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AbstractRevolutionary changes in energy storage technology have put forward higher requirements on next‐generation anode materials for lithium‐ion battery. Recently, a new class of materials with complex stoichiometric ratios, high‐entropy oxide (HEO), has gradually emerging into sight and embracing the prosperity. The ideal elemental adjustability and attractive synergistic effect make HEO promising to break through the integrated performance bottleneck of conventional anodes and provide new impetus for the design and development of electrochemical energy storage materials. Here, the research progress of HEO anodes is comprehensively reviewed. The driving force behind phase stability, the role of individual cations, potential mechanisms for controlling properties, as well as state‐of‐the‐art synthetic strategies and modification approaches are critically evaluated. Finally, we envision the future prospects and related challenges in this field, which will bring some enlightening guidance and criteria for researchers to further unlock the mysteries of HEO anodes.image

In the water-rich karst regions, high water and mud outbursts are common geological disasters in tunnel construction. To ensure the safe and smooth construction of tunnel projects, it is necessary to consider anti-water pressure, water inrush prevention and geological disasters during the design of tunnels. Based on the Yongfutun Tunnel Project, this paper studies the application and effect of radial grouting and curtain grouting, which involves those in high-water-pressure tunnels under double-layer support conditions. To obtain the effects and parameters of radial grouting and curtain grouting, the influences of different grouting ranges on the tunnel’s surrounding rocks and supporting structures were analyzed and the finite difference method was adopted. The results show that the radial grouting of the surrounding rock can notably improve the initial support of the tunnel, but the impact is less obvious when the grouting range exceeds 4 m. The design of radial grouting is recommended to be 4.0 m to 4.5 m. Curtain grouting can effectively reduce the external water pressure of the tunnel lining. The external water pressure of the grouting area is 23% greater than that without curtain grouting. Curtain grouting can slow down the infiltration of external water pressure. This is beneficial to the stress of the tunnel lining structure, but the improvement in initial support force is slight. Moreover, curtain grouting improves the safety reserve of the secondary lining by strengthening the self-stability ability of the surrounding rock. Meanwhile, the double-layer primary support can effectively share the external water pressure and surrounding rock pressure. This study provides a certain reference for the lining design of high-water-pressure tunnels.

Abstract This paper presented a novel method of dissipating solar photovoltaic heat based on the technology of micro-heat-pipe array and the utilization of photovoltaic-cell waste heat. This novel technology solved the problems of low PV electrical efficiency and thermal failure caused by high cell temperature, greatly increased the comprehensive utilization efficiency of solar energy, and extended the service life of photovoltaic modules. One-year experiments were conducted to investigate the electrical and thermal performance of a forced-circulation, household-type photovoltaic/thermal system based on micro-heat-pipe array in Beijing, China. Test results showed that on the four typical days in different seasons, the average electrical efficiencies were 13.76%, 11.92%, 13.71%, and 14.65%; the average thermal efficiencies were 31.62%, 33.07%, 24.99%, and 17.24%; and the average total efficiencies were 45.38%, 44.99%, 38.70%, 31.89%, respectively. The system met the demand of power supply on sunny days and the demand of hot water between March and November, except in cloudy days. These experimental results can provide basis and reference for practical applications of the system.

Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

The hydraulic balance of heating network is considered as a pre-condition for the implementation of low temperature district heating (LTDH). Its imbalance result into high energy consumption and heat-losses in the network. In this study, a novel hydraulic model is presented which investigates hydraulic imbalance in the LTDH network, using real weather and hourly monitored operational heating data from an existing boiler based building. Analysis of delta t in space-heating system shows that the delta t is maximum when the outside air temperature is lowest and it decreases with increase in outside air temperature. Furthermore, the hydraulic imbalance is analysed for four different control scenarios with the aim to find an optimum scenario with minimum pumping power, energy consumption and heat-losses in the LTDH network. Results show that the hydraulic imbalance is due to the absence of flow-limiters and balancing valves on the return pipe and thermostatic radiator valves (TRVs) alone are unable to maintain hydraulic balance in the space-heating system of buildings. Moreover, the control scenario with variable flow-rate and fixed supply water temperature from the sub-station is found to be optimum. Compared to the constant flow-rate scenario, the pumping power, energy consumption and heat-losses in the LTDH network are reduced by approximately 2%, 63% and 14%, respectively.

Abstract In a passive nuclear plant, the main control room must provide self-support functions for 72 h after an accident occurs. In this isolation mode, the heat generated by indoor occupants and equipment should be removed by using concrete walls that are 610 mm thick, and the finned ceiling made of concrete should maintain thermal habitability. However, the finned ceiling design has not been studied in normal buildings, and the cooling storage effect of plate-shaped fins is usually ignored during the design phase. In this study, a novel parametric resistance–capacitance thermal network is proposed to simulate the thermal performance of different fin-plate layout forms in the case of an accident. An experiment was conducted on a 1200 mm × 1200 mm × 610 mm fin-concrete module for 72 h to validate the model under constant air temperature conditions. Based on the model, multi-objective optimization was conducted to obtain optimal solution sets by using a radial basis function approximation model. The results show that the optimal performance indicators can be classified into unsteady and quasi-steady states, in which the dominant factors for heat transfer include the heat transfer area and the thickness of the finned plate, respectively. Further, the optimal solution sets for different convection and heating conditions obtained through an optimization process are used to design a fin layout based on actual temperature control demands and cooling storage.

In grounding fault of DC system, overvoltage will appear on equipment nodes in converter station. Due to different operation mode and equipment type, it is very different from overvoltage in AC system. Based on Shanghaimiao–Linyi​ ±800kV Ultra High Voltage Direct Current (UHVDC) transmission project, this paper studies the converter station overvoltage characteristics under the conditions of DC pole line grounding, DC bus grounding and converter transformer valve side grounding fault, then analyzes the influence of smoothing reactor, filter capacitor and grounding pole line on overvoltage. In grounding fault at DC pole line near the converter station, the maximum overvoltage occurs on the inductance of DC filter, which is 592.75kV; In grounding fault at the top of the high voltage converter valve, the maximum overvoltage occurs on the neutral bus, which is 272.17kV. Increasing the inductance or capacitance of the smoothing reactor and filter capacitor, shortening the length of grounding electrode wire can significantly reduce the amplitude and steepness of overvoltage. The calculation results provide a reference for the internal overvoltage suppression of DC converter station with layered access at the inverter side.

The steady-state phase distribution and the structural parameters have been taken as the input for the nuclear physics calculation in the ADS windowless spallation target. The distribution of the extreme large power density of the heat load is imported back as the source term in the energy equation. Then temperature distribution is obtained based on the flow process and heat transfer. The preliminary results show that the temperature distribution reaches the steady-state and its shape is like the broken wings of the butterfly. This is very important for the further design and optimization of the ADS windowless spallation target. So the two-way coupling simulation of the heat transfer process is successfully performed between the computational fluid dynamics and the nuclear physics simulation.