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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

<div class="section abstract"><div class="htmlview paragraph">The introduction of new light-duty vehicle emission limits to comply under real driving conditions (RDE) is pushing the diesel engine manufacturers to identify and improve the technologies and strategies for further emission reduction. The latest technology advancements on the after-treatment systems have permitted to achieve very low emission conformity factors over the RDE, and therefore, the biggest challenge of the diesel engine development is maintaining its competitiveness in the trade-off “CO₂-system cost” in comparison to other propulsion systems. In this regard, diesel engines can continue to play an important role, in the short-medium term, to enable cost-effective compliance of CO₂-fleet emission targets, either in conventional or hybrid propulsion systems configuration. This is especially true for large-size cars, SUVs and light commercial vehicles.</div><div class="htmlview paragraph">In this framework, a comprehensive approach covering the whole powertrain is of primary importance in order to simultaneously meet the performance, efficiency, noise and emission targets, and therefore, further development of the combustion system design and injection system represent important levers for additional improvements. For this purpose, a dedicated 0.5 dm³ single-cylinder engine has been developed and equipped with, a state-of-the-art Euro 6 combustion system, and an advanced common rail fuel injection system (FIS) offering higher flexibility in terms of injection strategy and higher quantity accuracy. Three injector nozzles with different hydraulic flow rates (HF) have been selected and employed for the overall combustion process optimization.</div><div class="htmlview paragraph">The optimization has been performed by means of an extensive DoE-based test campaign in which the engine and FIS operating parameters have been parametrized with the aim to carry out a proper combination in terms of HF and injection strategy. The results at partial load conditions evidence significant advantages in applying an advanced injection pattern, while the HF reduction can significantly improve the smoke emission and combustion noise without fuel consumption penalties. Therefore, a proper combination and optimization of the HF and injection strategy can provide low noise and engine-out smoke while maintaining the rated power performance targets.</div></div>

The potential of renewable energy should be fully exploited in the transportation sector to achieve a cleaner production. Therefore, this paper proposes an on-grid hybrid hydrogen refueling and battery swapping station powered by wind energy. This novel concept can promote the development of low-carbon emission vehicles including hydrogen-based vehicle and battery electric vehicle. During the daily operation of the station, the multiple uncertainties may lead to a higher operational cost. To address this problem, a hybrid stochastic/distributionally robust optimization method is proposed to handle different uncertainties for the energy management problem. The first type of uncertainties can be depicted by a certain distribution, i.e. electricity price and wind power, which is processed by a stochastic optimization method. The second type of uncertainties is associated with human behaviors and is difficult to find its probability distribution, i.e. the hydrogen demand of hydrogen-based vehicles, so the second type is processed by a distributionally robust optimization method. The overall objective is to minimize the total operational cost of the station, which also considers the battery swapping station overstock punishment. Because a reasonable battery swapping scheduling can reduce the waiting time of users and operational cost of the station. The results indicate that the proposed method can effectively address the conservatism of solutions as its total operational cost is 4.4% lower than that of the hybrid stochastic/robust optimization method under a high confidence level.

Nanosecond-level transient electromagnetic disturbance (TED), including very fast transient overvoltage caused by operation of disconnectors, high-altitude electromagnetic pulse, and many other fast transients may interfere or even damage the electrical equipment. As one of the main overvoltage protective equipment, the protective performance of metal-oxide surge arresters (MOAs) under nanosecond-level TED should be investigated and then compared with that under microsecond-level TED, especially the lightning impulse. Based on a testing platform containing a 400-kV pulse generator with adjustable rise time from 5 to 100 ns, the behaviors of nonlinearity, fast impulse response, and converting impedances of three types of 10-kV MOAs under TED with different rise time were explored experimentally in this article. The peak residual voltages of 10-kV MOAs under TED with the rise time of 5 ns at 5 kA are 50.2–60.7% higher than those under the lightning impulse. The rise time of TED has significant influence on the peak voltage and impedance converting behaviors of MOAs. A circuit model of 10-kV MOAs under nanosecond-level TED is built and validated by experimental results, which can be applied in insulation coordination and design of protective devices against TED.

The reclosing time of a transmission line has a distinct influence on system stability. A new method of calculating the optimal reclosing time based on the transient energy function (TEF) is presented in this paper. It has been shown that an optimal reclosing time can be used to set the autoreclosing device so that the system stability or power-transfer capability can be significantly improved. Though power-system TEF is based on classical models, the results from simulation studies of a real system (46 generators and 230 buses) with complex models show that the optimal reclosing time calculated using TEF can be used effectively.

The rotary regenerator (also called the heat wheel) is an important component of energy intensive sectors, which is used in many heat recovery systems. In this paper, a model-based analysis of a rotary regenerator is carried out with a major emphasis given to the development and implementation of mathematical models for the thermal analysis of the fluid and wheel matrix. The effect of heat conduction in the direction of the fluid flow is taken into account and the influence of variations in rotating speed of the wheel as well as other characteristics (ambient temperature, airflow and geometric size) on dynamic responses are analysed. The numerical results are compared with experimental measurements and with theoretical predications of energy efficiencies. (c) 2005 Elsevier B.V. All rights reserved.

Abstract Wood pellets were pyrolyzed using a microwave oven and different microwave power, apparatus set-up and microwave absorbers (none, Fe, and carbon). Pyrolysis was realized in a short time in the presence of Fe or carbon while it was incomplete if the absorber was not present. Furthermore when the absorber was present the shape of the pellets remained unaltered while if the absorber was not employed pellets were disaggregated. Three fractions were collected from each pyrolysis: a gas, a liquid also called bio-oil and a solid called bio-char. The bio-oil contained two phases and they were quantitatively characterized through a GC/MS-FID procedure using an internal standard according to a previously reported method. HPLC/MS, FTIR and 1 H NMR spectroscopy were also employed for characterization of these liquids. Cellulose pyrolysis products were present in the upper phase such as water, acetic acid, furans (such as furfural), carbohydrates and their derivatives. Compounds from pyrolysis of lignin such as phenols and veratric acid were present in the bottom phase. The microwave assisted pyrolysis showed the possibility to efficiently convert wood pellets in different products. The main economical important components may be separated and used as chemicals, natural drugs or pesticides, while the remaining components, the solid and the gas may be used for energy production (solid and bio-oil). Solid may be also used for carbon sequestration.