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Abstract Electricity markets in Europe become increasingly interconnected due to new grid connections and market coupling regulations. This paper examines the interdependencies between the Swiss electricity market and those of neighbouring countries. The Swiss market serves as a good example for a smaller electricity market which is increasingly affected by developments in the large neighbouring countries. To study these cross-border effects, especially those on Swiss electricity prices, we apply two different methodologies, an econometric and a Nash-Cournot equilibrium model. The analyses show that the Swiss electricity price correlates strongly with the German electricity price in the summer, but tends to follow the French electricity price in the winter. Another finding is that gas prices and the electricity load of neighbouring countries have a significant influence on prices. In particular, the load of France and Italy is driving up Swiss prices in the winter, while the German electricity demand and renewable energy generation have a larger influence on Swiss prices in the summer.

Abstract Electricity markets in Europe become increasingly interconnected due to new grid connections and market coupling regulations. This paper examines the interdependencies between the Swiss electricity market and those of neighbouring countries. The Swiss market serves as a good example for a smaller electricity market which is increasingly affected by developments in the large neighbouring countries. To study these cross-border effects, especially those on Swiss electricity prices, we apply two different methodologies, an econometric and a Nash-Cournot equilibrium model. The analyses show that the Swiss electricity price correlates strongly with the German electricity price in the summer, but tends to follow the French electricity price in the winter. Another finding is that gas prices and the electricity load of neighbouring countries have a significant influence on prices. In particular, the load of France and Italy is driving up Swiss prices in the winter, while the German electricity demand and renewable energy generation have a larger influence on Swiss prices in the summer.

An aerosol reactor was tested for the thermal reduction of ceria as part of a solar thermochemical redox cycle for producing H2 and CO from H2O and CO2. The design is based on the downward aerosol flow of ceria particles, counter to an argon sweep gas, which are rapidly heated and thermally reduced within residence times of less than 1 s. When operating in the temperature range of 1723–1873 K and at oxygen partial pressures between 5 × 10–5 and 1.2 × 10–4 atm, reduction extents of small particles (Dv50 = 12 μm) approached those predicted by thermodynamics. However, heat- and mass-transfer effects were found to limit their conversion when the ceria mass flow rate was increased above 100 mg s–1. This reactor concept inherently results in separation of the reduced ceria and evolved O2(g), operates isothermally throughout the day, and decouples the reduction and oxidation steps in both space and time for potential 24-h syngas generation.

An aerosol reactor was tested for the thermal reduction of ceria as part of a solar thermochemical redox cycle for producing H2 and CO from H2O and CO2. The design is based on the downward aerosol flow of ceria particles, counter to an argon sweep gas, which are rapidly heated and thermally reduced within residence times of less than 1 s. When operating in the temperature range of 1723–1873 K and at oxygen partial pressures between 5 × 10–5 and 1.2 × 10–4 atm, reduction extents of small particles (Dv50 = 12 μm) approached those predicted by thermodynamics. However, heat- and mass-transfer effects were found to limit their conversion when the ceria mass flow rate was increased above 100 mg s–1. This reactor concept inherently results in separation of the reduced ceria and evolved O2(g), operates isothermally throughout the day, and decouples the reduction and oxidation steps in both space and time for potential 24-h syngas generation.

Abstract Proper water management plays an essential role in the performance and durability of Polymer Electrolyte Fuel Cells (PEFCs), but it is challenged by the variety of water transport phenomena that take place in these devices. Previous experimental work has shown the existence of fluctuations between low and high current density levels in PEFCs operated with wet hydrogen and dry air feed. The alternation between both performance states is accompanied by strong changes in the high frequency resistance, suggesting a cyclic hydration and dehydration of the membrane. This peculiar scenario is examined here considering liquid water distributions from neutron imaging and predictions from a 3D two-phase non-isothermal model. The results show that the hydration-dehydration cycles are triggered by the periodic condensation and shedding of liquid water at the anode inlet. The input of liquid water humidifies the anode channel and offsets the membrane dry-out induced by the dry air stream, thus leading to the high-performance state. When liquid water is flushed out of the anode channel, the dehydration process takes over, and the cell comes back to the low-performance state. The predicted amplitude of the current oscillations grows with decreasing hydrogen and increasing air flow rates, in agreement with previous experimental data.

Abstract Proper water management plays an essential role in the performance and durability of Polymer Electrolyte Fuel Cells (PEFCs), but it is challenged by the variety of water transport phenomena that take place in these devices. Previous experimental work has shown the existence of fluctuations between low and high current density levels in PEFCs operated with wet hydrogen and dry air feed. The alternation between both performance states is accompanied by strong changes in the high frequency resistance, suggesting a cyclic hydration and dehydration of the membrane. This peculiar scenario is examined here considering liquid water distributions from neutron imaging and predictions from a 3D two-phase non-isothermal model. The results show that the hydration-dehydration cycles are triggered by the periodic condensation and shedding of liquid water at the anode inlet. The input of liquid water humidifies the anode channel and offsets the membrane dry-out induced by the dry air stream, thus leading to the high-performance state. When liquid water is flushed out of the anode channel, the dehydration process takes over, and the cell comes back to the low-performance state. The predicted amplitude of the current oscillations grows with decreasing hydrogen and increasing air flow rates, in agreement with previous experimental data.

A key concern for the safe operation of polymer electrolyte water electrolysis (PEWE) cells is the high hydrogen gas crossover that can lead to explosive hydrogen-oxygen gas mixtures. The safety aspect is especially important with thin membranes, high differential pressures and low current densities. Pt particles incorporated into the membrane catalyze the recombination of H-2 and O-2 to water and lower the content of hydrogen in the oxygen product stream. So far, different approaches have been taken for Pt distribution over the membrane's cross-section to suppress the hydrogen gas crossover: interlayer distribution, border distribution and uniform distribution. This work reports that only border-distributed Pt and uniformly-distributed Pt allow PEWE operation over a satisfying current density range for an extrapolated cathodic pressure of 30 bar(a). Uniform Pt reduction allows a 50% larger operational range than Pt deposition at the border. Further, it is found that reduction of the Pt content in the membrane from 0.06 to 0.01 mg cm(-2) does not allow satisfactory gas crossover suppression. Journal of the Electrochemical Society, 168 (10) ISSN:0013-4651 ISSN:1945-7111

A key concern for the safe operation of polymer electrolyte water electrolysis (PEWE) cells is the high hydrogen gas crossover that can lead to explosive hydrogen-oxygen gas mixtures. The safety aspect is especially important with thin membranes, high differential pressures and low current densities. Pt particles incorporated into the membrane catalyze the recombination of H-2 and O-2 to water and lower the content of hydrogen in the oxygen product stream. So far, different approaches have been taken for Pt distribution over the membrane's cross-section to suppress the hydrogen gas crossover: interlayer distribution, border distribution and uniform distribution. This work reports that only border-distributed Pt and uniformly-distributed Pt allow PEWE operation over a satisfying current density range for an extrapolated cathodic pressure of 30 bar(a). Uniform Pt reduction allows a 50% larger operational range than Pt deposition at the border. Further, it is found that reduction of the Pt content in the membrane from 0.06 to 0.01 mg cm(-2) does not allow satisfactory gas crossover suppression. Journal of the Electrochemical Society, 168 (10) ISSN:0013-4651 ISSN:1945-7111