• Energy Research
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This study introduces novel phenothiazine-based organic dyes, 2-LBH-100, 2-LBH-44, and 2-Ryu-4, specifically designed for quasi-solid-state dye-sensitized solar cells (QsDSSCs). Employing a donor-π-acceptor architecture, these dyes incorporate varying electron-donating moieties, including bis(3-(hexyloxy)phenyl)amine and diphenylamino, coupled with a cyanoacrylic acid acceptor. Alkoxy substitutions in 2-LBH-100 and 2-LBH-44 enhanced solubility and dye loading on TiO2, leading to improved performance in QsDSSCs. 2-LBH-100 exhibited a power conversion efficiency (PCE) exceeding 5% with excellent stability, while 2-LBH-44 demonstrated a PCE of over 3%, increasing to 4% over time. 2-Ryu-4, with its diphenylamino donor, achieved an initial PCE of over 6%. This research highlights the crucial role of donor–acceptor interactions in optimizing organic dye design for high-performance QsDSSCs, paving the way for efficient and stable next-generation solar energy technologies.

To study the heating performance of a solar-assisted cold-water phase-change-energy heat pump system, its heating performance under series and parallel connections is simulated for a community in Harbin, the influence of ice thickness on the different operation modes is analyzed, and the economy of the system is calculated for series and parallel connections in this paper. The results show that the water supply temperature is higher and more uniform in the parallel operation, and more terminal heat is supplied; the ice thickness has more of an influence on the series connection compared to the parallel connection; and the dynamic payback period is 6.72 years for the series connection and 7.28 years for the parallel connection. This case study can serve as a guide for practical engineering application projects and act as a reference for heating and economic data for the promotion of this heat pump system.

Accurate estimation of State-of-Charge (SoC) is essential for ensuring the safe and efficient operation of electric vehicles (EVs). Currently, second-order RC equivalent circuit models do not account for the influence of battery charging and discharging states on battery parameters. Additionally, offline parameter identification becomes inaccurate as the battery ages. Online identification requires real-time parameter updates during the SoC estimation process, which increases the computational complexity and reduces the computational efficiency of real vehicle Battery Management System (BMS) chips. To address these issues, this paper proposes a SoC estimation method that combines online and offline identification based on an optimized second-order RC equivalent circuit model, which distinguishes it from existing methods in the field. On the basis of the traditional second-order RC model, the Ohmic resistance (R0), polarization resistance (R1), polarization capacitance (C1), diffusion resistance (R2), and diffusion capacitance (C2) during the charging and discharging processes are discussed separately. R0, which does not change frequently, is identified offline, while R1, R2, C1, and C2, which dynamically change with time and current, are identified online. To thoroughly verify the feasibility of the proposed method, we construct an SoC estimation test bench, which allows us to adjust the battery’s surface temperature in real time using a temperature control chamber. Experimental validation under Federal Urban Driving Schedule (FUDS) (−10 °C to 45 °C, 80% battery capacity) and Dynamic Stress Test (DST) (−10 °C to 45 °C, 8% battery capacity) conditions demonstrate that our method improves SoC estimation accuracy by 16.28% under FUDS and 28.2% under DST compared to the improved GRU-based transfer learning method, while maintaining system SoC estimation efficiency.

Vehicle speed prediction plays a critical role in energy management strategy (EMS). Based on the adaptive particle swarm optimization–least squares support vector machine (APSO-LSSVM) algorithm with BP neural network (BPNN), a novel closed-loop vehicle speed prediction system is proposed. The database of a vehicle internet platform was adopted to construct a speed prediction model based on the APSO-LSSVM algorithm. Furthermore, a BPNN is established according to the local high-precision nonlinear fitting relationship between the predicted value and error so as to correct the prediction value. Then, the results are returned to the APSO-LSSVM model for calculating the minimum fitness function, thus obtaining a closed-loop prediction system. Finally, equivalent fuel consumption minimization strategy (ECMS) based EMS was performed. According to the simulation results, the RMSE performance is 0.831 km/h within 5 s, which is over 20% higher than other performances. Additionally, the training time is 15 min within 5 s, which is advantageous over BPNN. Furthermore, fuel consumption increases by 6.95% compared with the dynamic-programming algorithm and decreased by 5.6%~10.9% compared with the low accuracy of speed prediction. Overall, the proposed method is crucial for optimizing EMS as it is not only effective in improving prediction accuracy but also capable of reducing training time.

Finding a numerical method to model solute transport in porous media with high heterogeneity is crucial, especially when chemical reactions are involved. The phase space formulation termed the multi-advective water mixing approach (MAWMA) was proposed to address this issue. The water parcel method (WP) may be obtained by discretizing MAWMA in space, time, and velocity. WP needs two transition matrices of velocity to reproduce advection (Markovian in space) and mixing (Markovian in time), separately. The matrices express the transition probability of water instead of individual solute concentration. This entails a change in concept, since the entire transport phenomenon is defined by the water phase. Concentration is reduced to a chemical attribute. The water transition matrix is obtained and is demonstrated to be constant in time. Moreover, the WP method is compared with the classic random walk method (RW) in a high heterogeneous domain. Results show that the WP adequately reproduces advection and dispersion, but overestimates mixing because mixing is a sub-velocity phase process. The WP method must, therefore, be extended to take into account incomplete mixing within velocity classes.

The U.S. Environmental Protection Agency’s (EPA) Superfund—the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) database—has collected and built an open-source database based on nearly 2000 US soil remediation cases since 1980, providing detailed information and references for researchers worldwide to carry out remediation work. However, the cases were relatively independent to each other, so the whole database lacks systematicness and instructiveness to some extent. In this study, the basic features of all 144 soil remediation projects in four major oil-producing states (California, Texas, Oklahoma and Alaska) were extracted from the CERCLA database and the correlations among the pollutant species, pollutant site characteristics and selection of remediation methods were analyzed using traditional and machine learning techniques. The Decision Tree Classifier was selected as the machine learning model. The results showed that the growth of new contaminated sites has slowed down in recent years; physical remediation was the most commonly used method, and the probability of its application is more than 80%. The presence of benzene, toluene, ethylbenzene and xylene (BTEX) substances and the geographical location of the site were the two most influential factors in the choice of remediation method for a specific site; the maximum weights of these two features reaches 0.304 and 0.288.

Accurate and reliable PV power probabilistic-forecasting results can help grid operators and market participants better understand and cope with PV energy volatility and uncertainty and improve the efficiency of energy dispatch and operation, which plays an important role in application scenarios such as power market trading, risk management, and grid scheduling. In this paper, an innovative deep learning quantile regression ultra-short-term PV power-forecasting method is proposed. This method employs a two-branch deep learning architecture to forecast the conditional quantile of PV power; one branch is a QR-based stacked conventional convolutional neural network (QR_CNN), and the other is a QR-based temporal convolutional network (QR_TCN). The stacked CNN is used to focus on learning short-term local dependencies in PV power sequences, and the TCN is used to learn long-term temporal constraints between multi-feature data. These two branches extract different features from input data with different prior knowledge. By jointly training the two branches, the model is able to learn the probability distribution of PV power and obtain discrete conditional quantile forecasts of PV power in the ultra-short term. Then, based on these conditional quantile forecasts, a kernel density estimation method is used to estimate the PV power probability density function. The proposed method innovatively employs two ways of a priori knowledge injection: constructing a differential sequence of historical power as an input feature to provide more information about the ultrashort-term dynamics of the PV power and, at the same time, dividing it, together with all the other features, into two sets of inputs that contain different a priori features according to the demand of the forecasting task; and the dual-branching model architecture is designed to deeply match the data of the two sets of input features to the corresponding branching model computational mechanisms. The two a priori knowledge injection methods provide more effective features for the model and improve the forecasting performance and understandability of the model. The performance of the proposed model in point forecasting, interval forecasting, and probabilistic forecasting is comprehensively evaluated through the case of a real PV plant. The experimental results show that the proposed model performs well on the task of ultra-short-term PV power probabilistic forecasting and outperforms other state-of-the-art deep learning models in the field combined with QR. The proposed method in this paper can provide technical support for application scenarios such as energy scheduling, market trading, and risk management on the ultra-short-term time scale of the power system.