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Using recycled rubber crumbs as drainage layer in extensive green roofs have high potential to reduce the heating and cooling loads in buildings over traditional materials used as drainage layer, such as pozzolana gravel. However, the environmental impact due to the life cycle should be analyzed to assess its environmental benefit. This paper evaluates the environmental performance of green roofs in which the drainage layer is made of rubber crumbs, a recycled material the use of which is still experimental for this purpose. In this paper Life Cycle Assessment (LCA) is applied to compare the environmental impact of four constructive systems, two extensive green roofs without insulation layer and with different drainage materials, e a recycled material, rubber crumbs, and a conventional one, pozzolana gravel -, in front of two conventional flat roofs, with and without thermal insulation (polyurethane), built in an experimental set-up consisting of four monitored house-like cubicles, located in Mediterranean continental climate (Lleida, Spain). The LCA considered the production, construction, operational, and disposal phases of the roofs, according to UNE-EN 15643-2. The operational phase was carried out using data measured in the experimental set-up, considering heating and cooling energy consumptions in the winter and summer period, respectively.

Abstract This review summarizes and organizes the literature on life cycle assessment (LCA), life cycle energy analysis (LCEA) and life cycle cost analysis (LCCA) studies carried out for environmental evaluation of buildings and building related industry and sector (including construction products, construction systems, buildings, and civil engineering constructions). The review shows that most LCA and LCEA are carried out in what is shown as “exemplary buildings”, that is, buildings that have been designed and constructed as low energy buildings, but there are very few studies on “traditional buildings”, that is, buildings such as those mostly found in our cities. Similarly, most studies are carried out in urban areas, while rural areas are not well represented in the literature. Finally, studies are not equally distributed around the world.

Low temperature sensitive products transport and storage is an issue worldwide due to changes of the lifestyle population increase. Thermal energy storage (TES) is nowadays one of the most feasible solutions in facing the challenge of achieving energy savings. Many researchers have investigated energy efficiency of different cold units by applying TES systems using phase change materials (PCM). This paper provides an overview of the existing Spanish and European potential energy savings and CO2 mitigation by incorporating TES systems to cold storage and transportation systems. Data on energy savings were compiled from different case studies. Results depend on the scenarios studied and the extent of TES systems implementation; in the case of Europe for instance, yearly CO2 emissions may be cut down between 5% and 22% in reference to 2008 CO2 emissions from cold production considering that the proposed implementation of PCM TES in the case studies found in the literature is done.

The main objective of this paper is to study the possible use of D-mannitol as phase change material (PCM) for thermal energy storage. PCM are materials that have high phase change enthalpy and this thermophysical property gives them the ability to store energy as latent heat. D-mannitol is a material which has different morphological phases (polymorphism); here were studied b-form and d-form. Different polymorphic forms produce changes on melting point of D-mannitol. For this reason it is necessary to establish a suitable working temperature range for the use of D-mannitol as phase change material. The thermal characterization was performed with DSC analysis using 0.5 K min-1 slow-dynamic method. Polymorphism analysis of D-mannitol was analyzed to associate the thermal behavior obtained by DSC with a specific polymorphic phase. D-mannitol presented three different thermal behaviors: the first one had a melting peak at 167 oC, the second was a double melting peak at 155 oC and 166 oC, and the third a single peak at 155 oC. Due to irregular results, two working range were studied and through the thermal characterization, it was possible to define a working range where Dmannitol could be used as PCM for energy storage: this range is between 135 and 175 oC. Furthermore, it was possible to differentiate two crystalline phases of D-mannitol applying FT-IR analysis and to link them with thermal behavior observed in DSC. The percentage of times each thermal behavior is observed in DSC analysis was calculated. d-form is obtained 15.8% of analyzed cycles, the b-form appears 44.7% of times, and an intermediate transition between the two phases is found 39.5% of cycles.

Elevated environmental carbon dioxide (pCO2) levels have been found to cause organ damage in the early life stages of different commercial fish species, including Atlantic cod (Gadus morhua). To illuminate the underlying mechanisms causing pathologies in the intestines, the kidney, the pancreas and the liver in response to elevated pCO2, we examined related gene expression patterns in Atlantic cod reared for two months under three different pCO2 regimes: 380 μatm (control), 1800 μatm (medium) and 4200 μatm (high). We extracted RNA from whole fish sampled during the larval (32 dph) and early juvenile stage (46 dph) for relative expression analysis of 18 different genes related to essential metabolic pathways. At 32 dph, larvae subjected to the medium treatment displayed an up-regulation of genes mainly associated with fatty acid and glycogen synthesis (GYS2, 6PGL, ACoA, CPTA1, FAS and PPAR1b). Larvae exposed to the high pCO2 treatment upregulated fewer but similar genes (6PGL, ACoA and PPAR1b,). These data suggest stress-induced alterations in the lipid and fatty acid metabolism and a disrupted lipid homeostasis in larvae, providing a mechanistic link to the findings of lipid droplet overload in the liver and organ pathologies. At 46 dph, no significant differences in gene expression were detected, confirming a higher resilience of juveniles in comparison to larvae when exposed to elevated pCO2 up to 4200 μatm.

Abstract A heat pump coupled to thermal energy storage (TES) tanks is experimentally tested under simulated summer conditions and the results are presented in this paper. The cold TES tank is used for shifting the cooling load of a small house-like structure. The study evaluates the thermal behaviour of the TES tank for cold storage and the application of the system for space cooling. For the analysis, two different configurations of the tanks are compared: a water tank and a PCM tank. The PCM tank is filled with a commercial macro-encapsulated PCM, which has a phase change temperature of 10 °C. The results point out that the PCM tank is able to supply 14.5% more cold and to maintain the indoor temperature within comfort 20.65% longer than the water tank. However, it needs 4.55 times longer to charge the tank.

Abstract Life Cycle Assessment (LCA) has been conducted for seven experimental cubicles located in Puigverd de Lleida (Spain). The objective of this experimental set-up is to test different constructive solutions in order to point out the most sustainable solution with lower energy demand during the operational phase. Therefore, different building, insulation and Phase Change Materials (PCMs) have been tested under controlled temperature conditions to examine the thermal performance of the whole system. Although some of these materials are able to reduce the energy demand and consequently the environmental impact during the operational phase, they still have high embodied energy that can cause high environmental impact during the manufacturing phase. Therefore the LCA study in this paper focuses on assessing the impact of the embodied energy needed during the manufacturing and disposal phase by highlighting and comparing the effect of using different building materials, insulating materials, and phase change materials.

There remains conflicting evidence on the relationship between P supply and biological N(2)-fixation rates, particularly N(2)-fixing plant adaptive strategies under P limitation. This is important, as edaphic conditions inherent to many economically and ecologically important semi-arid leguminous tree species, such as Acacia senegal, are P deficient. Our research objective was to verify N acquisition strategies under phosphorus limitations using isotopic techniques. Acacia senegal var. senegal was cultivated in sand culture with three levels of exponentially supplied phosphorus [low (200 μmol of P seedling(-1) over 12 weeks), mid (400 μmol) and high (600 μmol)] to achieve steady-state nutrition over the growth period. Uniform additions of N were also supplied. Plant growth and nutrition were evaluated. Seedlings exhibited significantly greater total biomass under high P supply compared to low P supply. Both P and N content significantly increased with increasing P supply. Similarly, N derived from solution increased with elevated P availability. However, both the number of nodules and the N derived from atmosphere, determined by the (15)N natural abundance method, did not increase along the P gradient. Phosphorus stimulated growth and increased mineral N uptake from solution without affecting the amount of N derived from the atmosphere. We conclude that, under non-limiting N conditions, A. senegal N acquisition strategies change with P supply, with less reliance on N(2)-fixation when the rhizosphere achieves a sufficient N uptake zone.