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Cogeneration of heat and electricity is an important pillar of energy and climate policy. To plan the production and distribution system of combined heat and power (CHP) systems for residential heating, suitable methods for decision support are needed. For a comprehensive feasibility analysis, the integration of the location and capacity planning of the power plants, the choice of customers, and the network planning of the heating network into one optimization model are necessary. Thus, we develop an optimization model for electricity generation and heat supply. This mixed integer linear program (MILP) is based on graph theory for network flow problems. We apply the network location model for the optimization of district heating systems in the City of Osorno in Chile, which exhibits the “checkerboard layout” typically found in many South American cities. The network location model can support the strategic planning of investments in renewable energy projects because it permits the analysis of changing energy prices, calculation of break-even prices for heat and electricity, and estimation of greenhouse gas emission savings.

Abstract In many cases, hazardous wastes are subject to thermal treatment at elevated temperatures. Some types of wastes do not have a sufficient calorific value to cover the heat demand of the high temperature process. For thermal treatment of e.g. filter residues, dusts, sulfuric acid, aluminium dross, foundry sand, or waste water, supplementary energy supply is needed. The specific energy demand ranges from 0.5 to 2.5 kWh/kg (2–10 MJ/kg). An important aim of process optimisation is the reduction of (fossil) energy consumption and exhaust gas flow. Concentrated solar energy promises advantages when applied to high energy consuming waste treatment processes with regard to substitute fossil or electric energy consumption, to reduce CO2 emissions, and exhaust gas flow. In parallel to conceptional studies, a solar-heated rotary kiln mini-plant has been designed and constructed for tests in the DLR solar furnace. The tests will give indications of boundary conditions for solar thermal treatment or conversion of selected hazardous materials.

Buildings in private and domestic use are responsible for about 30% of the global greenhouse gas emissions attributable mainly to their need for heating and cooling energy. This corresponds to about 40% of the global final energy consumption. Therefore, a viable implementation of building energy efficiency policies is inevitable to realize a transformation of the energy system to mitigate climate change. Within the building sector lies a huge potential for emission reduction consisting in the renovation of the existing building stock and climate-friendly building guidelines applicable to new constructions, both adapting CO2-neutral technology solutions. However, as there are several different pathways leading to a decarbonized energy system, there is always the question which political and technological solutions are most efficient, effective, and feasible. This paper aims to analyze building efficiency policy measures and instruments and the related technological solutions in two front-runner countries of the energy transition, possessing different structural conditions: Germany and Norway. We hence apply a comparative approach which allows us to present and assess the policies in place. The paper answers three research questions: (1) Which policies prevail in Germany and Norway to foster the deployment of energy efficient and decarbonized solutions for residential buildings? (2) How do these policies respond to country-specific barriers to the energy transition in the building sector, and (3) What effects do they have on the actual implementation of technological and societal solutions? This research provides a new insight to the highly relevant topic of energy efficiency in buildings in the context of international Intended Nationally Determined Contribution benchmarking and discusses some unsolved trade-offs in the translation of the global climate governance into the national building sector.

Abstract The Heatpipe Reformer provides an allothermal gasification process for the generation of a hydrogen-rich synthesis gas. Heat pipes transport the heat from a fluidized bed furnace to the steam-blown fluidized bed gasification reactor. The goal of our institute is the generation of hydrogen from the synthesis gas by means of membrane separation in the fluidized bed reactor. The major requirement to ensure a high cold gas efficiency of the Heatpipe Reformer is a high efficiency of the combustor, which is determined by the used heat exchanger and the air–fuel ratio of the combustion. State-of-the-art is a cold gas efficiency of 70% with a combustor efficiency of 60–70%. For that reason the combustion chamber developed at our institute comprises of an efficient heat exchanger to internally recuperate the heat from the flue gas and ensure a high temperature of the primary and secondary air. Another consideration is the design of the secondary air inlet in order to allow a complete combustion of the fuel and low CO emissions. The paper describes the impact of the combustion chamber on the efficiency of the gasifiers cold gas efficiencies. It presents the current state-of-the-art of the heat pipe reformer as well as the current state of the construction of the 100 kW pilot at the Institute of energy process engineering (FAU-EVT). The paper shows experiments on the combustor discussing CO emissions and combustor efficiency in order to calculate a prospected cold gas efficiency of the whole system. Both, biomass and coal can be used as feedstock for the gasification system and results from combustor operation using lignite and wood pellets are shown. The combustion chamber provided CO emissions below 30 mg/m 3 . The internal air-preheater achieved temperatures of more than 500 °C. An analysis of heat losses finally indicates potentials for optimization of the Heatpipe Reformers cold gas efficiencies in the commercial scale.

Proton conducting ceramics (PCC) cells are promising energy conversion devices that enable high efficiency energy conversion at lower temperature range, solving the challenge of conventional solid oxide cells (SOCs) due to the high operating temperature. Electrochemical performance and chemical stability of PCC electrolyte has been investigated in recent studies, suggesting that rare-earth doped Ba(Zr,Ce)O3 perovskite-type ceramics are optimal materials exhibiting high proton conductivity and chemical stability during operations. On the contrary, mechanical stability of these PCC electrolyte materials has not been evaluated despite the fact that the mechanical properties are critically important for achieving long-term stable operation as fuel cells or electrolyser cells. For the development of conventional SOCs, mechanical stability during high temperature operation was one of the most significant challenges to deal with, which was attained as a result of detailed studies on in-situ elastic properties of composing materials such as oxygen ion conducting electrolytes and residual stresses. Similarly, for PCC cells, mechanical properties of cells and composing materials have been of significant interest in order to achieve mechanically stable long-term operation, even though PCC cells operate at lower temperature than SOCs. Furthermore, the metal-supported (MS) structure which provides superior mechanical robustness compared to anode-supported (AS) structure is expected to be applied effectively to PCC cells, which are called proton conducting ceramics – metal-supported cells (PCC-MSCs), leading to greater necessity of the mechanical evaluation of the cells and composing materials. Electrolyte is the most crucial component in an electrochemical cell and must be mechanically stable because ion transport and gas tightness made by electrolyte determines electrical performance. However, there has been important concern that larger thermal stresses might be introduced in PCC cells compared to SOCs, resulting from the thermal expansion coefficient (TEC) mismatch between the electrode and electrolyte and from the chemical expansion by the hydration that occurs in a certain temperature range. The PCC electrolyte is highly in need of investigation on in-situ mechanical properties, especially on elastic properties. In this study, elastic properties of electrochemically promising PCC, Y-doped Ba(Zr,Ce)O3 perovskite-type ceramics, were investigated under high temperature conditions. Elastic moduli such as Young’s modulus and Poisson’s ratio were measured by the method that we previously developed for elastic investigation in high temperature conditions using ultrasonic waves. This method enables highly accurate and repetitive examination of elastic properties at high temperatures in materials with poor sinterability including PCC by measuring ultrasonic sound velocities in pellets typically fabricated for electrochemical tests. Pellets of BaZr1-xYxO3-δ (BZY) with different concentrations of doped yttrium, BaZr0.9Y0.1O3-δ (BZY10), BaZr0.85Y0.15O3-δ (BZY15), and BaZr0.8Y0.2O3-δ (BZY20), were fabricated. Additionally, pellets of BaZryCe1-yY0.1O3-δ (BZCY) with different ratio of Ce to Zr, BaZr0.7Ce0.2Y0.1O3-δ (BZCY721) and BaZr0.8Ce0.1Y0.1O3-δ (BZCY811) were fabricated. Powders of PCCs above were consolidated to be thick rounded shape and sintered in air. Each prepared sample was set in an electric furnace in laboratory air atmosphere and sound velocities were measured with the sample slowly heated up to 700 °C and subsequently cooled down to room temperature to calculate elastic moduli at each measuring point. In the first series of heating and cooling measurements for as-sintered samples, hysteresis on elastic moduli in intermediate temperature range was observed. We repeatedly conducted a series of heating and cooling measurements several times, and then the hysteresis was not observed any further. Fig.1 shows final state Young’s modulus of BZCY721, BZCY811, and BZY10 (BZCY901) without hysteresis. Elastic moduli at room temperature have not changed through multiple heating and cooling measurements, and crystal structures and lattice parameters were also confirmed to remain constant by x-ray diffraction (XRD) analysis. The hysteresis found in a specific temperature range suggests that elastic moduli were influenced presumably by a change in defect structure of PCC caused by hydration or defect association of oxygen vacancies and dopants. At room temperature, Young’s modulus decreased with the increment of Ce concentration by 16 % from BZY10 to BZCY721. When materials have the same crystalline structure, Young’s modulus generally decreases as mean atomic volume of the base crystal increases. Because BaCeO3 has larger mean atomic volume than BaZrO3, this observation is qualitatively reasonable. However, in high temperatures, the difference became significant only for BZCY721, Young’s modulus decreased by 30 % from that at room temperature in BZCY721. These results suggest that Ce substitution causes different high temperature dependences. Figure 1

The application of neutron emitting radioisotopes in brachytherapy facilitates the use of the higher biological effectiveness of neutrons compared to photons in treating some cancers. Different types of high intensity sources are in use for the treatment of different cancers. To improve the therapy of bulky tumors the dose can be augmented by the additional use of the boron capture reaction of thermal neutrons. This requires information about the thermal neutron dose component around the Cf source. In this work, a Mg/Ar‐ionization chamber internally coated with was used to measure the thermal neutrons. These measurements were performed on two different sources, one in use in the Gershenson Radiation Oncology Center at Harper Hospital in Detroit, MI, and one at the University Hospital of Chiang Mai in Chiang Mai, Thailand. The results of these measurements are compared and indicate that the differences in the construction of the sources influence the thermal dose component.

Abstract A standard mechanical engineering mass transfer analysis is adapted to obtain performance calculations for the cathode of a typical polymer electrolyte membrane fuel cell. Mathematical details are provided and sample calculations performed, based on a number of simplifying assumptions. The relative advantages of low and high-mass transfer formulations are critically appraised and compared to a highly-simplified method.

Abstract Decarbonizing world economies implies the deployment of “green technologies”, meaning a renovation of the energy sector towards using renewable sources and zero emission transport technologies. This renovation will require huge amounts of raw materials, some of them with high supply risks. To assess such risks a new methodology is proposed, identifying possible bottlenecks of future demand versus geological availability. This has been applied to the world development of wind power, solar photovoltaic, solar thermal power and passenger electric vehicles for the 2016–2050 time period under a business as usual scenario considering the impact on 31 different raw materials. As a result, 13 elements were identified to have very high or high risk, meaning that these could generate bottlenecks in the future: cadmium, chromium, cobalt, copper, gallium, indium, lithium, manganese, nickel, silver, tellurium, tin and zinc. Tellurium, which is mostly demanded to manufacture solar photovoltaic cells, presents the highest risk. To overcome these constraints, measures consisting on improving recycling rates from 0.1% to 4.6% per year could avoid material shortages or restrictions in green technologies. For instance, lithium recycling rate should increase from 1% to 4.8% in 2050. This study aims to serve as a guideline for developing eco-design and recycling strategies.

The project between tthe Deutsche Biomasseforschungszentrum (DBFZ) and the Karlsruhe Institute of Technology (KIT) focuses on the pr rovision of alternative fuels by thermochemical conversion. Biogenic residues and wastes which are not used yet or which could be utilised more efficiently are studied. The selection of possible feedstock was supported by a techhnical potential analysis including the competition to th he food industry. The technical suitability of raw materials for the fast pyrolysis (FP) process was of special in nterest. As a possible feedstock following types of biomass were studied: corn stover, corn cobs, biogenic floating re efuse (river Rhine and Baltic Sea), scrap wood, bark, rape s straw, sunflower straw, draff, diverse residues of flour production and hay. A process development unit (PDU) with a biomass feeding rate of 10 kg/h and a twin screw m mixer reactor was used for all experiments. It was found that different types of biomass form different char, condensate e and gas yields due to varying ash levels and lignocellulosic composition. Elemental formulas for feedstock, char, organic condensate and gas were estimated independent on t the feedstock due to similar elemental compositions. Pyrolysis gas analysis during the experiments gave information on the mass yields. A CO/CO2-ratio of 1 (i.e. wood) corresponds to organic condensate yields of about 50 wt.-%%, whereas a ratio of 0.3-0.7 (straw) corresponds to 18-32 wt. .-% respectively. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 973-977

An anaerobic sequencing batch reactor (ASBR), seeded with a biomass inoculum that previously had not been exposed to the macrolide antimicrobial tylosin (mixture of Tylosin A, B, C, and D), was operated for 3 months with swine waste without Tylosin A and for 9 months with swine waste containing Tylosin A at an average concentration of 1.6 mg/L. When swine waste with tylosin was fed to the ASBR, methane production and volatile solids removal did not appear to be inhibited and a methane yield of 0.47 L methane per gram volatile solids fed to the ASBR was observed. Throughout the operating period, Tylosin A levels in ASBR biomass and effluent were below the detection limit of 0.01 mg/L. However, during the first 3 months of operation, the levels of macrolide-lincosamide-streptogramin B (MLSB)-resistant bacteria in the ASBR biomass increased substantially as determined by hybridizations with oligonucleotide probes designed to target MLSB-resistant bacteria. Since no Tylosin A was present in the swine waste during the initial 3 months, the presence of MLSB-resistant bacteria in the swine waste was likely the reason for the increase in resistance. Subsequently, the levels of MLSB-resistant bacteria in ASBR biomass stabilized with an average of 44.9% for the 9 months of operation with swine waste containing Tylosin A. The level of MLSB-resistant bacteria in the swine waste fed to the ASBR during this period averaged 18.0%. The results indicate that anaerobic treatment of a waste stream containing tylosin was effective (based on reactor performance) and that the level of resistant bacteria in the ASBR was substantially higher than in the waste stream fed to this system.