The project between tthe Deutsche Biomasseforschungszentrum (DBFZ) and the Karlsruhe Institute of Technology (KIT) focuses on the pr rovision of alternative fuels by thermochemical conversion. Biogenic residues and wastes which are not used yet or which could be utilised more efficiently are studied. The selection of possible feedstock was supported by a techhnical potential analysis including the competition to th he food industry. The technical suitability of raw materials for the fast pyrolysis (FP) process was of special in nterest. As a possible feedstock following types of biomass were studied: corn stover, corn cobs, biogenic floating re efuse (river Rhine and Baltic Sea), scrap wood, bark, rape s straw, sunflower straw, draff, diverse residues of flour production and hay. A process development unit (PDU) with a biomass feeding rate of 10 kg/h and a twin screw m mixer reactor was used for all experiments. It was found that different types of biomass form different char, condensate e and gas yields due to varying ash levels and lignocellulosic composition. Elemental formulas for feedstock, char, organic condensate and gas were estimated independent on t the feedstock due to similar elemental compositions. Pyrolysis gas analysis during the experiments gave information on the mass yields. A CO/CO2-ratio of 1 (i.e. wood) corresponds to organic condensate yields of about 50 wt.-%%, whereas a ratio of 0.3-0.7 (straw) corresponds to 18-32 wt. .-% respectively.

Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 973-977