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  • Energy Research
  • 13. Climate action
  • 6. Clean water
  • CO
  • Energies

  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: orcid Daniella Rodríguez-Urrego;
    Daniella Rodríguez-Urrego
    ORCID
    Harvested from ORCID Public Data File

    Daniella Rodríguez-Urrego in OpenAIRE
    orcid Leonardo Rodríguez-Urrego;
    Leonardo Rodríguez-Urrego
    ORCID
    Harvested from ORCID Public Data File

    Leonardo Rodríguez-Urrego in OpenAIRE
    orcid Benjamín González-Díaz;
    Benjamín González-Díaz
    ORCID
    Harvested from ORCID Public Data File

    Benjamín González-Díaz in OpenAIRE
    Ricardo Guerrero-Lemus;

    Groundwater pumping systems using photovoltaic (PV) energy are increasingly being implemented around the world and, to a greater extent, in rural and electrically isolated areas. Over time, the cost of these systems has decreased, providing greater accessibility to freshwater in areas far from urban centers and power grids. This paper proposes a novel sustainability analysis of the groundwater pumping systems in Tenerife Island as an example of a medium-size isolated system, analyzing the current status and the business-as-usual projection to 2030, considering the water reservoirs available and the final use of water. The 2030 projection focused on the PV deployment, evaluation of the levelized cost of electricity (LCOE), and the availability of the groundwater resource. HOMER software was used to analyze the LCOE, and ArcGIS software was used for the visual modeling of water resources. As a result, the average LCOE for a purely PV installation supplying electricity to a pumping system in Tenerife is 0.2430 €/kWh, but the location and characteristic of each pumping system directly affect the performance and costs, mostly due to the solar availability.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2022 . Peer-reviewed
    License: CC BY
    Data sources: Crossref
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2022
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Energies
      Article . 2022 . Peer-reviewed
      License: CC BY
      Data sources: Crossref
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2022
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: orcid Andrés Oviedo-Gómez;
    Andrés Oviedo-Gómez
    ORCID
    Harvested from ORCID Public Data File

    Andrés Oviedo-Gómez in OpenAIRE
    orcid Sandra Milena Londoño-Hernández;
    Sandra Milena Londoño-Hernández
    ORCID
    Harvested from ORCID Public Data File

    Sandra Milena Londoño-Hernández in OpenAIRE
    orcid Diego Fernando Manotas-Duque;
    Diego Fernando Manotas-Duque
    ORCID
    Harvested from ORCID Public Data File

    Diego Fernando Manotas-Duque in OpenAIRE

    COVID-19 disease shocked global economic activity and affected the electricity markets due to lockdown and work-from-home policies. Therefore, this study proposes an empirical analysis to identify the electricity spot price response during the preventive and mandatory insulation in Colombia, where the economic contraction caused the largest decrease in the electricity demand, especially in the industrial sector. The methodology applied was quantile regression to quantify the non-linear effect on the spot price returns, and two sample periods were selected to contrast the results: 2018 and 2019. The main findings showed that regulated demand variation caused the highest variability on the spot price dynamic during the strict quarantine. However, the price could not fully capture the effects of the demand change due to the short duration of the shock and, also, the price variability in 2019 was higher than 2020 by an El Niño shock.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
    License: CC BY
    Data sources: Crossref
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article
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    Energies
    Article . 2021
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Energies
      Article . 2021 . Peer-reviewed
      License: CC BY
      Data sources: Crossref
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2021
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Aldair Benavides Gamero; Josué Camargo Vanegas; orcid Jorge Duarte Forero;
    Jorge Duarte Forero
    ORCID
    Harvested from ORCID Public Data File

    Jorge Duarte Forero in OpenAIRE
    orcid Guillermo Valencia Ochoa;
    Guillermo Valencia Ochoa
    ORCID
    Harvested from ORCID Public Data File

    Guillermo Valencia Ochoa in OpenAIRE
    +1 Authors

    This paper aims to present the real improvement opportunities of a simple organic Rankine cycle (ORC) as waste heat recovery system (WHRS) from the exhaust gases of a natural gas engine using toluene as the working fluid, based on the exergy and environmental point of view. From the energy and exergy balances, the advanced exergetic analysis was developed to determine the irreversibilities and opportunities for improvement. Since the traditional exergo-environmental analysis, it was found that the component with the greatest potential environmental impact associated with exergy (bF = 0.067 mPts/MJ) and per unit of exergy (ḂD = 8.729 mPts/h) was the condenser, while the exergy-environmental fraction was presented in the turbine (52.51%) and pump-2 (21.12%). The advanced exergo-environmental analysis showed that the environmental impact is more associated with the operational behavior of the components, with 75.33% of the environmental impacts being of endogenous nature, showing that the environmental impacts are generated to a reduced magnitude through the interactions between components. However, it was identified that much of the environmental impacts in ITC 1 could be reduced, with 81.3% of these impacts being avoidable. Finally, the sensitivity analysis results revealed that steel is the material of the components with the least environmental impact.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2023 . Peer-reviewed
    License: CC BY
    Data sources: Crossref
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2023
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2023 . Peer-reviewed
      License: CC BY
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      Energies
      Article . 2023
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    Authors: orcid Máximo A. Domínguez-Garabitos;
    Máximo A. Domínguez-Garabitos
    ORCID
    Harvested from ORCID Public Data File

    Máximo A. Domínguez-Garabitos in OpenAIRE
    orcid Víctor S. Ocaña-Guevara;
    Víctor S. Ocaña-Guevara
    ORCID
    Harvested from ORCID Public Data File

    Víctor S. Ocaña-Guevara in OpenAIRE
    orcid Félix Santos-García;
    Félix Santos-García
    ORCID
    Harvested from ORCID Public Data File

    Félix Santos-García in OpenAIRE
    orcid Adriana Arango-Manrique;
    Adriana Arango-Manrique
    ORCID
    Harvested from ORCID Public Data File

    Adriana Arango-Manrique in OpenAIRE
    +1 Authors

    The energy transition has shown that fossil generation can be complemented with renewable energy and other resources capable of providing flexibility to the energy system’s operation, in compliance with the wholesale electricity market’s rules. This paper proposes a market-based methodology for introducing flexible demand in the energy dispatch, optimizing the scheduling of electricity system operation in the short-term, and considers the challenge of implementing an incentive scheme for participants in demand-response programs. The scheme includes the criteria of the elasticity of substitution and a renewable energy quota. This methodology is focused on a strategic demand shift to minimize the cost of supply; increase the dispatch of renewable energy; control CO2 emissions; and satisfy the generation, demand, and transmission operating constraints. These conditions encourage the development of a simulation tool that allows a sensitivity analysis to aid decision-making by operators and agents. The proposed methodology optimizes the operational cost of generation supply and specific performance indicators to determine the percentages of demand shift, the amount of CO2 emissions, the ratio of unserved power, the demand benefits obtained from an incentive scheme, and the natural market behavior.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2022 . Peer-reviewed
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    Energies
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      Article . 2022 . Peer-reviewed
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      Energies
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    Authors: orcid Bibi Ibrahim;
    Bibi Ibrahim
    ORCID
    Harvested from ORCID Public Data File

    Bibi Ibrahim in OpenAIRE
    orcid Luis Rabelo;
    Luis Rabelo
    ORCID
    Harvested from ORCID Public Data File

    Luis Rabelo in OpenAIRE
    Alfonso T. Sarmiento; orcid Edgar Gutierrez-Franco;
    Edgar Gutierrez-Franco
    ORCID
    Harvested from ORCID Public Data File

    Edgar Gutierrez-Franco in OpenAIRE

    The digital revolution requires greater reliability from electric power systems. However, predicting the growth of electricity demand is challenging as there is still much uncertainty in terms of demographics, industry changes, and irregular consumption patterns. Machine learning has emerged as a powerful tool, particularly with the latest developments in deep learning. Such tools can predict electricity demand and, thus, contribute to better decision-making by energy managers. However, it is important to recognize that there are no efficient methods for forecasting peak demand growth. In addition, features that add complexity, such as climate change and economic growth, take time to model. Therefore, these new tools can be integrated with other proven tools that can be used to model specific system structures, such as system dynamics. This research proposes a unique framework to support decision-makers in dealing with daily activities while attentively tracking monthly peak demand. This approach integrates advances in machine learning and system dynamics. This integration has the potential to contribute to more precise forecasts, which can help to develop strategies that can deal with supply and demand variations. A real-world case study was used to comprehend the needs of the environment and the effects of COVID-19 on power systems; it also helps to demonstrate the use of leading-edge tools, such as convolutional neural networks (CNNs), to predict electricity demand. Three well-known CNN variants were studied: a multichannel CNN, CNN-LSTM, and a multi-head CNN. This study found that the multichannel CNN outperformed all the models, with an R2 of 0.92 and a MAPE value of 1.62% for predicting the month-ahead peak demand. The multichannel CNN consists of one main model that processes four input features as a separate channel, resulting in one feature map. Furthermore, a system dynamics model was introduced to model the energy sector’s dynamic behavior (i.e., residential, commercial, and government demands, etc.). The calibrated model reproduced the historical data curve fairly well between 2005 and 2017, with an R2 value of 0.94 and a MAPE value of 4.8%.

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    Energies
    Article . 2023 . Peer-reviewed
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      Energies
      Article . 2023 . Peer-reviewed
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    Authors: orcid Alberto Veses;
    Alberto Veses
    ORCID
    Harvested from ORCID Public Data File

    Alberto Veses in OpenAIRE
    orcid Juan Martínez;
    Juan Martínez
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    Juan Martínez in OpenAIRE
    orcid María Callén;
    María Callén
    ORCID
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    María Callén in OpenAIRE
    Ramón Murillo; +1 Authors

    This paper reports the performance of a spark ignition engine using gasoline blended with an upgraded bio-oil rich in aromatics and ethanol. This upgraded bio-oil was obtained using a two-step catalytic process. The first step comprised an in-situ catalytic pyrolysis process with CaO in order to obtain a more stable deoxygenated organic fraction, while the second consisted of a catalytic cracking of the vapours released using ZSM-5 zeolites to obtain an aromatics-rich fraction. To facilitate the mixture between bio-oil and gasoline, ethanol was added. The behaviour of a stationary spark ignition engine G12TFH (9600 W) was described in terms of fuel consumption and electrical efficiency. In addition, gaseous emissions and polycyclic aromatic hydrocarbon (PAH) concentrations were determined. Trial tests suggested that it is possible to work with a blend of gasoline, ethanol and bio-oil (90/8/2 vol%, herein named G90E8B2) showing similar fuel consumption than pure gasoline (G100) at the same load. Moreover, combustion could be considered more efficient when small quantities of ethanol and organic bio-oil are simultaneously added. A reduction, not only in the PAH concentrations but also in the carcinogenic equivalent concentrations, was also obtained, decreasing the environmental impact of the exhaust gases. Thus, results show that it is technically feasible to use low blends of aroma-rich bio-oil, ethanol and gasoline in conventional spark ignition engines.

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    Energies
    Article . 2020 . Peer-reviewed
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    Energies
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    Energies
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      Energies
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    Authors: Saleh Al-Haddad; orcid Cynthia Kusin Okoro-Shekwaga;
    Cynthia Kusin Okoro-Shekwaga
    ORCID
    Harvested from ORCID Public Data File

    Cynthia Kusin Okoro-Shekwaga in OpenAIRE
    Louise Fletcher; Andrew Ross; +1 Authors

    Hydrogen gas (H2) is an energy carrier that does not generate carbon dioxide emissions during combustion, but several processes in use for its production demand high energy inputs associated with fossil fuels and greenhouse emissions. Biological processes, such as dark fermentation (DF), have the potential to remove the dependency on fossil fuels in H2 production. DF is a process that encourages fermentative bacteria to ferment organic substrates to produce H2 as a truly clean energy carrier, but its success depends on removing the presence of competing H2−consuming microorganisms in the inoculum consortia. This paper addresses a strategy to enhance H2 production from different types of substrates by testing inoculum pre-treatment processes to inactivate H2−consuming bacteria, including acid-shock (pH 3), basic-shock (pH 10) and heat-shock (115 °C) methods. Digestate from anaerobic digesters processing sewage sludge was used to produce pre-treated inocula, which were subsequently tested in a batch bio-H2 potential (BHP) test using glucose as a substrate. The results show that heat-shock pre-treatment was the best method, reporting a H2 yield of 191.8 mL-H2/gVS added (the untreated inoculum reported 170.91 mL-H2/gVS added). Glucose conversion data show a high concentration of butyric acid in both treated and untreated inocula during BHP tests, which indicate that the butyrate pathway for H2 production was dominant; shifting this to the formate route could further enhance net H2 production. A standardised inoculum-conditioning method can help to consistently assess the biohydrogen potential of suitable feedstock for DF and maximise H2 yields.

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    Energies
    Article . 2023 . Peer-reviewed
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    Energies
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      Energies
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    Authors: orcid José D. Morcillo;
    José D. Morcillo
    ORCID
    Harvested from ORCID Public Data File

    José D. Morcillo in OpenAIRE
    orcid bw Fabiola Angulo;
    Fabiola Angulo
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    Fabiola Angulo in OpenAIRE
    orcid Carlos Franco;
    Carlos Franco
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    Carlos Franco in OpenAIRE

    In this paper, the variations in hydropower generation are addressed considering the seasonality and ENSO (El Niño-Southern Oscillation) episodes. The dynamic hypothesis and the stock-flow structure of the Colombian electricity market were analyzed. Moreover, its dynamic behavior was analyzed by using Dynamic Systems tools aimed at providing deep insight into the system. The MATLAB/Simulink model was used to evaluate the Colombian electricity market. Since we combine System Dynamics and Dynamic Systems, this methodology provides a novel insight and a deeper analysis compared with System Dynamics models and can be easily implemented by policymakers to suggest improvements in regulation or market structures. We also provide a detailed description of the Colombian electricity market dynamics under a broad range of demand growth rate scenarios inspired by the bifurcation and control theory of Dynamic Systems.

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    Energies
    Article . 2020 . Peer-reviewed
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    Energies
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    Energies
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      Energies
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    Authors: John J. Sandoval-Cobo; Diana M. Caicedo-Concha; orcid Luis F. Marmolejo-Rebellón;
    Luis F. Marmolejo-Rebellón
    ORCID
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    Luis F. Marmolejo-Rebellón in OpenAIRE
    Patricia Torres-Lozada; +1 Authors

    This study evaluated leachate recirculation (LR) as a stabilisation strategy for landfills using bioreactor experiments with excavated waste from a tropical landfill in Colombia. The experimental evaluation was performed in two 115 L bioreactors, one simulating the operation of a landfill with LR, Br2, where the leachate produced was recirculated at a rate of 0.8 L d−1, and a control system without LR, Br1. Both systems reached stabilisation indicator values on a dry matter (DM) basis for volatile solids VS (<25% DM) and a biochemical methane potential BMP (≤10 mL CH4 g−1 DM). Likewise, towards the end of the experiment, the leachate generated in Br2 reached stabilisation indicator values for BOD5 (<100 mg L−1) and the BOD (biological oxygen demand)/COD (chemical oxygen demand) ratio (<0.1). Although the stabilisation criterion for COD was not met in any bioreactor (<200 mg L−1), LR helped to release 19% more oxidisable organic matter in Br2 than in Br1, indicating a reduction in the contaminating potential of the waste in the case of uncontrolled discharges of leachate to the environment. Regarding biogas production, the generation of CH4 in Br2 was more intense and its cumulative production was 34.5% higher than Br1; thus, Br2 achieved CH4 emission rates, indicating waste stabilisation (<1.0 L CH4 m−2 h−1) sooner than Br1, showing an accelerating effect of LR on waste degradation. A carbon mass balance indicated that waste degradation, in terms of the initial total organic carbon mineralisation and the C gas discharge via CH4, was greater in Br2. These results demonstrate the LR potential to accelerate the stabilisation of a landfill but also to reduce greenhouse gas emissions in final disposal sites where biogas is also captured and utilised for energy production; a key aspect when improving the sustainability of landfill operations in developing countries.

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    Energies
    Article . 2022 . Peer-reviewed
    License: CC BY
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    Energies
    Article . 2022
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      Energies
      Article . 2022 . Peer-reviewed
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      Energies
      Article . 2022
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    Authors: orcid Gustavo Maya;
    Gustavo Maya
    ORCID
    Harvested from ORCID Public Data File

    Gustavo Maya in OpenAIRE
    Aurora L. Carreño Otero; Fabián L. Monares Bueno; orcid Arnold R. Romero Bohórquez;
    Arnold R. Romero Bohórquez
    ORCID
    Harvested from ORCID Public Data File

    Arnold R. Romero Bohórquez in OpenAIRE
    +3 Authors

    Recent research has highlighted wettability alteration as the main consequence of the different mechanisms involved in technologies such as adjusted brine composition water flooding (ABCW) and low-salinity water flooding (LSW). However, studies are still needed to give a phenomenological explanation, and the most influential components of the system (rock–oil–brine) must be clarified. This work focuses on determining the most relevant variables for the smart water effects to occur. Static (contact angles) and dynamic tests (coreflooding) were conducted. For the static tests, aged Berea slices, a specific crude oil (27° API, 10.5 cp at 60 °C), and mono and divalent inorganic salts (Na+, K+, Ca2+, and Mg2+/Cl−) were used in 3 different concentrations of 1000, 3000, and 5000 ppm (ionic strength variation between 0.015 and 0.06) to establish the wettability state by measuring the contact angles of the system. When salts containing chloride were evaluated, a decrease in oil wettability was observed at 5000 ppm. At 3000 and 1000 ppm, tendencies depended on the particular cation. Three brines were selected from the contact angle experiments to be used in coreflooding assays, considering a particular design to identify ion exchange from the rock–oil–brine system. The first assay was carried out in the absence of crude oil as a baseline to determine the ion exchange between the brine and the rock, and a second test considered crude oil to provide insight into ion exchange and its effect on displacement efficiency. Capillary electrophoresis was used in this research as a novel contribution to the systematic study of oil displacement tests, and it has proven to be a powerful tool for understanding the mechanisms involved. The results show that the variations in the concentrations detected in the displacement effluents were the product of the interactions between rock, oil, and brine since the concentrations measured in the absence of oil phase were comparable to those in the injection brine. Significant variations in the effluent ion concentrations were determined for the different brines used, and increases in the pressure differentials were observed for the KCl and CaCl2 brines. These results suggest that the oil–brine ion exchange (salting in/out) represents a relevant mechanism to explain the observed displacement efficiencies and differential pressures. The ionic enrichment of the water phase due to the salting in/out effect needs to be better understood.

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    Energies
    Article . 2023 . Peer-reviewed
    License: CC BY
    Data sources: Crossref
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2023
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      Article . 2023
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