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This study introduces novel phenothiazine-based organic dyes, 2-LBH-100, 2-LBH-44, and 2-Ryu-4, specifically designed for quasi-solid-state dye-sensitized solar cells (QsDSSCs). Employing a donor-π-acceptor architecture, these dyes incorporate varying electron-donating moieties, including bis(3-(hexyloxy)phenyl)amine and diphenylamino, coupled with a cyanoacrylic acid acceptor. Alkoxy substitutions in 2-LBH-100 and 2-LBH-44 enhanced solubility and dye loading on TiO2, leading to improved performance in QsDSSCs. 2-LBH-100 exhibited a power conversion efficiency (PCE) exceeding 5% with excellent stability, while 2-LBH-44 demonstrated a PCE of over 3%, increasing to 4% over time. 2-Ryu-4, with its diphenylamino donor, achieved an initial PCE of over 6%. This research highlights the crucial role of donor–acceptor interactions in optimizing organic dye design for high-performance QsDSSCs, paving the way for efficient and stable next-generation solar energy technologies.

This study introduces novel phenothiazine-based organic dyes, 2-LBH-100, 2-LBH-44, and 2-Ryu-4, specifically designed for quasi-solid-state dye-sensitized solar cells (QsDSSCs). Employing a donor-π-acceptor architecture, these dyes incorporate varying electron-donating moieties, including bis(3-(hexyloxy)phenyl)amine and diphenylamino, coupled with a cyanoacrylic acid acceptor. Alkoxy substitutions in 2-LBH-100 and 2-LBH-44 enhanced solubility and dye loading on TiO2, leading to improved performance in QsDSSCs. 2-LBH-100 exhibited a power conversion efficiency (PCE) exceeding 5% with excellent stability, while 2-LBH-44 demonstrated a PCE of over 3%, increasing to 4% over time. 2-Ryu-4, with its diphenylamino donor, achieved an initial PCE of over 6%. This research highlights the crucial role of donor–acceptor interactions in optimizing organic dye design for high-performance QsDSSCs, paving the way for efficient and stable next-generation solar energy technologies.

The paper presents a preliminary technical-economic comparison between a 3 kV DC railway and the use of trains with on-board storage systems. Numerical simulations have been carried out on a real railway line, which presents an electrified section at 3 kV DC and a non-electrified section, currently covered by diesel-powered trains. Different types of ESS have been analyzed, implementing the models in Matlab/Simulink environment. A preparatory economic investigation has been carried out.

The paper presents a preliminary technical-economic comparison between a 3 kV DC railway and the use of trains with on-board storage systems. Numerical simulations have been carried out on a real railway line, which presents an electrified section at 3 kV DC and a non-electrified section, currently covered by diesel-powered trains. Different types of ESS have been analyzed, implementing the models in Matlab/Simulink environment. A preparatory economic investigation has been carried out.

To study the heating performance of a solar-assisted cold-water phase-change-energy heat pump system, its heating performance under series and parallel connections is simulated for a community in Harbin, the influence of ice thickness on the different operation modes is analyzed, and the economy of the system is calculated for series and parallel connections in this paper. The results show that the water supply temperature is higher and more uniform in the parallel operation, and more terminal heat is supplied; the ice thickness has more of an influence on the series connection compared to the parallel connection; and the dynamic payback period is 6.72 years for the series connection and 7.28 years for the parallel connection. This case study can serve as a guide for practical engineering application projects and act as a reference for heating and economic data for the promotion of this heat pump system.

To study the heating performance of a solar-assisted cold-water phase-change-energy heat pump system, its heating performance under series and parallel connections is simulated for a community in Harbin, the influence of ice thickness on the different operation modes is analyzed, and the economy of the system is calculated for series and parallel connections in this paper. The results show that the water supply temperature is higher and more uniform in the parallel operation, and more terminal heat is supplied; the ice thickness has more of an influence on the series connection compared to the parallel connection; and the dynamic payback period is 6.72 years for the series connection and 7.28 years for the parallel connection. This case study can serve as a guide for practical engineering application projects and act as a reference for heating and economic data for the promotion of this heat pump system.

Lithium-ion batteries exhibit a dynamic voltage behaviour depending nonlinearly on current and state of charge. The modelling of lithium-ion batteries is therefore complicated and model parametrisation is often time demanding. Grey-box models combine physical and data-driven modelling to benefit from their respective advantages. Neural ordinary differential equations (NODEs) offer new possibilities for grey-box modelling. Differential equations given by physical laws and NODEs can be combined in a single modelling framework. Here we demonstrate the use of NODEs for grey-box modelling of lithium-ion batteries. A simple equivalent circuit model serves as a basis and represents the physical part of the model. The voltage drop over the resistor–capacitor circuit, including its dependency on current and state of charge, is implemented as a NODE. After training, the grey-box model shows good agreement with experimental full-cycle data and pulse tests on a lithium iron phosphate cell. We test the model against two dynamic load profiles: one consisting of half cycles and one dynamic load profile representing a home-storage system. The dynamic response of the battery is well captured by the model.