- home
- Advanced Search
- Energy Research
- Embargo
- DE
- CN
- Energy Research
- Embargo
- DE
- CN
description Publicationkeyboard_double_arrow_right Article 2023Embargo end date: 21 Jul 2024Publisher:Wiley Xinyue He; Xin Jiang; Dominick V. Spracklen; Joseph Holden; Eryuan Liang; Hongyan Liu; Chongyang Xu; Jianhui Du; Kai Zhu; Paul R. Elsen; Zhenzhong Zeng;pmid: 37477066
AbstractMountain treelines are thought to be sensitive to climate change. However, how climate impacts mountain treelines is not yet fully understood as treelines may also be affected by other human activities. Here, we focus on “closed‐loop” mountain treelines (CLMT) that completely encircle a mountain and are less likely to have been influenced by human land‐use change. We detect a total length of ~916,425 km of CLMT across 243 mountain ranges globally and reveal a bimodal latitudinal distribution of treeline elevations with higher treeline elevations occurring at greater distances from the coast. Spatially, we find that temperature is the main climatic driver of treeline elevation in boreal and tropical regions, whereas precipitation drives CLMT position in temperate zones. Temporally, we show that 70% of CLMT have moved upward, with a mean shift rate of 1.2 m/year over the first decade of the 21st century. CLMT are shifting fastest in the tropics (mean of 3.1 m/year), but with greater variability. Our work provides a new mountain treeline database that isolates climate impacts from other anthropogenic pressures, and has important implications for biodiversity, natural resources, and ecosystem adaptation in a changing climate.
ZENODO arrow_drop_down Global Change BiologyArticle . 2023 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1111/gcb.16885&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen bronze 12 citations 12 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
visibility 6visibility views 6 Powered bymore_vert ZENODO arrow_drop_down Global Change BiologyArticle . 2023 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1111/gcb.16885&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Other literature type 2017Embargo end date: 02 Oct 2018 GermanyPublisher:The Electrochemical Society Zachary Lebens-Higgins; Nicholas Faenza; Pinaki Mukherjee; Shawn Sallis; Fadwa Badway; Nathalie Pereira; Christoph Schlueter; Tien-Lin Lee; Frederic Cosandey; Glenn Amatucci; Louis F.J. Piper;For layered oxide cathodes, aluminum doping has widely been shown to improve performance, particularly at high degrees of delithiation. While this has led to increased interest in Al-doped systems, including $\mathrm{LiNi_{0.8}Co_{0.15}Al_{0.05}O_{2}}$ (NCA), the aluminum surface environment has not been thoroughly investigated. Using hard x-ray photoelectron spectroscopy measurements of the Al 1s core region for NCA electrodes, we examined the evolution of the surface aluminum environment under electrochemical and thermal stress. By correlating the aluminum environment to transition metal reduction and electrolyte decomposition, we provide further insight into the cathode-electrolyte interface layer. A remarkable finding is that Al-O coatings in LiPF$_6$ electrolyte mimic the evolution observed for the aluminum surface environment in doped layered oxides. ECS transactions 80(10), 197 - 206 (2017). doi:10.1149/08010.0197ecst Published by Pennington, NJ
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1149/08010.0197ecst&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu4 citations 4 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1149/08010.0197ecst&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euapps Other research productkeyboard_double_arrow_right Other ORP type 2022 GermanyÖsterle, Ines; Ulrich, Christian; Herwartz, Sebastian; Sigle, Sebastian; Weimer, Jürgen; Conzelmann, Marcus; Fleck, Tobias; Zofka, Marc René;add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::eae4868f84e45d86dead9c15244b0739&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::eae4868f84e45d86dead9c15244b0739&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euapps Other research productkeyboard_double_arrow_right Other ORP type 2019 GermanySchröder, Matthias; Gentner, Christoph; Montaner Rios, Gema; Becker, Florian; Bleeck, Stefan; Sokolov, Igor; Kallo, Josef;add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::5b77bbd6491bc2fc839c7044aeefc276&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::5b77bbd6491bc2fc839c7044aeefc276&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euResearch data keyboard_double_arrow_right Dataset 2024Embargo end date: 30 Sep 2024Publisher:Mendeley Data Tunn, Johanna; Kalt, Tobias; Müller, Franziska; Simon, Jenny; Hennig, Jesko; Ituen, Imeh; Glatzer, Nina;- Quantitative database of risks regarding green hydrogen production for 28 prospective exporting countries in the Global South, based on publicly available soures, e.g. World Bank, IRENA, IEA, EJ Atlas. - Country sample: Algeria, Angola, Benin, Brazil, Burkina Faso, Cabo Verde, Côte d’Ivoire, DR Congo, Egypt, Gambia, Ghana, Guinea, Guinea-Bissau, Kenya, Liberia, Mauritania, Mali, Morocco, Namibia, Niger, Nigeria, Oman, Saudi Arabia, Senegal, Sierra Leone, South Africa, Togo, Tunisia. - Data sheet with comprehensive list of references and analysis framework for quantitative data - Publication: Green hydrogen transitions deepen socioecological risks and extractivist patterns: evidence from 28 prospective exporting countries in the Global South, in: Energy Research and Social Science.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.17632/4tjyh56hft.1&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.17632/4tjyh56hft.1&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2016 ItalyPublisher:Elsevier BV Funded by:EC | NASCENTEC| NASCENTManuel Schnabel; Sergi Hernández; J. López-Vidrier; Philipp Löper; Mariaconcetta Canino; B. Garrido; Caterina Summonte; Stefan Janz;The optical and photovoltaic properties of Si NCs / SiC multilayers (MLs) are investigated using a membrane-based solar cell structure. By removing the Si substrate in the active cell area, the MLs are studied without any bulk Si substrate contribution. The occurrence is confirmed by scanning electron microscopy and light-beam induced current mapping . Optical characterization combined with simulations allows us to determine the absorption within the ML absorber layer, isolated from the other cell stack layers. The results indicate that the absorption at wavelengths longer than 800 nm is only due to the SiC matrix. The measured short-circuit current is significantly lower than that theoretically obtained from absorption within the ML absorber, which is ascribed to losses that limit carrier extraction. The origin of these losses is discussed in terms of the material regions where recombination takes place. Our results indicate that carrier extraction is most efficient from the Si NCs themselves, whereas recombination is strongest in SiC and residual a-Si domains . Together with the observed onset of the external quantum efficiency (EQE) at 700-800 nm, this fact is an evidence of quantum confinement in Si NCs embedded in SiC on device level.
CNR ExploRA arrow_drop_down Solar Energy Materials and Solar CellsArticle . 2016 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.solmat.2015.10.006&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen bronze 11 citations 11 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert CNR ExploRA arrow_drop_down Solar Energy Materials and Solar CellsArticle . 2016 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.solmat.2015.10.006&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024Publisher:AIP Publishing Yiwei Hu; Benlei Wang; Zhanghua Wu; Jianying Hu; Ercang Luo; Jingyuan Xu;Thermoacoustic technology emerges as a sustainable and low-carbon method for energy conversion, leveraging environmentally friendly working mediums and independence from electricity. This study presents the development of a multimode heat-driven thermoacoustic system designed to utilize medium/low-grade heat sources for room-temperature cooling and heating. We constructed both a simulation model and an experimental prototype for a single-unit direct-coupled thermoacoustic system, exploring its performance in heating-only, cooling-only, and hybrid heating and cooling modes. Internal characteristic analysis including an examination of internal exergy loss and a distribution analysis of key parameters was first conducted in the hybrid cooling and heating mode. The results indicated a positive-focused traveling-wave-dominant acoustic field within the thermoacoustic core unit, enhancing energy conversion efficiency. The output system performance was subsequently tested under different working conditions in the heating-only and cooling-only modes. A maximum output heating power of 2.3 kW and a maximum COPh of 1.41 were observed in the heating-only mode. Meanwhile, a cooling power of 748 W and a COPc of 0.4 were obtained in the typical cooling condition at 7 °C when operating in cooling-only mode. These findings underscore the promising potential of thermoacoustic systems for efficiently utilizing medium/low-grade heat sources for cooling and/or heating applications in the future.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1063/5.0196770&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess Routesbronze 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1063/5.0196770&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2023 GermanyPublisher:Elsevier BV Authors: Herranz, Luis E.; Gabrielli, Fabrizio; Paci, Sandro;add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.anucene.2023.109834&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 1 citations 1 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.anucene.2023.109834&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024Publisher:Oxford University Press (OUP) Longzhen, Gao; Xiao, Feng; Yixuan, Zhang; Hongguang, Guo; Xiaogang, Mu; Zaixing, Huang; Michael, Urynowicz;pmid: 38849297
Abstract Biogenic coalbed methane (CBM) is a developing clean energy source. However, it is unclear how the mechanisms of bio-methane production with different sizes of coal. In this work, pulverized coal (PC) and lump coal (LC) were used for methane production by mixed fungi-methanogen microflora. The lower methane production from LC was observed. The aromatic carbon of coal was degraded slightly by 2.17% in LC, while 11.28% in PC. It is attributed to the proportion of lignin-degrading fungi, especially Penicillium, which was reached 67.57% in PC on the 7th day, higher than that of 11.38% in LC. The results suggested that the limited interaction area in LC led to microorganisms hardly utilize aromatics. It also led the accumulation of aromatic organics in the fermentation broth in PC. Increasing the reaction area of coal and facilitating the conversion of aromatic carbon are suggested means to increase methane production in situ.
FEMS Microbiology Le... arrow_drop_down FEMS Microbiology LettersArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1093/femsle/fnae037&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert FEMS Microbiology Le... arrow_drop_down FEMS Microbiology LettersArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1093/femsle/fnae037&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2023 GermanyPublisher:Karlsruher Institut für Technologie (KIT) Authors: Gracia, Lisa Lou;Künstliche Photosynthese ist ein chemischer Prozess, der darauf abzielt, die natürliche Photosynthese nachzuahmen, indem CO₂ nur unter Verwendung von Sonnenenergie in wertvolle Rohstoffe umgewandelt wird. Es bietet eine Chance, die ökologischen und ökonomischen Probleme zu beantworten, die mit dem gestörten Kohlenstoffkreislauf verbunden sind und der für den Klimawandel verantwortlich ist. Die ersten künstlichen Photosynthesesysteme wurden in den frühen 80er Jahren von LEHN und Mitarbeitern eingeführt und haben seitdem beträchtliche Aufmerksamkeit auf sich gezogen. Um die verschiedenen Schritte der natürlichen Photosynthese nachzuahmen, kombinieren die beschriebenen homogenen Systeme ein lichtsammelndes Molekül (Photosensibilisator, PS), einen metallhaltigen Katalysator, der in der Lage ist, mit CO₂ zu reagieren und es zu reduzieren, sowie Protonen- und Elektronenquellen, um die Umwandlung von CO₂ in C1-Bausteine zu ermöglichen (Kohlenmonoxid, Formiate, Methanol, Methan). Erst kürzlich wurden unedle Metalle in die Strukturen integriert, um die seltenen und teuren Edelmetalle zu ersetzen, wodurch die Systeme nachhaltiger und kostengünstiger wurden. Ihre unterschiedliche Reaktivität erfordert jedoch ein gründliches Verständnis der beteiligten Mechanismen sowie ein spezifisches Ligandendesign und angepasste Reaktionsbedingungen. In dieser Dissertation wurden neue Komplexe auf Übergangsmetallbasis für die photokatalytische Reduktion von CO₂ hauptsächlich zu CO und H₂ als Nebenprodukt entworfen. Im ersten Projekt wurde ein System mit dem bekannten und leichtverfügbaren Ni(cyclam)Cl₂ als Katalysator in Kombination mit neuen CuI-basierten Photosensibilisatoren entworfen. Das System wurde optimiert und produzierte selektiv CO mit einer TON von 8, wenn der bimetallische CuI-Komplex PS-4 als PS mit einer Quanteneffizienz von 2,1% verwendet wurde. Diese Ergebnisse gehören zu den höchsten, die mit Ni(cyclam)Cl₂ als Katalysator berichtet wurden, der zum ersten Mal mit einem unedlen Metall als PS in Verbindung gebracht wurde, was zeigt, dass Edelmetalle ersetzt werden können. In einem zweiten Schritt wurden neue auf unedlen Metallen-basierte einkernige Katalysatoren für die photokatalytische CO₂-Reduktion mit 2,6-Bis(1,2,3-triazol-yl-methyl)pyridin-Ligandenstrukturen entworfen, aus denen ein bestimmter Eisenkomplex hervorstich. Er produzierte CO mit einer TON von 576 und einer Quanteneffizienz von 7,1% in Kombination mit einem CuI-Photosensibilisator. Seine Aktivität als Katalysator wurde untersucht und ein katalytischer Mechanismus vorgeschlagen. Die Umwandlung des Phenylliganden in ein Chinolin ermöglichte die Bildung eines zweikernigen Kobaltkomplexes, der bei Verwendung als Katalysator dreimal mehr CO produzierte als sein einkerniges Analogon. Dies erlaubte die Annahme eines kooperativen Effekts zwischen den beiden Metallen. Ein anderer Syntheseansatz führte zur Bildung eines trimetallischen Eisenkomplexes, dessen Eigenschaften untersucht und beschrieben wurden. Weder seine magnetischen Eigenschaften noch seine Verwendung als Katalysator für die CO₂-Reduktion zeigten das Vorhandensein von Kooperativitätseffekten zwischen den Metallen. Schließlich wurde das Design von Multimetall-Photokatalysatoren untersucht, die einen Photosensibilisator und einen Katalysator im selben Molekül kombinieren. Aus den Synthesewegen gingen jedoch nur einkernige Komplexe hervor, die interessante katalytische Aktivitäten zeigten.
https://dx.doi.org/1... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Doctoral thesis . 2023Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5445/ir/1000161470&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert https://dx.doi.org/1... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Doctoral thesis . 2023Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5445/ir/1000161470&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu
description Publicationkeyboard_double_arrow_right Article 2023Embargo end date: 21 Jul 2024Publisher:Wiley Xinyue He; Xin Jiang; Dominick V. Spracklen; Joseph Holden; Eryuan Liang; Hongyan Liu; Chongyang Xu; Jianhui Du; Kai Zhu; Paul R. Elsen; Zhenzhong Zeng;pmid: 37477066
AbstractMountain treelines are thought to be sensitive to climate change. However, how climate impacts mountain treelines is not yet fully understood as treelines may also be affected by other human activities. Here, we focus on “closed‐loop” mountain treelines (CLMT) that completely encircle a mountain and are less likely to have been influenced by human land‐use change. We detect a total length of ~916,425 km of CLMT across 243 mountain ranges globally and reveal a bimodal latitudinal distribution of treeline elevations with higher treeline elevations occurring at greater distances from the coast. Spatially, we find that temperature is the main climatic driver of treeline elevation in boreal and tropical regions, whereas precipitation drives CLMT position in temperate zones. Temporally, we show that 70% of CLMT have moved upward, with a mean shift rate of 1.2 m/year over the first decade of the 21st century. CLMT are shifting fastest in the tropics (mean of 3.1 m/year), but with greater variability. Our work provides a new mountain treeline database that isolates climate impacts from other anthropogenic pressures, and has important implications for biodiversity, natural resources, and ecosystem adaptation in a changing climate.
ZENODO arrow_drop_down Global Change BiologyArticle . 2023 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1111/gcb.16885&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen bronze 12 citations 12 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
visibility 6visibility views 6 Powered bymore_vert ZENODO arrow_drop_down Global Change BiologyArticle . 2023 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1111/gcb.16885&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Other literature type 2017Embargo end date: 02 Oct 2018 GermanyPublisher:The Electrochemical Society Zachary Lebens-Higgins; Nicholas Faenza; Pinaki Mukherjee; Shawn Sallis; Fadwa Badway; Nathalie Pereira; Christoph Schlueter; Tien-Lin Lee; Frederic Cosandey; Glenn Amatucci; Louis F.J. Piper;For layered oxide cathodes, aluminum doping has widely been shown to improve performance, particularly at high degrees of delithiation. While this has led to increased interest in Al-doped systems, including $\mathrm{LiNi_{0.8}Co_{0.15}Al_{0.05}O_{2}}$ (NCA), the aluminum surface environment has not been thoroughly investigated. Using hard x-ray photoelectron spectroscopy measurements of the Al 1s core region for NCA electrodes, we examined the evolution of the surface aluminum environment under electrochemical and thermal stress. By correlating the aluminum environment to transition metal reduction and electrolyte decomposition, we provide further insight into the cathode-electrolyte interface layer. A remarkable finding is that Al-O coatings in LiPF$_6$ electrolyte mimic the evolution observed for the aluminum surface environment in doped layered oxides. ECS transactions 80(10), 197 - 206 (2017). doi:10.1149/08010.0197ecst Published by Pennington, NJ
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1149/08010.0197ecst&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu4 citations 4 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1149/08010.0197ecst&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euapps Other research productkeyboard_double_arrow_right Other ORP type 2022 GermanyÖsterle, Ines; Ulrich, Christian; Herwartz, Sebastian; Sigle, Sebastian; Weimer, Jürgen; Conzelmann, Marcus; Fleck, Tobias; Zofka, Marc René;add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::eae4868f84e45d86dead9c15244b0739&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::eae4868f84e45d86dead9c15244b0739&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euapps Other research productkeyboard_double_arrow_right Other ORP type 2019 GermanySchröder, Matthias; Gentner, Christoph; Montaner Rios, Gema; Becker, Florian; Bleeck, Stefan; Sokolov, Igor; Kallo, Josef;add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::5b77bbd6491bc2fc839c7044aeefc276&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______1640::5b77bbd6491bc2fc839c7044aeefc276&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euResearch data keyboard_double_arrow_right Dataset 2024Embargo end date: 30 Sep 2024Publisher:Mendeley Data Tunn, Johanna; Kalt, Tobias; Müller, Franziska; Simon, Jenny; Hennig, Jesko; Ituen, Imeh; Glatzer, Nina;- Quantitative database of risks regarding green hydrogen production for 28 prospective exporting countries in the Global South, based on publicly available soures, e.g. World Bank, IRENA, IEA, EJ Atlas. - Country sample: Algeria, Angola, Benin, Brazil, Burkina Faso, Cabo Verde, Côte d’Ivoire, DR Congo, Egypt, Gambia, Ghana, Guinea, Guinea-Bissau, Kenya, Liberia, Mauritania, Mali, Morocco, Namibia, Niger, Nigeria, Oman, Saudi Arabia, Senegal, Sierra Leone, South Africa, Togo, Tunisia. - Data sheet with comprehensive list of references and analysis framework for quantitative data - Publication: Green hydrogen transitions deepen socioecological risks and extractivist patterns: evidence from 28 prospective exporting countries in the Global South, in: Energy Research and Social Science.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.17632/4tjyh56hft.1&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.17632/4tjyh56hft.1&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2016 ItalyPublisher:Elsevier BV Funded by:EC | NASCENTEC| NASCENTManuel Schnabel; Sergi Hernández; J. López-Vidrier; Philipp Löper; Mariaconcetta Canino; B. Garrido; Caterina Summonte; Stefan Janz;The optical and photovoltaic properties of Si NCs / SiC multilayers (MLs) are investigated using a membrane-based solar cell structure. By removing the Si substrate in the active cell area, the MLs are studied without any bulk Si substrate contribution. The occurrence is confirmed by scanning electron microscopy and light-beam induced current mapping . Optical characterization combined with simulations allows us to determine the absorption within the ML absorber layer, isolated from the other cell stack layers. The results indicate that the absorption at wavelengths longer than 800 nm is only due to the SiC matrix. The measured short-circuit current is significantly lower than that theoretically obtained from absorption within the ML absorber, which is ascribed to losses that limit carrier extraction. The origin of these losses is discussed in terms of the material regions where recombination takes place. Our results indicate that carrier extraction is most efficient from the Si NCs themselves, whereas recombination is strongest in SiC and residual a-Si domains . Together with the observed onset of the external quantum efficiency (EQE) at 700-800 nm, this fact is an evidence of quantum confinement in Si NCs embedded in SiC on device level.
CNR ExploRA arrow_drop_down Solar Energy Materials and Solar CellsArticle . 2016 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.solmat.2015.10.006&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen bronze 11 citations 11 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert CNR ExploRA arrow_drop_down Solar Energy Materials and Solar CellsArticle . 2016 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.solmat.2015.10.006&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024Publisher:AIP Publishing Yiwei Hu; Benlei Wang; Zhanghua Wu; Jianying Hu; Ercang Luo; Jingyuan Xu;Thermoacoustic technology emerges as a sustainable and low-carbon method for energy conversion, leveraging environmentally friendly working mediums and independence from electricity. This study presents the development of a multimode heat-driven thermoacoustic system designed to utilize medium/low-grade heat sources for room-temperature cooling and heating. We constructed both a simulation model and an experimental prototype for a single-unit direct-coupled thermoacoustic system, exploring its performance in heating-only, cooling-only, and hybrid heating and cooling modes. Internal characteristic analysis including an examination of internal exergy loss and a distribution analysis of key parameters was first conducted in the hybrid cooling and heating mode. The results indicated a positive-focused traveling-wave-dominant acoustic field within the thermoacoustic core unit, enhancing energy conversion efficiency. The output system performance was subsequently tested under different working conditions in the heating-only and cooling-only modes. A maximum output heating power of 2.3 kW and a maximum COPh of 1.41 were observed in the heating-only mode. Meanwhile, a cooling power of 748 W and a COPc of 0.4 were obtained in the typical cooling condition at 7 °C when operating in cooling-only mode. These findings underscore the promising potential of thermoacoustic systems for efficiently utilizing medium/low-grade heat sources for cooling and/or heating applications in the future.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1063/5.0196770&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess Routesbronze 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1063/5.0196770&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2023 GermanyPublisher:Elsevier BV Authors: Herranz, Luis E.; Gabrielli, Fabrizio; Paci, Sandro;add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.anucene.2023.109834&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 1 citations 1 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.anucene.2023.109834&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024Publisher:Oxford University Press (OUP) Longzhen, Gao; Xiao, Feng; Yixuan, Zhang; Hongguang, Guo; Xiaogang, Mu; Zaixing, Huang; Michael, Urynowicz;pmid: 38849297
Abstract Biogenic coalbed methane (CBM) is a developing clean energy source. However, it is unclear how the mechanisms of bio-methane production with different sizes of coal. In this work, pulverized coal (PC) and lump coal (LC) were used for methane production by mixed fungi-methanogen microflora. The lower methane production from LC was observed. The aromatic carbon of coal was degraded slightly by 2.17% in LC, while 11.28% in PC. It is attributed to the proportion of lignin-degrading fungi, especially Penicillium, which was reached 67.57% in PC on the 7th day, higher than that of 11.38% in LC. The results suggested that the limited interaction area in LC led to microorganisms hardly utilize aromatics. It also led the accumulation of aromatic organics in the fermentation broth in PC. Increasing the reaction area of coal and facilitating the conversion of aromatic carbon are suggested means to increase methane production in situ.
FEMS Microbiology Le... arrow_drop_down FEMS Microbiology LettersArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1093/femsle/fnae037&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert FEMS Microbiology Le... arrow_drop_down FEMS Microbiology LettersArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1093/femsle/fnae037&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2023 GermanyPublisher:Karlsruher Institut für Technologie (KIT) Authors: Gracia, Lisa Lou;Künstliche Photosynthese ist ein chemischer Prozess, der darauf abzielt, die natürliche Photosynthese nachzuahmen, indem CO₂ nur unter Verwendung von Sonnenenergie in wertvolle Rohstoffe umgewandelt wird. Es bietet eine Chance, die ökologischen und ökonomischen Probleme zu beantworten, die mit dem gestörten Kohlenstoffkreislauf verbunden sind und der für den Klimawandel verantwortlich ist. Die ersten künstlichen Photosynthesesysteme wurden in den frühen 80er Jahren von LEHN und Mitarbeitern eingeführt und haben seitdem beträchtliche Aufmerksamkeit auf sich gezogen. Um die verschiedenen Schritte der natürlichen Photosynthese nachzuahmen, kombinieren die beschriebenen homogenen Systeme ein lichtsammelndes Molekül (Photosensibilisator, PS), einen metallhaltigen Katalysator, der in der Lage ist, mit CO₂ zu reagieren und es zu reduzieren, sowie Protonen- und Elektronenquellen, um die Umwandlung von CO₂ in C1-Bausteine zu ermöglichen (Kohlenmonoxid, Formiate, Methanol, Methan). Erst kürzlich wurden unedle Metalle in die Strukturen integriert, um die seltenen und teuren Edelmetalle zu ersetzen, wodurch die Systeme nachhaltiger und kostengünstiger wurden. Ihre unterschiedliche Reaktivität erfordert jedoch ein gründliches Verständnis der beteiligten Mechanismen sowie ein spezifisches Ligandendesign und angepasste Reaktionsbedingungen. In dieser Dissertation wurden neue Komplexe auf Übergangsmetallbasis für die photokatalytische Reduktion von CO₂ hauptsächlich zu CO und H₂ als Nebenprodukt entworfen. Im ersten Projekt wurde ein System mit dem bekannten und leichtverfügbaren Ni(cyclam)Cl₂ als Katalysator in Kombination mit neuen CuI-basierten Photosensibilisatoren entworfen. Das System wurde optimiert und produzierte selektiv CO mit einer TON von 8, wenn der bimetallische CuI-Komplex PS-4 als PS mit einer Quanteneffizienz von 2,1% verwendet wurde. Diese Ergebnisse gehören zu den höchsten, die mit Ni(cyclam)Cl₂ als Katalysator berichtet wurden, der zum ersten Mal mit einem unedlen Metall als PS in Verbindung gebracht wurde, was zeigt, dass Edelmetalle ersetzt werden können. In einem zweiten Schritt wurden neue auf unedlen Metallen-basierte einkernige Katalysatoren für die photokatalytische CO₂-Reduktion mit 2,6-Bis(1,2,3-triazol-yl-methyl)pyridin-Ligandenstrukturen entworfen, aus denen ein bestimmter Eisenkomplex hervorstich. Er produzierte CO mit einer TON von 576 und einer Quanteneffizienz von 7,1% in Kombination mit einem CuI-Photosensibilisator. Seine Aktivität als Katalysator wurde untersucht und ein katalytischer Mechanismus vorgeschlagen. Die Umwandlung des Phenylliganden in ein Chinolin ermöglichte die Bildung eines zweikernigen Kobaltkomplexes, der bei Verwendung als Katalysator dreimal mehr CO produzierte als sein einkerniges Analogon. Dies erlaubte die Annahme eines kooperativen Effekts zwischen den beiden Metallen. Ein anderer Syntheseansatz führte zur Bildung eines trimetallischen Eisenkomplexes, dessen Eigenschaften untersucht und beschrieben wurden. Weder seine magnetischen Eigenschaften noch seine Verwendung als Katalysator für die CO₂-Reduktion zeigten das Vorhandensein von Kooperativitätseffekten zwischen den Metallen. Schließlich wurde das Design von Multimetall-Photokatalysatoren untersucht, die einen Photosensibilisator und einen Katalysator im selben Molekül kombinieren. Aus den Synthesewegen gingen jedoch nur einkernige Komplexe hervor, die interessante katalytische Aktivitäten zeigten.
https://dx.doi.org/1... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Doctoral thesis . 2023Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5445/ir/1000161470&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert https://dx.doi.org/1... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Doctoral thesis . 2023Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5445/ir/1000161470&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu