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Hot water heat stores with stratification are a common technology used in solar energy systems and reuse of waste heat. Adding a PCM module at the top of the water tank would give the system higher storage density, and compensate heat loss in the top layer. The work presented here includes experimental results and numerical simulation of the system using an explicit finite-difference method. Experiments and simulations were carried out using different cylindrical PCM modules. With only 1/16 of the volume of the store being PCM, 3/16 of water at the top of the store was held warm for 50% to 200% longer and the average energy density was increased by 20% to 45%. Furthermore, these 3/16 of water were reheated by the heat from the module after being cooled down in only 20 min.

Searching suitable panchromatic QD sensitizers for expanding the light-harvesting range, accelerating charge separation, and retarding charge recombination is an effective way to improve power conversion efficiency (PCE) of quantum-dot-sensitized solar cells (QDSCs). One possible way to obtain a wide absorption range is to use the exciplex state of a type-II core/shell-structured QDs. In addition, this system could also provide a fast charge separation and low charge-recombination rate. Herein, we report on using a CdTe/CdSe type-II core/shell QD sensitizer with an absorption range extending into the infrared region because of its exciplex state, which is covalently linked to TiO2 mesoporous electrodes by dropping a bifunctional linker molecule mercaptopropionic acid (MPA)-capped QD aqueous solution onto the film electrode. High loading and a uniform distribution of QD sensitizer throughout the film electrode thickness have been confirmed by energy dispersive X-ray (EDX) elemental mapping. The accelerated electron injection and retarded charge-recombination pathway in the built CdTe/CdSe QD cells in comparison with reference CdSe QD-based cells have been confirmed by impedance spectroscopy, fluorescence decay, and intensity-modulated photocurrent/photovoltage spectroscopy (IMPS/IMVS) analysis. With the combination of the high QD loading and intrinsically superior optoelectronic properties of type-II core/shell QD (wide absorption range, fast charge separation, and slow charge recombination), the resulting CdTe/CdSe QD-based regenerative sandwich solar cells exhibit a record PCE of 6.76% (J(sc) = 19.59 mA cm(-2), V(oc) = 0.606 V, and FF = 0.569) with a mask around the active film under a full 1 sun illumination (simulated AM 1.5), which is the highest reported to date for liquid-junction QDSCs.

Abstract In recent years, the overall energy consumption is increasing significantly and the energy consumption in the building sector represents over 30% of the global ones in developed countries. Thermal energy storage (TES) using phase change materials (PCM), which are materials able to store high amounts of energy as latent heat, is suggested as a possible solution to decrease the energy consumption. The authors of this paper developed materials able to encapsulate/stabilize PCM in addition to isolate an industrial residue from the steel recycling process: electrical arc furnace dust (EAFD). This waste is a hazardous dust, and when it is combined with a polymeric matrix produce dense sheet materials suitable for multilayered constructive systems. In this paper the physical, mechanical, thermal and acoustical characterization of two new materials with EAFD and PCM in a polymeric matrix for constructive system is presented. The results are compared with those obtained for one commercial dense sheet material available in the market, Texsound commercialized by TEXSA (Spain). The new dense sheet materials developed in this paper have similar acoustic properties compared to the results obtained for the commercial material and are competitive with it, even better because the new material incorporates PCM which increases the thermal inertia of final constructive system.

Abstract Thermal energy storage systems for both heat and cold are necessary for many industrial processes. High energy density and high power capacity are desirable properties of the storage. The use of latent heat increases the energy density of the storage tank with high temperature control close to the melting point. Tube in PCM tank is a very promising system that provides high packing factor. This work presents an experimental study of a PCM tank for cold storage applications. Two different configurations and different flow rates of the heat transfer fluid were studied. The effectiveness of the PCM storage system was defined as that of a heat exchanger. The results showed that the heat exchange effectiveness of the system did not vary with time, decreased with increasing flow rate and increased with increasing heat transfer area. The effectiveness was experimentally determined to only be a function of the ratio m ˙ /A. This equation was found to be adequately be used to design a PCM storage system, and a case study is presented. It was shown that the tube in tank design together with a low temperature PCM is suitable as a thermal storage facility for cold storage.

A water-soluble organic redox couple (TT−/DTT) and new organic dyes (D45 and D51) have been developed for aqueous dye-sensitized solar cells (DSCs). An optimal efficiency of 3.5% was obtained using the D51 dye and an optimized electrolyte composition. The highest IPCE value obtained was 68% at 460 nm.

A commercial drum chipper was fed alternately and piecewise with poplar stems and poplar tops, in order to determine the effect of piece size and tree part on machine performance. Chipping stems required most of the available power (231 kW) delivered by the tractor, whereas chipping tops took about half that much. However, productivity was twice as high with stems, compared to tops (i.e. 25 and 11 t h-1 of oven dry wood, respectively). As a consequence, specific fuel consumption per unit product was 15% lower with stems, compared to tops - i.e. 0.61 and 0.72 L m-3, respectively. Mean feeding speed was 0.37 m s-1 for stems and 0.41 m s-1 for tops, but the difference was not significant (p = 0.1677). Productivity and fuel consumption were strongly related to piece size, but tree part had its own additional effect, independent from size and possibly related to form. When chipping tops it is advisable to feed more pieces at a time, in order to partly compensate for the effect of piece size. Operators expecting to chip primarily small-size materials may acquire special chipper versions with wider drums and additional side rollers, for smoother mass feeding. oThe same chipper was tested with poplar stems and tops.oChipping stems resulted in higher productivity and lower fuel consumption.oChipping stems required most of the available tractor power.oChip particle size distribution was about the same for both feedstocks. © 2013 Elsevier Ltd.

In Italy, olive tree groves may offer up to a million tonnes of dry biomass per year as pruning residue. Searching for a cost-effective way to tap this potential, the authors tested a new machine, capable of recovering pruning residue at the same time as pruning. The pre-commercial prototype was tested on four different plots and compared to a simpler tractorbase mechanical pruning unit. The authors conducted detailed time-studies in order to determine machine productivity and residue recovery cost. The integrated machine can treat between 0.2 and 0.6 ha h(-1), producing between 0.33 and 1.03 tonnes of fresh residue hour(-1). Its integrated residue recovery function does not slow the pruning, which actually proceeds faster than with the tractor-base unit, due to the more efficient multiple-disc cutting bar. The marginal cost of residue recovery hovers around 40-45 (sic) fresh tonne(-1). However, the new machine must not be considered just as a biomass harvester, but rather as a mechanical pruning unit with an integrated biomass recovery function. Its main benefit derives from the capacity of performing a very effective mechanical pruning, and the residue recovery function is a secondary benefit yet unavailable on standard pruning machines. Its deployment must be seen in the context of a general effort to modernize olive grove management and to develop an integrated biomass production system, rather than as a further attempt to build a specialised biomass supply chain.

Using recycled rubber crumbs as drainage layer in extensive green roofs have high potential to reduce the heating and cooling loads in buildings over traditional materials used as drainage layer, such as pozzolana gravel. However, the environmental impact due to the life cycle should be analyzed to assess its environmental benefit. This paper evaluates the environmental performance of green roofs in which the drainage layer is made of rubber crumbs, a recycled material the use of which is still experimental for this purpose. In this paper Life Cycle Assessment (LCA) is applied to compare the environmental impact of four constructive systems, two extensive green roofs without insulation layer and with different drainage materials, e a recycled material, rubber crumbs, and a conventional one, pozzolana gravel -, in front of two conventional flat roofs, with and without thermal insulation (polyurethane), built in an experimental set-up consisting of four monitored house-like cubicles, located in Mediterranean continental climate (Lleida, Spain). The LCA considered the production, construction, operational, and disposal phases of the roofs, according to UNE-EN 15643-2. The operational phase was carried out using data measured in the experimental set-up, considering heating and cooling energy consumptions in the winter and summer period, respectively.