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Ultrarich filtration combustion of ethane is studied in a porous medium composed of alumina spheres with the aim to achieve optimized conversion to hydrogen and syngas. Temperature, velocities, and...

Abstract The oxidation characteristics of several small methyl and ethyl esters with carbon number less than six were investigated in laminar flames. The kinetics of such fuels are subsets of those of larger alkyl esters that are constituents of practical biodiesel fuels. A total of seven fuels, namely methyl formate, methyl acetate, methyl propionate, methyl butanoate, ethyl formate, ethyl acetate, and ethyl propionate were considered. Experiments were conducted at atmospheric pressure, elevated reactant temperatures, and over a wide range of equivalence ratios. Laminar flame speeds were determined in the counterflow configuration in which flow velocities were measured using particle image velocimetry. Several detailed kinetic models were tested against the experimental data, and insight was provided into the high-temperature combustion kinetics of the aforementioned fuels. Based on comparisons between experimental and computed results it became apparent that the chemistry of alkyl-ester combustion chemistry is evolving and much needs to be done in order to derive improved rate constants for a wide range of elementary steps.

White sweet clover found voluntarily growing on a deep bed of soft coal fly ash was found to contain high concentrations of a number of elements including selenium, bromine, and molybdenum, rubidium, strontium, and others. The clover was harvested and fed as 23.5% of a dry pelleted ration to lambs and pregnant goats for up to 173 days. High concentrations of selenium were found in 11 tissues, blood, goats' milk, and excreta of lambs, goats, and newborn kids. Molybdenum in liver, strontium in bone, and bromine and rubidium in animal tissues were also elevated over those in the corresponding tissues of animals fed an identical ration containing control clover grown on soil. No gross or histologic lesions were present in any of the animals.

Abstract A great deal of heat is wasted in intensive public shower facilities, such as those in schools, barracks and natatoriums, which open up at specified time. It will contribute a lot to energy saving and environmental protection with significant economic benefits to recycle the exhaust heat. In this paper, we propose two different kinds of heat pumps (an electric heat pump and an absorption heat pump) in the heat recovery systems. In both system, the used shower water is drained through a pipe and collected in a gray water pool. When the wastewater reaches certain volume, the heat pump system will begin working and recycling heat. The wastewater is filtered and piped to the heat exchanger to exchange heat with the tap water whose temperature will increase from 12 °C to 25 °C with the wastewater temperature dropping from 30 °C to 17 °C. Then the wastewater is piped to the heat pump evaporator and the tap water is piped to the condenser for farther heating. According to the different characteristics of the electric heat pump and absorption heat pump, we also introduce the processes and control methods of different heat recovery systems in details in this paper. Based on a practical example, this paper analyzes and compares the economic and environmental benefits of three retrofitting schemes, including “exhaust heat recovery using electric heat pump”, “exhaust heat recovery using electric heat pump + gas boiler” and “exhaust heat recovery using direct-fired heat pump”. Then we find out that the heat recovery system using direct-fired absorption heat pump has lower energy consumption, less pollution, lower operating cost, and shorter payback period. And it has a promising practical application.

Construction involves the use of significant quantities of raw materials and entails high-energy consumption. For the sake of choosing the most appropriate solution that considers environmental and sustainable concepts, tools such as the integrated value model for sustainable assessment (Modelo Integrado de Valor para una Evaluación Sostenible, MIVES) used in Spain, plays a key role in obtaining the best solution. MIVES is a multi-criteria decision-making method based on the value function concept and the seminars delivered by experts. Such tools, in order to show how they may work, require application to case studies. In this paper, two concrete slabs manufactured with differing reinforcements during the construction of the La Canda Tunnels are compared by means of MIVES. The two concrete slabs were reinforced with a conventional steel-mesh and with polyolefin fibres. This research was focussed on the main aspects affecting the construction. That is to say, the environmental, economic, and social factors were assessed by the method, being of special impact the issues related with maintenance of the structure. The results showed that from the point of view of sustainability, the use of polyolefin fibres provided a significant advantage, mainly due to the lower maintenance required.

The ethanolic fermentation of liquid fractions (hydrolysates) issued from dilute acid pre-treatment of olive tree biomass by Pichia stipitis is reported for the first time. On the one side, P. stipitis has been reported as the most promising naturally occurring C5 fermenting microorganism; on the other side, olive tree biomass is a renewable, low cost, and lacking of alternatives agricultural residue especially abundant in Mediterranean countries. The study was performed in two steps. First, the fermentation performance of P. stipitis was evaluated on a fermentation medium also containing the main inhibitors found in these hydrolysates (acetic acid, formic acid, and furfural), as well as glucose and xylose as carbon sources. The effect of inhibitors, individually or in a mixture, on kinetic and yield parameters was calculated. In a second step, hydrolysates obtained from 1% (w/w) sulfuric acid pre-treatment of olive tree biomass at 190ºC for 10 min were used as a real fermentation medium with the same microorganism. Due to inhibition, effective fermentation required dilution of the hydrolysate and either overliming or activated charcoal treatment. Results show that ethanol yields obtained from hydrolysates, ranging from 0.35 to 0.42 g/g, are similar to those from synthetic medium, although the process proceeds at lower rates. Inhibiting compounds affect the fermentation performance in a synergistic way. Furfural is rapidly assimilated by the yeast; acetic acid and formic acid concentrations decrease slowly during the process. Activated charcoal or overliming detoxification improve the fermentability of diluted hydrolysates.

The battery power state (SOP) is the basic indicator for the Battery management system (BMS) of the battery energy storage system (BESS) to formulate control strategies. Although there have been many studies on state estimation of lithium-ion batteries (LIBs), aging and temperature variation are seldom considered in peak power prediction during the whole life of the battery. To fill this gap, this paper aims to propose an adaptive peak power prediction method for power lithium-ion batteries considering temperature and aging is proposed. First, the Thevenin equivalent circuit model is used to jointly estimate the state of charge (SOC) and SOP of the lithium-ion power battery, and the variable forgetting factor recursive least squares (VFF-RLS) algorithm and extended Kalman filter (EKF) are utilized to identify the battery parameters online. Then, multiple constraint parameters including current, voltage, and SOC were derived, considering the dependence of the polarization resistance of the battery on the battery current. Finally, the verification experiment was carried out with LiFePO4 battery. The experimental results under FUDS operating conditions show that the maximum SOC estimation error is 1.94%. And the power prediction errors at 20%, 50%, and 70% SOC were 5.0%, 8.1% and 4.5%, respectively. Our further work will focus on the joint estimation of battery state to further improve the accuracy.

ABSTRACTPlant heme oxygenases (HOs) regulate biosynthesis of phytochrome which accounts for photo‐acceptance and ‐morphogenesis. Recent studies have demonstrated that plant HOs also regulate many other physiological processes including response to environmental stimuli. To elucidate the mechanism by which HOs regulate plant adaptation to heavy metal exposure, three novel HOs genes were isolated from rapeseed (Brassica napus) and their expression patterns were analysed. Alignment of deduced protein sequences revealed that the three BnHOs share high identity with their corresponding orthologos (AtHO1‐3) from Arabidopsis. To investigate whether the BnHO regulates plant tolerance to Hg toxicity, we constructed B. napus transgenic plants overexpressing BnHO‐1. Under Hg stress, the transgenic plants had 1.41–1.59 folds higher biomass than the untransformants. However, overexpression of BnHO‐1 resulted in less accumulation of Hg in some lines of transformants than in untransformants. The transgenic plants show lower abundance of reactive oxygen species and attenuated oxidative injury compared with the untransgenic plants. We cloned the promoter sequences of BnHO‐1 from B. napus. Analysis revealed that the 1119 bp fragment contains a conserved Cd responsive element (CdRE) and others responding to multiple environmental stimuli. Transient expression in tobacco leaves showed differential responses to heavy metals (Zn, Cu, Pb, Hg and Cd).