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Synopsis Climate change can directly and indirectly affect species distribution. Warming may allow for invasive species, such as apple snails, to migrate to higher latitudes where temperatures are more conducive to their survival and invasion success. Higher temperatures and lower pH ranges have been previously documented to affect the form and function of calcium carbonate shells, which serve many functions, including protection from predators and thermoregulation. This study aimed to quantify differences in the morphology and mechanical properties of invasive apple snail, Pomacea maculata, shells after altering temperature and pH. We mechanically tested shells among three five-week treatments: control, higher temperature, and lower pH. Ultimate Strength increased in shells that were exposed to higher temperatures, but Young’s Modulus and Peak Load did not differ among control, temperature, and pH treatments. Apple snails in higher temperature tanks increased their shell length over the five-week trials. Although snail morphometrics did not differ between sexes, male shells exhibited a higher Peak Load, Young’s Modulus, and Ultimate Strength compared to female shells. Our findings are consistent with previous gastropod studies, in that a lower pH is associated with a decrease in shell size, and higher temperatures yield larger snail shells with a higher ultimate strength. Peak Load did not significantly differ among treatments, which suggests that the cross-sectional area is relatively important when considering this species mechanical performance today and in future climates. Due to the intense nutritional and calcium demands of egg production, female snails may be more susceptible to weakened shells due to low pH environments caused by climate change.

The search for affordable high performance electrode materials in photoelectrochemical hydrogen production by solar water splitting is an ongoing quest. Hematite is a photoanode material with an electronic band gap suitable for efficient absorption of visible light in a photoelectrochemical cell (PEC). Although its poor electronic structure makes hematite a controversial candidate for PEC, it remains promising because it is an earth abundant, chemically stable and low cost material – necessary prerequisites for PEC to become a competitive cost-efficient solar fuel economy. In addition to reviewing some recent PEC research on hematite and its relevant physical and chemical characteristics, we show how hematite obtained by a low cost synthesis can be refined by hydrothermal treatment and further functionalized by coating with phycocyanin, a light harvesting protein known for photosynthesis in blue-green algae.

This work analyzes the synergy between two complementary unit operations - adsorbent dehumidification and drying - and presents a mixed integer nonlinear programming approach to optimize energy performance in a two-stage system. Combined with active constraint analysis, the adsorbent properties that promote energy performance are derived. Microporous adsorbents with higher sorption capacities at low vapor pressures and requiring higher regeneration temperatures are preferred for ambient air dehumidification in the first stage. For exhaust air dehumidification, mesoporous adsorbents with lower regeneration temperatures are preferred such that the exhaust air from the first regeneration stage can sufficiently regenerate them. For drying below 50 C, energy consumption reductions of about 70% are achieved compared to conventional dryers without adsorbent dehumidification depending on adsorbent properties. The results demonstrate the usefulness of superstructure optimization in matching the drying process with the capabilities of the adsorbents to enhance process synergy for improved energy efficiency. © 2013 American Chemical Society.

This paper aims at reviewing the life cycle assessment (LCA) literature on second generation bioethanol based on lignocellulosic biomass and at identifying issues to be resolved for good LCA practice. Reviews are carried out on respective LCA studies published over the last six years. We use the classification of lignocellulosic biomass to define system boundaries, so that the comparison among LCA results can be thoroughly assessed based on identified system components. A basis for attributing environmental burden for different biomass feedstocks is also suggested. Despite the non-homogeneous systems, we conclude that second generation bioethanol performs better than fossil fuel at least for the two most studied impact categories, net energy output and global warming. For the latter category, carbon sequestration at the biomass generation stage can even consistently offset the GHG emissions from all parts of the life cycle chains at high ethanol percentage (≥85%). The aspect of biogenic carbon and agrochemical input for energy crops and biomass residues, and the effect of removal of the latter from soil have not been treated consistently. In contrast, the exclusion of upstream chain of biomass waste feedstocks is observed in practice. The bioethanol conversion process is mostly based on simultaneous saccharification and co-fermentation, characterized by high yield and low energy input. In this regard, the LCA results tend to under estimate the real impacts of the current technology. The choice of allocation methods strongly influences the final results, particularly when economic value is used as a reference. Substitution of avoided burden seems to be the most popular allocation method in practice, followed by partition based on mass, energy, and economic values.

Synopsis Classic debates in community ecology focused on the complexities of considering an ecosystem as a super-organ or organism. New consideration of such perspectives could clarify mechanisms underlying the dynamics of forest carbon dioxide (CO2) uptake and water vapor loss, important for predicting and managing the future of Earth’s ecosystems and climate system. Here, we provide a rubric for considering ecosystem traits as aggregated, systemic, or emergent, i.e., representing the ecosystem as an aggregate of its individuals or as a metaphorical or literal super-organ or organism. We review recent approaches to scaling-up plant water relations (hydraulics) concepts developed for organs and organisms to enable and interpret measurements at ecosystem-level. We focus on three community-scale versions of water relations traits that have potential to provide mechanistic insight into climate change responses of forest CO2 and H2O gas exchange and productivity: leaf water potential (Ψcanopy), pressure volume curves (eco-PV), and hydraulic conductance (Keco). These analyses can reveal additional ecosystem-scale parameters analogous to those typically quantified for leaves or plants (e.g., wilting point and hydraulic vulnerability) that may act as thresholds in forest responses to drought, including growth cessation, mortality, and flammability. We unite these concepts in a novel framework to predict Ψcanopy and its approaching of critical thresholds during drought, using measurements of Keco and eco-PV curves. We thus delineate how the extension of water relations concepts from organ- and organism-scales can reveal the hydraulic constraints on the interaction of vegetation and climate and provide new mechanistic understanding and prediction of forest water use and productivity.

Over half of the world's forests are disturbed, and the rate at which ecosystem processes recover after disturbance is important for the services these forests can provide. We analyze the drivers' underlying changes in rates of key ecosystem processes (biomass productivity, litter productivity, actual litter decomposition, and potential litter decomposition) during secondary succession after shifting cultivation in wet tropical forest of Mexico.We test the importance of three alternative drivers of ecosystem processes: vegetation biomass (vegetation quantity hypothesis), community‐weighted trait mean (mass ratio hypothesis), and functional diversity (niche complementarity hypothesis) using structural equation modeling. This allows us to infer the relative importance of different mechanisms underlying ecosystem process recovery.Ecosystem process rates changed during succession, and the strongest driver was aboveground biomass for each of the processes. Productivity of aboveground stem biomass and leaf litter as well as actual litter decomposition increased with initial standing vegetation biomass, whereas potential litter decomposition decreased with standing biomass. Additionally, biomass productivity was positively affected by community‐weighted mean of specific leaf area, and potential decomposition was positively affected by functional divergence, and negatively by community‐weighted mean of leaf dry matter content.Our empirical results show that functional diversity and community‐weighted means are of secondary importance for explaining changes in ecosystem process rates during tropical forest succession. Instead, simply, the amount of vegetation in a site is the major driver of changes, perhaps because there is a steep biomass buildup during succession that overrides more subtle effects of community functional properties on ecosystem processes. We recommend future studies in the field of biodiversity and ecosystem functioning to separate the effects of vegetation quality (community‐weighted mean trait values and functional diversity) from those of vegetation quantity (biomass) on ecosystem processes and services.

In this paper some preliminary experimental results on a Zebra battery based propulsion system for urban bus applications are presented. The tests were carried out using a laboratory 1:1 scale test bench, composed by a 65 kW electric drive, specifically designed for urban bus applications, supplied by two 20 kWh Zebra batteries connected in parallel. The electric power train was tested on a laboratory bench, connected through a fixed ratio gear box to a 100 kW regenerative electric brake provided with speed and torque controls, in order to evaluate the propulsion system performance in steady state operative conditions. The obtained preliminary experimental results were utilized to implement a Matlab-Simulink model of urban bus, which might be powered by the same electric propulsion system studied. Thanks to this model it was possible to evaluate the dynamic behavior of the urban bus, working on standard driving cycles, taking into account the resistant forces represented by proper vehicle/road/aerodynamic parameters. An evaluation of the expected real vehicle driving range was also estimated in different road conditions.

Solar Energy Materials and Solar Cells, 116 + (2013) 176-181. doi:10.1016/j.solmat.2013.04.019