• Energy Research
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The effect of the combined application of nano-hydroxyapatite (NHAP) or nano-carbon black (NCB) on the phytoextraction of Pb by ryegrass was investigated as an enhanced remediation technique for soils by field-scale experiment. After the addition of 0.2% NHAP or NCB to the soil, temporal variation of the uptake of Pb in aboveground parts and roots were observed. Ryegrass shoot concentrations of Pb were lower with nano-materials application than without nano-materials for the first month. However, the shoot concentrations of Pb were significantly increased with nano-materials application, in particular NHAP groups. The ryegrass root concentrations of Pb were lower with nano-materials application for the first month. These results indicated that nano-materials had significant effects on stabilization of lead, especially at the beginning of the experiment. Along with the experimental proceeding, phytotoxicity was alleviated after the incorporation of nano-materials. The ryegrass biomass was significantly higher with nano-materials application. Consequently, the Pb phytoextraction potential of ryegrass significantly increased with nano-materials application compared to the gounps without nano-materials application. The total removal rates of soil Pb were higher after combined application of NHAP than NCB. NHAP is more suitable than NCB for in-situ remediation of Pb-contaminated soils. The ryegrass translocation factor exhibited a marked increase with time. It was thought that the major role of NHP and NBA might be to alleviate the Pb phytotoxicity and increase biomass of plants.

AbstractElevated carbon-dioxide concentration [eCO2] is a key climate change factor affecting plant growth and yield. Conventionally, crop modeling work has evaluated the effect of climatic parameters on crop growth, without considering CO2. It is conjectured that a novel multimodal ensemble approach may improve the accuracy of modelled responses to eCO2. To demonstrate the applicability of a multimodel ensemble of crop models to simulation of eCO2, APSIM, CropSyst, DSSAT, EPIC and STICS were calibrated to observed data for crop phenology, biomass and yield. Significant variability in simulated biomass production was shown among the models particularly at dryland sites (44%) compared to the irrigated site (22%). Increased yield was observed for all models with the highest average yield at dryland site by EPIC (49%) and lowest under irrigated conditions (17%) by APSIM and CropSyst. For the ensemble, maximum yield was 45% for the dryland site and a minimum 22% at the irrigated site. We concluded from our study that process-based crop models have variability in the simulation of crop response to [eCO2] with greater difference under water-stressed conditions. We recommend the use of ensembles to improve accuracy in modeled responses to [eCO2].

In recent years, the accelerating climate change and intensifying natural disasters have called for more renewable, resilient, and reliable energy from more distributed sources to more diversified consumers, resulting in a pressing need for advanced situational awareness of modern smart distribution systems [...]

Land use changes from cropland to orchards in Eastern China have raised serious concerns about the regional nitrogen (N) cycle and greenhouse gas balance. We measured soil nitrous oxide (N2O) emissions and methane (CH4) uptake using manual static chambers in an apple orchard. The primary aims were to assess the effect of N fertilizer application on gas fluxes and quantify the site-specific N2O emission factor (EFd). Field experiments were arranged in a randomized block design with three N input rates (0, 800 and 2600/2000 kg N ha−1 year−1). We found that orchard soils were a negligible CH4 sink (−1.1 to −0.4 kg C ha−1 year−1). Annual N2O emissions responded positively to N input rates, ranging from 34.1 to 60.3 kg N ha−1 year−1. EFd ranged from 1.00% to 1.65% with a mean of 1.34%. The extremely large background emissions of N2O (34.1–34.3 kg N ha−1 year−1) most likely originated from nitrate accumulation in the soil profile because of historical overuse of N fertilizer. We conclude that (1) site-specific EFd is suitable for assessing regional direct N2O emissions from upland orchards; and (2) conventional fertilization regimes must be avoided, and reduced N input rates are recommended in the study region.

The phenomena of climate change transcend all national and regional boundaries. To address this complex challenge, we must determine the areas of the country of interest, in this case, Greece, that have been most adversely affected by climate. Greece is surrounded by water, and a significant part of its GDP is derived from the marine and maritime industries, including tourism. Since the start of the IntelComp project, a Preparatory Living Lab (PLL) has been planned and delivered, feeding into the development of the IntelComp platform and the Living Lab on Climate Change Adaptation. The study's results lead to the conclusion that one of the most important challenges in tackling climate change is the decarbonisation challenge, specifically the shift to renewable energy sources and the investments that must be made. Several EU and national policy frameworks, including the European Green Deal, the Climate Law, the National Long-term Strategy for 2050 (on the Climate and Energy), highlight the decarbonisation as one of the major challenges in the climate change pledge. This will be the primary subject of the IntelComp climate change case study. PLLs also led to the identification of policy questions and useful data sources to aid the IntelComp project's launch. While previous research on co-production has primarily focused on involving citizens through public participation processes in order to gain their support, trust, and insights in structured decision-making processes, our approach opens a new channel for incorporating external knowledge into problem-solving processes. The IntelComp project will aid in policy development by providing pertinent tools co-developed with the final users that will provide insights and analysis in the field of STI (Science, Technology, Innovation) encompassing all of the Energy areas mentioned above.

Abstract Egg yolk-derived P and N dual doped nano carbon capsules (PNCCs) have been synthesized and used as lithium ion battery anodes. The application of egg yolk as the carbon source is a new and environmental-friendly approach for biomass recycling. The reversible capacity of half cells made of PNCCs is as high as ~770 mA h g−1 at a current density of 0.5 A g−1 with considerable rate capacity and cycling stability. PNCCs show a capsule-like structure, which provide extra edges and active sites for lithium intercalation. The heteroatom doping also introduce defects and disorder, which increases the electrochemical activity and creates more active sites for lithium insertion.

This study aims to introduce, conceptualize, and design a novel biomass/gasification-driven hybrid energy configuration. The proposed hybrid configuration has four subsystems: reformer solid oxide fuel cell (RSOFC), biomass/gasification, homogeneous charge compression ignition engine (HCCIE) plus waste heat recovery system (WHRS). RSOFC and HCCIE systems are embedded to generate electric energy. The syngas required for these two subsystems is captured from the biomass/gasification subsystem. In addition to generating electrical energy, fuel cell is responsible for providing combustible fuel to the HCCIE subsystem. The embedded engine in the system can improve the proposed configuration efficiency by increasing the rate of electrical energy production. In addition, the dissipated heat of fuel cell and engine subsystems is recovered by WHRS. The proposed energy configuration is evaluated and discussed from energetically, exergetically and exergoeconomic and environmental aspects to obtain a comprehensive feasibility study of the plant. The offered hybrid design has new component's structure and relationships that have not been reported in the publications. The analysis indicated that the proposed hybrid configuration is capable of generating approximately 1100 kW and 366.3 W of electric and thermal power, respectively, with the overall energetic and exergetic efficiencies of 69.4% and 52.1%. Exergoeconomic analysis results revealed that the specific fuel cost of the total proposed configuration was approximately 1.96 USD per GJ. In addition, compared to a coal and petroleum oil-based power generation plants, the proposed hybrid configuration can have approximately 2.75-fold and 97.7% lower CO2 emissions, sequentially. Besides, the proposed system can rival other similar biomass-driven designs.