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This paper presents an analysis of the problem of reorientation of a riser pipe from an initially horizontal configuration during subsurface tow to the vertical position for installation. Front and rear barges support the pipe through cables. The orientation into a vertical configuration is accomplished by paying out the front cable. The pipe is treated as a Bernoulli-Euler beam with significant tension undergoing large angle deflections. A finite element procedure used state transfer matrices and successive linearization and the results show that the stress critical phase occurs when the pipe is going through the 60-deg angle to the horizontal direction.

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

Acidogenic anaerobic fermentation route was explored for the production of bioethanol and volatile fatty acids (VFA) from the press mud (PM) obtained from sugar mill. Slurry was prepared from PM having 10% of total solids and the same was hydrolyzed under acidic thermal conditions. Both press mud slurry (PMS) and pre-treated press mud slurry (PTPMS) was used as feedstock with mixed microbial consortia (MMC) and enriched mixed microbial consortia (EMMC). Mix of bioethanol and VFA were obtained in all the four cases (PMS-MMC, PMS-EMMC, PTPMS-EMC and PTPMS-EMMC), but, bioethanol and VFA yield of 0.04 g/g and 0.27 g/g, respectively obtained from PTPMS with EMMC was found to be comparatively higher. Control experiments carried out with glucose yielded bioethanol and VFA of 0.042 g/g and 0.28 g/g, respectively demonstrating that the organism was using reducible sugars in the feedstock for the generation of bioethanol by simultaneously producing the VFA from COD.

Abstract Microorganisms used in syngas fermentation require nutrients to grow and convert syngas (CO, H2 and CO2) into various products. Many of the essential nutrients can be provided by biochar. Poultry litter biochar (PLBC) contains minerals and trace metals and has a high pH buffering capacity, making it suitable as a nutrient supplement. The effects of PLBC loadings from 1 to 20 g L−1 on syngas fermentation were determined in 250 ml bottle assays. Results showed that 10 and 20 g L−1 PLBC significantly increased ethanol production compared to standard yeast extract (YE) medium. Fermentations in a 3L continuous stirred tank reactor (CSTR) with 10 g L−1 PLBC with and without 4-morpholineethanesulfonic acid (MES) showed 64% and 36% more ethanol production, respectively, than standard medium. The acetic acid accumulated at the beginning of fermentation was completely converted to ethanol in all media tested in the CSTR. These results demonstrate the feasibility of using PLBC medium without costly MES in the CSTR to enhance ethanol production from syngas for potential use at commercial scale.

Energy is consumed at every stage of the cycle of water production, distribution, end use, and recycled water treatment. Understanding the nexus of energy and water may help to minimize energy and water consumption and reduce environmental emissions. However, the interlinkages between water and energy have not received adequate attention. To address this gap, this paper disaggregates and quantifies the energy consumption of the entire water cycle process in Beijing. The results of this study show that total energy consumption by water production, treatment and distribution, end use, and recycled water reuse amounts to 55.6 billion kWh of electricity in 2015, or about 33% of the total urban energy usage. While water supply amount increased by only 10% from 2005 to 2015, the related energy consumption increased by 215% due to water supply structural change. The Beijing municipal government plans to implement many water saving measures in the area from 2016 to 2020, however, these policies will increase energy consumption by 74 million kWh in Beijing. This study responds to the urgent need for research on the synergies between energy and water. In order to achieve the goal of low-energy water utilization in the future, water and energy should be integrated in planning and management.

Electrical submersible pumps (ESPs) are widely used in upstream oil production. The presence of a low concentration solid phase, particle-laden flow, in the production fluid may cause severe damage in the internal sections of the pump which reduces its operating lifetime. To better understand the ESP pump's endurance, two different designs of commonly used mixed flow ESPs were studied numerically to determine the pump's flow behavior at its best efficiency point. Computational fluid dynamics (CFD) analysis was conducted on two stages of one design type of pump's primary flow path employing Eulerian–Granular scheme in ANSYS FLUENT. The key parameters affecting the erosion phenomena within the pump such as turbulence kinetic energy, local sand concentration, and near wall relative sand velocity were identified. The predictive erosion model applicable to pumps was developed by correlating the erosion key parameters with available experimental results. It is concluded that the use of an erosion model on the second design of ESP proves the model's versatility to predict the erosion on different designs of ESPs.

Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

The influence of various solvents (H2O, CH3OH, and C2H5OH) on product distribution and nature of products during hydrothermal liquefaction of sargassum tenerrimum algae has been examined. Hydrothermal liquefaction was performed using H2O (260, 280 and 300°C) and organic solvents CH3OH and C2H5OH (280°C) for 15min. The use of organic solvents significantly increased the yield of bio-oil. In the case of liquefaction with CH3OH and C2H5OH, the bio-oil yield was 22.8 and 23.8wt.% respectively whereas the bio-oil yield was 16.33wt.% with H2O. GC-MS analysis of the liquid products indicated the presence of various organic compounds including aromatics, nitrogenated and oxygenated compounds and higher selectivity amount of ester compounds were observed in the presence of alcoholic solvents. NMR and FT-IR showed that present of solvents have an effect on the decomposition of sargassum tenerrimum algae.

The Western Rajasthan commonly known as the ‘Indian Thar Desert’ is characterised by harsh climatic conditions with active dunal activities. Precipitation (150–420 mm/yr) is far lower than evapotranspiration potentials (1500–2000 mm/yr). Ground water is limited and often brakish and high (75–100 m) water table. Solar intensity in the region varies from 5.85 to 6.44 kWh/m2/day. Further, peculiarity of the region is that sun is available for 345–355 days in a year, the area being highly scarce in rainfall. On an average, rains occur only for 10.4–20.5 days in a year in the Thar Desert. Therefore, there is high scope to harness solar energy for useful purposes. Considering these solar energy technologies for entrepreneurs, the detailed cost analysis has been worked out and presented. With initial investment of Rs (Indian Rupees) 3.50 lakhs for solar drying projects for handling 60,000 kg fresh vegetables annually (300 working days/yr), the payback period and average net annual returns come to 2.17 years and ...

Anode with good electrocatalytic capabilities is more specifically required to reduce the ohimic losses during microbial fuel cell (MFC) operation. Highly conductive polymers viz., Polyaniline (PANi) and Polyaniline/Carbon nanotube (PANi/CNT) composite were prepared by in situ oxidative chemical polymerization method. Anodes were fabricated independently by coating PANi and CNT/PANi composites on the surface of SSM. The fabricated electrodes were evaluated as anode against stainless steel mess (SSM) as cathode during MFC operation. Maximum bioelectricity generation was observed in SSM-PANi/CNT-anode with power density of 48 mW/m2 and COD removal efficiency of 80% compared with SSM-PANi-anode (38 mW/m2; 65%) and SSM-anode (28 mW/m2; 58%). Bioelectrochemical characterization of the electrode materials using cyclic voltammetry and electrochemical impedance spectroscopy showed high electrocatalytic activity of PANi/CNT composite electrode. The study concluded the efficiency of PANi/CNT composite electrodes as bioanode in operation of MFCs towards achieving increased bioelectricity production along with wastewater treatment.