the Coupled Models Inter comparison Project Phase 5 (CMIP5). Upwelling magnitude and surface signature are characterized by several sea surface temperature and wind stress indices. We highlight the ability of the climate models to reproduce the system, as well as their biases. The simulations suggest that the intensity of the SMUS winter/spring upwelling will moderately decrease in the future, primarily because of a reduction of the wind forcing linked to a northward shift of Azores anticyclone and a more regional modulation of the low pressures found over Northwest Africa. The implications of such an upwelling reduction on the ecosystems and local communities exploiting them remains very uncertain.

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

Abstract The integrity of PWR pressure vessels is assured by keeping the crack tip stress intensity factor below the toughness of the material under monotonic isothermal loading. To study the effects of sudden cooling associated with a thermal gradient, a specially modified compact specimen has been developed. This has been used to carry out tests in the transition zone with different loading-temperature sequences liable to call the conventional criteria into question. The test is described in detail in Part I of this article [Chapuliot S, et al. Thermomechanical analysis of thermal shock fracture in the brittle/ductile transition zone. Part I: Description of the tests. Engng Fract Mech, 72, 2005, 661–73]. The second part describes numerical investigations to estimate the local mechanical fields at the crack tip and the overall parameters of the fracture mechanics. Finite element thermomechanical calculations are used to interpret the results of these new thermal shock tests using the master curve concept [ASTM E 1921–1997. Standard test method for determination of reference temperature To for ferritic steels in the transition range, 1997] and the Beremin statistical model [Beremin FM. A local criterion for cleavage fracture of a nuclear pressure vessel steel. Metall Trans A, 14A, November 1983, 2287–777].

Abstract In the present work two intelligent load frequency controllers have been developed to regulate the power output and system frequency by controlling the speed of the generator with the help of fuel rack position control. The first controller is obtained using fuzzy logic (FL) only, whereas the second one by using a combination of FL, genetic algorithms and neural networks. The aim of the proposed controller(s) is to restore in a very smooth way the frequency to its nominal value in the shortest time possible whenever there is any change in the load demand etc. The action of these controller(s) provides a satisfactory balance between frequency overshoot and transient oscillations with zero steady-state error. The design and performance evaluation of the proposed controller(s) structure are illustrated with the help of case studies applied (without loss of generality) to a typical single-area power system. It is found that the proposed controllers exhibit satisfactory well overall dynamic performance and overcome the possible drawbacks associated with other competing techniques.

Abstract This work aims to predict the general performances of a pilot parabolic trough collector during transient periods. To do so, a one-dimensional thermal model has been developed. It has been validated with experimental results from two different experimental setups, in steady-state conditions, with a transmitted power maximum error of 3.4%. Since the model only predicts the collector's thermal behavior, the parabolic trough collector has been first optically qualified. Then, optical efficiencies were used as input for the model. Experimental results were obtained in steady-state conditions and compared to the model. Then, experimental and numerical results were compared during two period of time with varying inlet conditions (i.e. dynamic condition tests): the first one with stable conditions, and the other one with harsh conditions. The developed model showed a good capability of predicting the thermal behavior of the parabolic trough collector with unstable environment (DNI, mass flow, inlet temperature), with a 9.6% relative standard error in the worst case. As a conclusion, while previous studies only focused on steady-state conditions, it has been showed that this kind of model can be used to precisely predict the dynamic behavior of large power plants.

A detailed analysis of the effects of ground grid configuration on grounding performance has been carried out for uniform and horizontally stratified soils with multiple layers. The results of the analysis reveal that the most efficient and cost-effective design is highly dependent on soil structure type and characteristics. In the absence of ground rods, grounding grids with uniform mesh size are quite efficient in soils having a thin (relative to grid size) high resistivity (relative to the lower layers) top soil, while grids with small mesh size at the periphery of the grid provide optimum performance in uniform soils and soils with low resistivity top soils. Ground rods were found to be effective only when a significant portion of their length is in contact with a low resistivity soil, as expected.