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The incorporation of recycled materials in concrete as a partial replacement of cement is becoming an alternative strategy for decreasing energy-intensive and CO2 emissions imputable to the cement manufacture, while investigating new potential uses of such multifunctional materials for environmental sustainability opportunities. Therefore, low-cost and worldwide availability of by-products materials is being assessed for sensible heat thermal energy storage applications based on cementitious materials. A greater concern is especially required focusing on the thermal stability of cement paste under high temperature cycled conditions. Moreover, compatibility between cement type and supplementary cementitious materials is determinant for the proper performance reliability. In this study, benchmark cement types were selected, i.e., ordinary Portland and calcium aluminate. Six supplementary cementitious materials were added to both types of cement in a content of 10 % and 25 %. Thermo-mechanical properties were studied before and after 10 thermal cycles from 290 to 650 ◦C. Results after thermal cycling showed that calcium aluminate cement paste mixtures maintained their integrity. However, most ordinary Portland cement paste mixtures were deteriorated: only mixtures with 25 % cement replacement with chamotte, flay ash, and ground granulated blast furnace slag remained without cracks. Calcium aluminate cement paste mixtures obtained the highest compressive strength, for partial replacement of cement with 10 % of chamotte, ground granulated blast furnace slag, and iron silicate. The incorporation of supplementary cementitious materials did not increase the thermal conductivity. This work was partially funded by the Ministerio de Ciencia, Innovación y Universidades de España (RTI2018-093849-B-C31 - MCIU/AEI/FEDER, UE) and by the Ministerio de Ciencia, Innovación y Universidades - Agencia Estatal de Investigación (AEI) (RED2018-102431-T). The authors at University of Lleida would like to thank the Catalan Government for the quality accreditation given to their research group (2017 SGR 1537). GREiA is certified agent TECNIO in the category of technology developers from the Government of Catalonia. This work is partially supported by ICREA under the ICREA Academia programme and by the Italian project ‘SOS-CITTA’ supported by Fondazione Cassa di Risparmio di Perugia under grant agreement No 2018.0499.026. Laura Boquera acknowledgments are due to the PhD school in Energy and Sustainable Development from University of Perugia. Laura Boquera would like to acknowledge the financial support provided by UNIPG – CIRIAF InpathTES project. The authors also thank the companies that provided the material to make possible this experimental research: Arciresa, Abrasivos Mendiola EDERSA—Masaveu Industria, General Admixtures S.p.A, Mapei, Ciments Molins industrial, and Promsa for the material supplied in this research. Financial support of the UNIPG-CIRIAF team has been achieved from the Italian Ministry of University and Research (MUR) in the framework of the Project FISR 2019: “Eco Earth” (code 00245) and it is gratefully acknowledged.

The Authors tested a complete new system for recovering wood fuel from the termination of depleted orchards. This operation can generate between 25 and 80 fresh t ha?¹, that can be directed to the growing bioenergy sector. The new system is based on highly-mobile low-investment general-purpose equipment, which allows containing operational cost and speeding relocation between work sites. The new residue collection system is quite flexible, and achieves cost-effective recovery on relatively small fields, often smaller than 1 ha. Under the conditions of the study, trees are cut, chipped and delivered at a cost between 35 and 40 EUR t?¹ (40% water mass fraction), provided that fields are within a 20 km distance from the biomass plant. Use of a standard drum chipper results in a better product quality than if a grinders is used, as is the case for conventional orchard removal operations. Feeding the chipper with a separate loader allows a significant cost reduction, provided that the field offers at least 25 t of fresh wood. In the future, use of remote controls and electronic tethers may allow a further cost reduction, which is estimated at 15%.

Elevated environmental carbon dioxide (pCO2) levels have been found to cause organ damage in the early life stages of different commercial fish species, including Atlantic cod (Gadus morhua). To illuminate the underlying mechanisms causing pathologies in the intestines, the kidney, the pancreas and the liver in response to elevated pCO2, we examined related gene expression patterns in Atlantic cod reared for two months under three different pCO2 regimes: 380 μatm (control), 1800 μatm (medium) and 4200 μatm (high). We extracted RNA from whole fish sampled during the larval (32 dph) and early juvenile stage (46 dph) for relative expression analysis of 18 different genes related to essential metabolic pathways. At 32 dph, larvae subjected to the medium treatment displayed an up-regulation of genes mainly associated with fatty acid and glycogen synthesis (GYS2, 6PGL, ACoA, CPTA1, FAS and PPAR1b). Larvae exposed to the high pCO2 treatment upregulated fewer but similar genes (6PGL, ACoA and PPAR1b,). These data suggest stress-induced alterations in the lipid and fatty acid metabolism and a disrupted lipid homeostasis in larvae, providing a mechanistic link to the findings of lipid droplet overload in the liver and organ pathologies. At 46 dph, no significant differences in gene expression were detected, confirming a higher resilience of juveniles in comparison to larvae when exposed to elevated pCO2 up to 4200 μatm.

For the design of ground-source heat-pump systems, the local subsoil is an invariant factor. To improve the evaluation of the local heat exchange capability, significant efforts recently have been devoted to identifying the ground thermal conductivity vertical profile. In recent years, an innovative method using hybrid optic fiber cables inserted into the ground has been developed. The technique relies on copper wires that thermally stimulate the ground. Optical fibers measure the temperature variation over time all along the cable at a high spatial and temporal resolution. In this work, the hybrid cable was grouted into a 125-m well located in the Po Plain in Northern Italy. The provided core defined the geological environment as a continuous succession of unconsolidated alluvial deposits of very limited thickness, grouped in 15 different granulometric units. Three enhanced thermal response test (ETRT) data sets were acquired in different seasons; for 5 days of heating followed by 5 days of recovery, the soil temperature was recorded continuously along the well, with a spatial resolution of 1 m. A new approach using a multiple linear regression is proposed to analyze the data sets to distinguish the thermal conductivity of each individual granulometric unit. The obtained thermal conductivity values were compared and discussed considering the standard thermal response test outputs and the thermal conductivity data obtained from direct measurements performed on the cores. The analytical method's reliability stands due to the high repeatability of the obtained results, despite the increased complexity of the treated geological setting.

Abstract Hydrothermal liquefaction (HTL) is a promising technology for converting organic-rich waste biomass such as swine manure (SM) and sewage sludge (SS) into energy-dense bio-crude. Until now, one of the major challenges associated with HTL is the pumpability of high dry-matter containing fibrous feedstocks for continuous processing. In this context, this batch scale study presents a suitable approach for enhancing the pumpability of the fibrous material, specifically SM, by co-processing with SS. Obtained results showed that SM was not pumpable itself due to its fibrous nature, but became pumpable by the addition of SS at overall 25 % dry matter content. It was highlighted that the sample mixture containing ~80 % of the SM was smoothly pumped with 20 % SS. Subsequently, HTL experiments were carried out on samples mixed under the ratios SM:SS (100:0, 0:100, 50:50, 80:20, and 20:80). The highest bio-crude yield (42.38 %) via maximum synergistic effect was obtained from the sample SM/SS (50:50) at ratio 1:1 with the best HHV of 36 MJ/kg. Almost 60–70 % mass of all bio-crudes contained volatiles at 350 °C. ICP-AES measurements revealed that the majority of the inorganic elements were concentrated into the solid phase, while 40–50 % of the potassium and sodium were transferred to the aqueous phase. In conclusion, using SS as a co-substrate with SM not only enhances the pumpability of SM, but its co-liquefaction has demonstrated beneficial synergistic effects on improving the energy recovery of the bio-crude.

The termination of a fruit orchard generates a considerable amount of residues that can be used as fuel in biomass-fired power plants. Various studies have explored the separate collection of the above-ground tree portion and the rootstock. The present work analyses the potential of complete-tree harvesting (aboveground biomass and rootstock) from a depleted peach orchard and compares this technique with the collection of the aboveground biomass (pruning residues and stems) only. Complete trees were extracted and piled, then ground into chunks and cleaned to reduce contamination with dirt and stones. As an alternative, trees were cut, stacked and chipped, leaving the rootstocks in the ground for later disposal. Extracting complete trees and piling them at the field's edge proceeded at a pace of ca. 1 ha day-1. Grinding and cleaning allowed reducing soil contamination by 10-15%. The study showed that complete-tree harvesting is a viable approach to containing the costs of biomass recovery from depleted orchards. Supply chain efficiency is maximized by including biomass compaction during the loading of trucks.

Novel methods for enhancing collaboration and interactions are required to ensure that stakeholders and governments are able to develop a shared vision that supports sustainable watershed governance. Particular attention must be placed on integrating stakeholders who would otherwise have limited decision-making power. By crossing professional, ideological and jurisdictional boundaries, stakeholders' perspectives are more likely to change than when staying within those boundaries. This process, known as boundary crossing, requires boundary objects; either artifacts, people, or institutions that play a bridging role between different boundary spaces. For this study, serious games powered by scientific models are identified as potentially effective boundary objects. A serious game simulation called Aqua Republica was used to organize game simulation events allowing stakeholders to connect in an in-person, informal and novel setting. This exploratory research aims to study the role and impact of serious games as boundary objects to enhancing collaboration and knowledge co-creation. The following research questions are addressed: (1) Do interactions increase over the course of a game simulation event? (2) Does the quality of interactions change over the course of a game simulation event? (3) Are the quantity and quality of interactions affected by pre-existing relationships? And if so, how? (4) How does the relationship between participants change over the course of a game simulation event? As part of this study, four game simulation events were organized that included students, professionals and diverse stakeholder groups working in watershed management contexts across Eastern Canada with 40 participants in total. Participants were divided into teams of 3-5 members and were surveyed and their interactions recorded. An interaction and social network analysis of the audiovisual recordings of each game simulation event indicates that interactions between participants increase in both quantity and quality as the game progresses. The analysis shows that serious game simulations provide an intervention platform not only to facilitate cross-boundary interactions, but also to strengthen relationships between diverse stakeholders, as expressed by an increase in mutual trust and empathy, as well as an improved understanding among the participants of the watershed system and the complex issues at stake.

Central solar heating plants with seasonal storage (CSHPSS) are among the most promising technologies to save energy in the industrial and residential-commercial building sectors. This work introduces a systematic approach to optimize these systems according to economic and environmental criteria. Our method, which combines the TRNSYS 17 simulation software with life cycle assessment and multi-objective optimization, identifies optimal CSHPSS designs for any climatic condition and heating demand profile considering economic and environmental criteria simultaneously. The capabilities of this approach are illustrated through its application to a case study of a CSHPSS located in Barcelona (Spain), which satisfies a heating demand for a neighborhood of 1120 dwellings. Numerical results show that the CSHPSS plant leads to significant environmental and economic improvements compared to the use of a conventional natural gas heating system. Our tool can guide engineers and architects in the transition towards a more sustainable residential sector.