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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jesus Gonzalez-Feliu; Joelle Morana;

    Urban logistics is a field that studies the best solutions for urban freight distribution with high environmental objectives. However, most actions are started by public authorities without taking into account the impacts of the new organizational schemas in the existing distribution enterprises’ organization. This paper proposes a case study from Padova, Italy: the city logistics system Cityporto, from which the sustainability of such systems is discussed in a Sustainable Development point of view, for both enterprise and collective dimensions, in order to relate the particularities of city logistics to the corresponding supply chains, i.e. to global logistics. Tema. Journal of Land Use, Mobility and Environment, Vol 3, N° 2 (2010): City Logistics

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ INRIA a CCSD electro...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ INRIA a CCSD electro...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/

    Today, the term “liquid sunlight” refers to a green fuel obtained by means of a process inspired by the natural photosynthesis. The method to have this fuel is based on the combination of compatible inorganic and biological components to transform light, water, and carbon dioxide to methane. A similar term, “sunlight-to-liquid” or “sun-to-liquid”, exists for a recently proposed synthesis of a gas, which is further processed to obtain kerosene. Here we will show that in the past the term “liquid sunlight” was used for the petroleum. Actually, the meaning of the term, today and in the past, is the same: conversion of the sunlight energy into a fuel.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Hyper Article en Lig...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    ZENODO
    Other literature type . 2019
    License: CC BY
    Data sources: ZENODO
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    ZENODO
    Research . 2019
    License: CC BY
    Data sources: Datacite
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    ZENODO
    Research . 2019
    License: CC BY
    Data sources: Datacite
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Hyper Article en Lig...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      ZENODO
      Other literature type . 2019
      License: CC BY
      Data sources: ZENODO
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      ZENODO
      Research . 2019
      License: CC BY
      Data sources: Datacite
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      ZENODO
      Research . 2019
      License: CC BY
      Data sources: Datacite
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jeannine Wagner-kuhr; Juraj Bracinik; Yoichi Ninomiya; Pavel Starovoitov; +196 Authors

    The dynamics of isolated-photon production in association with a jet in proton–proton collisions at a centre-of-mass energy of 13 TeV are studied with the ATLAS detector at the LHC using a dataset with an integrated luminosity of 3.2 $fb^{−1}$. Photons are required to have transverse energies above 125 GeV. Jets are identified using the anti-$k_t$ algorithm with radius parameter $R = 0.4$ and required to have transverse momenta above 100 GeV. Measurements of isolated-photon plus jet cross sections are presented as functions of the leading-photon transverse energy, the leading-jet transverse momentum, the azimuthal angular separation between the photon and the jet, the photon–jet invariant mass and the scattering angle in the photon–jet centre-of-mass system. Tree-level plus parton-shower predictions from Sherpa and Pythia as well as next-to-leading-order QCD predictions from Jetphox and Sherpa are compared to the measurements. Physics letters / B 780, 578 - 602 (2018). doi:10.1016/j.physletb.2018.03.035 Published by North-Holland Publ., Amsterdam

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ COREarrow_drop_down
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    CORE
    Article . 2018
    License: CC BY
    Data sources: CORE
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Physics Letters B
    Article . 2018
    Data sources: DOAJ
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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    CERN Document Server
    Other literature type . 2017
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Riederer, Peter;

    Room models, currently used for controller tests, assume the room air to be perfectly mixed. A new room model is developed, assuming non-homogeneous room conditions and distinguishing between different sensor positions. From measurement in real test rooms and detailed CFD simulations, a list of convective phenomena is obtained that has to be considered in the development of a model for a room equipped with different HVAC systems. The zonal modelling approach that divides the room air into several sub-volumes is chosen, since it is able to represent the important convective phenomena imposed on the HVAC system. The convective room model is divided into two parts: a zonal model, representing the air at the occupant zone and a second model, providing the conditions at typical sensor positions. Using this approach, the comfort conditions at the occupant zone can be evaluated as well as the impact of different sensor positions. The model is validated for a test room equipped with different HVAC systems. Sensitivity analysis is carried out on the main parameters of the model. Performance assessment and energy consumption are then compared for different sensor positions in a room equipped with different HVAC systems. The results are also compared with those obtained when a well-mixed model is used. A main conclusion of these tests is, that the differences obtained, when changing the position of the controller's sensor, is a function of the HVAC system and controller type. The differences are generally small in terms of thermal comfort but significant in terms of overall energy consumption. For different HVAC systems the cases are listed, in which the use of a simplified model is not recommended. This PhD has been submitted in accordance to the conditions for attaining both the French and the German degree of a PhD, on a co-national basis, in the frame of a statement of the French government from January 18th, 1994. The research has been carried out in the Automation and Energy Management Group (AGE), Department of Sustainable Development (DDD), at the "Centre Scientifique et Technique du Bâtiment" (CSTB) in Marne la Vallée, France, in collaboration with the "Centre Energétique" (CENERG) at the "Ecole Nationale Supérieure des Mines de Paris" (ENSMP), Paris, France and the Technical University of Dresden (TUD), Germany.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ INRIA a CCSD electro...arrow_drop_down
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    Qucosa
    Doctoral thesis . 2001
    Data sources: Qucosa
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Qucosa
      Doctoral thesis . 2001
      Data sources: Qucosa
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    Authors: M. Aaboud; G. Aad; B. Abbott; J. Abdallah; +196 Authors

    Measurements of dijet $p_T$ correlations in Pb+Pb and pp collisions at a nucleon–nucleon centre-of-mass energy of $\sqrt{{s}NN}$ = 2.76 TeV are presented. The measurements are performed with the ATLAS detector at the Large Hadron Collider using Pb + Pb and pp data samples corresponding to integrated luminosities of 0.14 nb$^{−1}$ and 4.0 pb$^{−1}$ , respectively. Jets are reconstructed using the anti-$k_t$ algorithm with radius parameter values R = 0.3 and R = 0.4 . A background subtraction procedure is applied to correct the jets for the large underlying event present in Pb+Pb collisions. The leading and sub-leading jet transverse momenta are denoted $p_{{T}_{1}}$ and $p_{{T}_{2}}$ . An unfolding procedure is applied to the two-dimensional ( $p_{{T}_{1}}, p_{{T}_{2}}$ ) distributions to account for experimental effects in the measurement of both jets. Distributions of (1/N)dN/$dx_J$ , where $x_J$ = $p_{{T}_{1}} / p_{{T}_{2}}$ , are presented as a function of $p_{{T}_{1}}$ and collision centrality. The distributions are found to be similar in peripheral Pb+Pb collisions and pp collisions, but highly modified in central Pb + Pb collisions. Similar features are present in both the R = 0.3 and R = 0.4 results, indicating that the effects of the underlying event are properly accounted for in the measurement. The results are qualitatively consistent with expectations from partonic energy loss models.

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    Authors: Rousselet, Jérôme; ROBINET, Christelle; Battisti, Andrea; Roques, Alain; +1 Authors

    International audience

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    ProdInra
    Conference object . 2014
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      ProdInra
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      Conference object . 2016
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    Authors: Andrea Bocci; Adomas Jelinskas; Vasiliki A Mitsou; Ryunosuke Iguchi; +196 Authors

    A measurement of the production of three isolated photons in proton–proton collisions at a centre-of-mass energy $\sqrt{s}$ = 8 TeV is reported. The results are based on an integrated luminosity of 20.2 fb$^{−1}$ collected with the ATLAS detector at the LHC. The differential cross sections are measured as functions of the transverse energy of each photon, the difference in azimuthal angle and in pseudorapidity between pairs of photons, the invariant mass of pairs of photons, and the invariant mass of the triphoton system. A measurement of the inclusive fiducial cross section is also reported. Next-to-leading-order perturbative QCD predictions are compared to the cross-section measurements. The predictions underestimate the measurement of the inclusive fiducial cross section and the differential measurements at low photon transverse energies and invariant masses. They provide adequate descriptions of the measurements at high values of the photon transverse energies, invariant mass of pairs of photons, and invariant mass of the triphoton system. Physics letters / B 781, 55 - 76 (2018). doi:10.1016/j.physletb.2018.03.057 Published by North-Holland Publ., Amsterdam

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    CORE
    Article . 2018
    License: CC BY
    Data sources: CORE
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    Physics Letters B
    Article . 2018
    Data sources: DOAJ
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    CERN Document Server
    Other literature type . 2017
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    Authors: Hoyer-Klick, Carsten; Wald, Lucien; Ménard, Lionel; Blanc, Philippe; +12 Authors

    The solar resource is the "fuel" of solar energy applications and its availability is a key economic parameter in system design. Even though the southern and eastern Mediterranean region is served by several commercial data providers, in a public domain, so far only coarse resolution (100 km) data or data with limited temporal coverage is available. For more rapid development of policies and to attract the industrial interest in this region a more enhanced and easy to access free information is needed. The project will bring high resolution (1 km), long term coverage of at least 15 years data on the available solar resources for the region covering the countries Syria, Jordan, Israel, Lebanon, Egypt, Libya, Tunisia, Algeria, Morocco, Palestine National Authority, Mauretania and Turkey. The resource data will be derived from Earth Observation satellite data, based on published and transparent methodologies and the data will be validated with existing ground measurements in the region. The database will be provided by SOLEMI and Helioclim (SoDa) sources - Global Horizontal Irradiation (GHI) and Direct Normal Irradiation (DNI). The data will be made available via a distributed information system which will ensure the ease access to the data. The free access to the data will include historical annual and monthly averages, and more detailed data products and services will remain the domain of commercial data providers. This paper will show the first prototype of the user interface for an easy web access to the solar radiation as well as ancillary geographical data. With the presentation of this paper we aim to encourage potential users to give us feedback on the further development.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Onwukamike, Kelechukwu Nnabuike;

    Als Kohlenstoffquelle mit der größten Verfügbarkeit auf unserem Planeten, ohne Konkurrenz zur Lebens- und Futtermittelversorgung, stellt Cellulose eine interessante Alternative dar, um die vielfältig genutzten, nicht-nachhaltigen Polymere auf Erdölbasis zu ersetzen. Die Mehrheit der Forscher, die mit diesem faszinierenden Biopolymer arbeiten, vernachlässigt allerdings Überlegungen zur Nachhaltigkeit in die chemische Modifizierung von Cellulose bei der Herstellung von Materialien zu integrieren. Die Konsequenz dessen ist eine Verlagerung der Umweltbelastung auf andere Abschnitte des Prozess-Zyklus. Um Nachhaltigkeit sicherzustellen, sind deshalb sowohl der erneuerbare Aspekt von Cellulose als auch Überlegungen zur Nachhaltigkeit im Reaktionsprozess wichtig. Dies beinhaltet die Berücksichtigung des Lösungsmittels, die Reaktanden, des Derivatisierungsprozesses, die produzierten Abfälle sowie eine Beurteilung der Nachhaltigkeit der resultierenden Produkte, die relevante Eigenschaften aufweisen müssen um mit bestehenden Alternativen konkurrieren zu können. Diese Arbeit ist deshalb in drei Teile gegliedert (Löslichkeit, Rückgewinnung und Derivatisierung von Cellulose) und befasst sich mit den verschiedenen Aspekten der Nachhaltigkeit während der Umsetzung von Cellulose mit dem Ziel, verarbeitbare Materialien herzustellen. Im ersten Teil der Arbeit wurde ein nachhaltiges Lösungsmittelsystem für Cellulose untersucht. In diesem Zusammenhang wurde eine detaillierte Optimierungsstudie des DBU-CO2 schaltbaren Lösungsmittelsystems mittels in-situ Infrarot Spektroskopie durchgeführt. Nach der Optimierung konnten bis zu 8 Gew.-% Cellulose innerhalb von 15 min. bei 30°C und einem niedrigen CO2-Druck (2-5 bar) gelöst werden. Verglichen mit klassischen Lösungsmitteln für Cellulose weist dieses Lösungsmittelsystem verschiedene nachhaltige Aspekte auf: Einfaches Recycling durch entfernen des CO2-Drucks, schnelles und mildes Auflösen und geringere Kosten als ionische Flüssigkeiten. Durch erfolgreiches Abfangen des in-situ gebildeten Cellulose-Carbonats mit einem Elektrophil, konnte schließlich ein besseres Verständnis dieses Lösungsmittelsystems erreicht werden. Die erfolgreiche Optimierung eines Lösungsmittelsystems für Cellulose führte zum zweiten Teil der Arbeit: der Regenerierung von Cellulose. Hier wurde der bereits mit anderen Systemen beschriebene Weg von Lösen und Ausfällen, gefolgt von Gefriertrocknen übernommen, um Cellulose-Aerogele herzustellen. Verschiedene Bedingungen bei der Verarbeitung wie die Cellulose-Konzentration, Lösungsmittel zum Ausfällen und die Superbase und deren Effekt auf die Eigenschaften der Aerogele (Dichte, Morphologie und Porengröße) wurden untersucht. So wurden Aerogele mit einer Dichte von 0.05-1.20 g/cm3, Porositäten zwischen 92 und 97% und Porengrößen zwischen 1.1 und 4.5 µm erhalten. Zusätzlich wurden im Rasterelektronenmikroskop offene große und makroporöse, miteinander verbundene Cellulose-Netzwerke beobachtet. Die Derivatisierung von Cellulose zur Herstellung von thermisch verarbeitbaren Materialien wird im dritten Teil der Arbeit behandelt. Dieser Teil ist in die zwei Kapitel Umesterung und Modifizierung durch Multikomponenten-Reaktionen unterteilt. Im ersten Kapitel, und unter Berücksichtigung der Prinzipien der Nachhaltigen Chemie, ermöglichte die einzigartige Natur des DBU-CO2 schaltbaren Lösungsmittelsystems (Möglichkeit zur Änderung der Polarität) den direkten Einsatz von Sonnenblumenöl mit hohem Ölsäuregehalt in der Umesterung von Cellulose. Dieser Ansatz ist nachhaltiger als der übliche Einsatz von aktivierten Säurederivaten (z.B. Anhydride oder Säurechloride), die nicht nur giftig sind, sondern gleichermaßen im Voraus synthetisiert werden müssen. Es wurde ein Substitutionsgrad von 1.59 erreicht und die erhaltenen Fettsäure-Cellulose-Ester (FACEs) konnten zu Filmen mit guten mechanischen und thermischen Eigenschaften verarbeitet werden (E-Module von bis zu 478 MPa, maximale Spannung von 22 MPa, Zersetzungstemperaturen bis zu 368°C). Im zweiten Kapitel wurden Multikomponenten-Reaktionen (MCRs) eingesetzt, um multifunktionale, verarbeitbare Materialien auf Cellulosebasis zu synthetisieren. MCRs sind Eintopfreaktionen, weisen üblicherweise eine hohe Atomökonomie und Effizienz auf und benötigen keine Aufreinigung zwischen den Syntheseschritten. Der erste Ansatz, Cellulose direkt mit CO2 in einer Ugi Fünfkomponenten-Reaktion umzusetzen, war nicht erfolgreich. Ein indirekter Ansatz unter Verwendung von mit Bernsteinsäureanhydrid modifizierter Cellulose in der Ugi Vierkomponenten-Reaktion war jedoch erfolgreich. In diesem Fall wurden modifizierte Cellulosederivate mit hohem Molekulargewicht (193-242 kDa) erhalten, diese zeigten hohe Tg-Werte zwischen 99 und 116°C. Die Tg-Werte konnten durch einen einfachen Austausch der einzelnen Komponenten verändert werden. Um den Anwendungsbereich der Multikomponenten-Reaktionen zu erweitern, wurde anschließend die Passerini Vierkomponenten-Reaktion eingeführt. Der Schlüsselschritt in diesem Ansatz war das in-situ gebildete Carbonat-Ion im CO2 schaltbaren Lösungsmittelsystem, das die direkte Einführung von CO2 in die synthetisierte Verbindung ermöglichte. Dieser Ansatz, der eine Möglichkeit zur Fixierung von CO2 zur Herstellung nützlicher Verbindungen darstellt, ermöglicht auch den direkten Einsatz von verschiedenen Alkoholen (primär, sekundär, aromatisch, allylisch). Da viele Kohlenhydrate Hydroxygruppen enthalten, könnte diese Reaktion in der Zukunft neue Möglichkeiten für deren Modifikation eröffnen.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Hyper Article en Lig...arrow_drop_down
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    https://dx.doi.org/10.5445/ir/...
    Doctoral thesis . 2019
    Data sources: Datacite
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      https://dx.doi.org/10.5445/ir/...
      Doctoral thesis . 2019
      Data sources: Datacite
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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    Authors: M. Aaboud; G. Aad; B. Abbott; J. Abdallah; +196 Authors

    Multi-particle cumulants and corresponding Fourier harmonics are measured for azimuthal angle distributions of charged particles in $pp$ collisions at $\sqrt{s}$ = 5.02 and 13 TeV and in $p$+Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV, and compared to the results obtained for low-multiplicity Pb+Pb collisions at $\sqrt{s_{NN}}$ = 2.76 TeV. These measurements aim to assess the collective nature of particle production. The measurements of multi-particle cumulants confirm the evidence for collective phenomena in $p$+Pb and low-multiplicity Pb+Pb collisions. On the other hand, the $pp$ results for four-particle cumulants do not demonstrate collective behaviour, indicating that they may be biased by contributions from non-flow correlations. A comparison of multi-particle cumulants and derived Fourier harmonics across different collision systems is presented as a function of the charged-particle multiplicity. For a given multiplicity, the measured Fourier harmonics are largest in Pb+Pb, smaller in $p$+Pb and smallest in $pp$ collisions. The $pp$ results show no dependence on the collision energy, nor on the multiplicity. The European physical journal / C 77(6), 428 (2017). doi:10.1140/epjc/s10052-017-4988-1 Published by Springer, Berlin

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    Article . 2017
    License: CC BY
    Data sources: CORE
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jesus Gonzalez-Feliu; Joelle Morana;

    Urban logistics is a field that studies the best solutions for urban freight distribution with high environmental objectives. However, most actions are started by public authorities without taking into account the impacts of the new organizational schemas in the existing distribution enterprises’ organization. This paper proposes a case study from Padova, Italy: the city logistics system Cityporto, from which the sustainability of such systems is discussed in a Sustainable Development point of view, for both enterprise and collective dimensions, in order to relate the particularities of city logistics to the corresponding supply chains, i.e. to global logistics. Tema. Journal of Land Use, Mobility and Environment, Vol 3, N° 2 (2010): City Logistics

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ INRIA a CCSD electro...arrow_drop_down
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    Today, the term “liquid sunlight” refers to a green fuel obtained by means of a process inspired by the natural photosynthesis. The method to have this fuel is based on the combination of compatible inorganic and biological components to transform light, water, and carbon dioxide to methane. A similar term, “sunlight-to-liquid” or “sun-to-liquid”, exists for a recently proposed synthesis of a gas, which is further processed to obtain kerosene. Here we will show that in the past the term “liquid sunlight” was used for the petroleum. Actually, the meaning of the term, today and in the past, is the same: conversion of the sunlight energy into a fuel.

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    ZENODO
    Other literature type . 2019
    License: CC BY
    Data sources: ZENODO
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    ZENODO
    Research . 2019
    License: CC BY
    Data sources: Datacite
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    ZENODO
    Research . 2019
    License: CC BY
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      ZENODO
      Other literature type . 2019
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      ZENODO
      Research . 2019
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      ZENODO
      Research . 2019
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    Authors: Jeannine Wagner-kuhr; Juraj Bracinik; Yoichi Ninomiya; Pavel Starovoitov; +196 Authors

    The dynamics of isolated-photon production in association with a jet in proton–proton collisions at a centre-of-mass energy of 13 TeV are studied with the ATLAS detector at the LHC using a dataset with an integrated luminosity of 3.2 $fb^{−1}$. Photons are required to have transverse energies above 125 GeV. Jets are identified using the anti-$k_t$ algorithm with radius parameter $R = 0.4$ and required to have transverse momenta above 100 GeV. Measurements of isolated-photon plus jet cross sections are presented as functions of the leading-photon transverse energy, the leading-jet transverse momentum, the azimuthal angular separation between the photon and the jet, the photon–jet invariant mass and the scattering angle in the photon–jet centre-of-mass system. Tree-level plus parton-shower predictions from Sherpa and Pythia as well as next-to-leading-order QCD predictions from Jetphox and Sherpa are compared to the measurements. Physics letters / B 780, 578 - 602 (2018). doi:10.1016/j.physletb.2018.03.035 Published by North-Holland Publ., Amsterdam

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    CORE
    Article . 2018
    License: CC BY
    Data sources: CORE
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    Physics Letters B
    Article . 2018
    Data sources: DOAJ
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    CERN Document Server
    Other literature type . 2017
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    Authors: Riederer, Peter;

    Room models, currently used for controller tests, assume the room air to be perfectly mixed. A new room model is developed, assuming non-homogeneous room conditions and distinguishing between different sensor positions. From measurement in real test rooms and detailed CFD simulations, a list of convective phenomena is obtained that has to be considered in the development of a model for a room equipped with different HVAC systems. The zonal modelling approach that divides the room air into several sub-volumes is chosen, since it is able to represent the important convective phenomena imposed on the HVAC system. The convective room model is divided into two parts: a zonal model, representing the air at the occupant zone and a second model, providing the conditions at typical sensor positions. Using this approach, the comfort conditions at the occupant zone can be evaluated as well as the impact of different sensor positions. The model is validated for a test room equipped with different HVAC systems. Sensitivity analysis is carried out on the main parameters of the model. Performance assessment and energy consumption are then compared for different sensor positions in a room equipped with different HVAC systems. The results are also compared with those obtained when a well-mixed model is used. A main conclusion of these tests is, that the differences obtained, when changing the position of the controller's sensor, is a function of the HVAC system and controller type. The differences are generally small in terms of thermal comfort but significant in terms of overall energy consumption. For different HVAC systems the cases are listed, in which the use of a simplified model is not recommended. This PhD has been submitted in accordance to the conditions for attaining both the French and the German degree of a PhD, on a co-national basis, in the frame of a statement of the French government from January 18th, 1994. The research has been carried out in the Automation and Energy Management Group (AGE), Department of Sustainable Development (DDD), at the "Centre Scientifique et Technique du Bâtiment" (CSTB) in Marne la Vallée, France, in collaboration with the "Centre Energétique" (CENERG) at the "Ecole Nationale Supérieure des Mines de Paris" (ENSMP), Paris, France and the Technical University of Dresden (TUD), Germany.

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    Qucosa
    Doctoral thesis . 2001
    Data sources: Qucosa
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      Qucosa
      Doctoral thesis . 2001
      Data sources: Qucosa
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    Authors: M. Aaboud; G. Aad; B. Abbott; J. Abdallah; +196 Authors

    Measurements of dijet $p_T$ correlations in Pb+Pb and pp collisions at a nucleon–nucleon centre-of-mass energy of $\sqrt{{s}NN}$ = 2.76 TeV are presented. The measurements are performed with the ATLAS detector at the Large Hadron Collider using Pb + Pb and pp data samples corresponding to integrated luminosities of 0.14 nb$^{−1}$ and 4.0 pb$^{−1}$ , respectively. Jets are reconstructed using the anti-$k_t$ algorithm with radius parameter values R = 0.3 and R = 0.4 . A background subtraction procedure is applied to correct the jets for the large underlying event present in Pb+Pb collisions. The leading and sub-leading jet transverse momenta are denoted $p_{{T}_{1}}$ and $p_{{T}_{2}}$ . An unfolding procedure is applied to the two-dimensional ( $p_{{T}_{1}}, p_{{T}_{2}}$ ) distributions to account for experimental effects in the measurement of both jets. Distributions of (1/N)dN/$dx_J$ , where $x_J$ = $p_{{T}_{1}} / p_{{T}_{2}}$ , are presented as a function of $p_{{T}_{1}}$ and collision centrality. The distributions are found to be similar in peripheral Pb+Pb collisions and pp collisions, but highly modified in central Pb + Pb collisions. Similar features are present in both the R = 0.3 and R = 0.4 results, indicating that the effects of the underlying event are properly accounted for in the measurement. The results are qualitatively consistent with expectations from partonic energy loss models.

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    Authors: Rousselet, Jérôme; ROBINET, Christelle; Battisti, Andrea; Roques, Alain; +1 Authors

    International audience

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    Authors: Andrea Bocci; Adomas Jelinskas; Vasiliki A Mitsou; Ryunosuke Iguchi; +196 Authors

    A measurement of the production of three isolated photons in proton–proton collisions at a centre-of-mass energy $\sqrt{s}$ = 8 TeV is reported. The results are based on an integrated luminosity of 20.2 fb$^{−1}$ collected with the ATLAS detector at the LHC. The differential cross sections are measured as functions of the transverse energy of each photon, the difference in azimuthal angle and in pseudorapidity between pairs of photons, the invariant mass of pairs of photons, and the invariant mass of the triphoton system. A measurement of the inclusive fiducial cross section is also reported. Next-to-leading-order perturbative QCD predictions are compared to the cross-section measurements. The predictions underestimate the measurement of the inclusive fiducial cross section and the differential measurements at low photon transverse energies and invariant masses. They provide adequate descriptions of the measurements at high values of the photon transverse energies, invariant mass of pairs of photons, and invariant mass of the triphoton system. Physics letters / B 781, 55 - 76 (2018). doi:10.1016/j.physletb.2018.03.057 Published by North-Holland Publ., Amsterdam

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    Physics Letters B
    Article . 2018
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    CERN Document Server
    Other literature type . 2017
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    Authors: Hoyer-Klick, Carsten; Wald, Lucien; Ménard, Lionel; Blanc, Philippe; +12 Authors

    The solar resource is the "fuel" of solar energy applications and its availability is a key economic parameter in system design. Even though the southern and eastern Mediterranean region is served by several commercial data providers, in a public domain, so far only coarse resolution (100 km) data or data with limited temporal coverage is available. For more rapid development of policies and to attract the industrial interest in this region a more enhanced and easy to access free information is needed. The project will bring high resolution (1 km), long term coverage of at least 15 years data on the available solar resources for the region covering the countries Syria, Jordan, Israel, Lebanon, Egypt, Libya, Tunisia, Algeria, Morocco, Palestine National Authority, Mauretania and Turkey. The resource data will be derived from Earth Observation satellite data, based on published and transparent methodologies and the data will be validated with existing ground measurements in the region. The database will be provided by SOLEMI and Helioclim (SoDa) sources - Global Horizontal Irradiation (GHI) and Direct Normal Irradiation (DNI). The data will be made available via a distributed information system which will ensure the ease access to the data. The free access to the data will include historical annual and monthly averages, and more detailed data products and services will remain the domain of commercial data providers. This paper will show the first prototype of the user interface for an easy web access to the solar radiation as well as ancillary geographical data. With the presentation of this paper we aim to encourage potential users to give us feedback on the further development.

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    Authors: Onwukamike, Kelechukwu Nnabuike;

    Als Kohlenstoffquelle mit der größten Verfügbarkeit auf unserem Planeten, ohne Konkurrenz zur Lebens- und Futtermittelversorgung, stellt Cellulose eine interessante Alternative dar, um die vielfältig genutzten, nicht-nachhaltigen Polymere auf Erdölbasis zu ersetzen. Die Mehrheit der Forscher, die mit diesem faszinierenden Biopolymer arbeiten, vernachlässigt allerdings Überlegungen zur Nachhaltigkeit in die chemische Modifizierung von Cellulose bei der Herstellung von Materialien zu integrieren. Die Konsequenz dessen ist eine Verlagerung der Umweltbelastung auf andere Abschnitte des Prozess-Zyklus. Um Nachhaltigkeit sicherzustellen, sind deshalb sowohl der erneuerbare Aspekt von Cellulose als auch Überlegungen zur Nachhaltigkeit im Reaktionsprozess wichtig. Dies beinhaltet die Berücksichtigung des Lösungsmittels, die Reaktanden, des Derivatisierungsprozesses, die produzierten Abfälle sowie eine Beurteilung der Nachhaltigkeit der resultierenden Produkte, die relevante Eigenschaften aufweisen müssen um mit bestehenden Alternativen konkurrieren zu können. Diese Arbeit ist deshalb in drei Teile gegliedert (Löslichkeit, Rückgewinnung und Derivatisierung von Cellulose) und befasst sich mit den verschiedenen Aspekten der Nachhaltigkeit während der Umsetzung von Cellulose mit dem Ziel, verarbeitbare Materialien herzustellen. Im ersten Teil der Arbeit wurde ein nachhaltiges Lösungsmittelsystem für Cellulose untersucht. In diesem Zusammenhang wurde eine detaillierte Optimierungsstudie des DBU-CO2 schaltbaren Lösungsmittelsystems mittels in-situ Infrarot Spektroskopie durchgeführt. Nach der Optimierung konnten bis zu 8 Gew.-% Cellulose innerhalb von 15 min. bei 30°C und einem niedrigen CO2-Druck (2-5 bar) gelöst werden. Verglichen mit klassischen Lösungsmitteln für Cellulose weist dieses Lösungsmittelsystem verschiedene nachhaltige Aspekte auf: Einfaches Recycling durch entfernen des CO2-Drucks, schnelles und mildes Auflösen und geringere Kosten als ionische Flüssigkeiten. Durch erfolgreiches Abfangen des in-situ gebildeten Cellulose-Carbonats mit einem Elektrophil, konnte schließlich ein besseres Verständnis dieses Lösungsmittelsystems erreicht werden. Die erfolgreiche Optimierung eines Lösungsmittelsystems für Cellulose führte zum zweiten Teil der Arbeit: der Regenerierung von Cellulose. Hier wurde der bereits mit anderen Systemen beschriebene Weg von Lösen und Ausfällen, gefolgt von Gefriertrocknen übernommen, um Cellulose-Aerogele herzustellen. Verschiedene Bedingungen bei der Verarbeitung wie die Cellulose-Konzentration, Lösungsmittel zum Ausfällen und die Superbase und deren Effekt auf die Eigenschaften der Aerogele (Dichte, Morphologie und Porengröße) wurden untersucht. So wurden Aerogele mit einer Dichte von 0.05-1.20 g/cm3, Porositäten zwischen 92 und 97% und Porengrößen zwischen 1.1 und 4.5 µm erhalten. Zusätzlich wurden im Rasterelektronenmikroskop offene große und makroporöse, miteinander verbundene Cellulose-Netzwerke beobachtet. Die Derivatisierung von Cellulose zur Herstellung von thermisch verarbeitbaren Materialien wird im dritten Teil der Arbeit behandelt. Dieser Teil ist in die zwei Kapitel Umesterung und Modifizierung durch Multikomponenten-Reaktionen unterteilt. Im ersten Kapitel, und unter Berücksichtigung der Prinzipien der Nachhaltigen Chemie, ermöglichte die einzigartige Natur des DBU-CO2 schaltbaren Lösungsmittelsystems (Möglichkeit zur Änderung der Polarität) den direkten Einsatz von Sonnenblumenöl mit hohem Ölsäuregehalt in der Umesterung von Cellulose. Dieser Ansatz ist nachhaltiger als der übliche Einsatz von aktivierten Säurederivaten (z.B. Anhydride oder Säurechloride), die nicht nur giftig sind, sondern gleichermaßen im Voraus synthetisiert werden müssen. Es wurde ein Substitutionsgrad von 1.59 erreicht und die erhaltenen Fettsäure-Cellulose-Ester (FACEs) konnten zu Filmen mit guten mechanischen und thermischen Eigenschaften verarbeitet werden (E-Module von bis zu 478 MPa, maximale Spannung von 22 MPa, Zersetzungstemperaturen bis zu 368°C). Im zweiten Kapitel wurden Multikomponenten-Reaktionen (MCRs) eingesetzt, um multifunktionale, verarbeitbare Materialien auf Cellulosebasis zu synthetisieren. MCRs sind Eintopfreaktionen, weisen üblicherweise eine hohe Atomökonomie und Effizienz auf und benötigen keine Aufreinigung zwischen den Syntheseschritten. Der erste Ansatz, Cellulose direkt mit CO2 in einer Ugi Fünfkomponenten-Reaktion umzusetzen, war nicht erfolgreich. Ein indirekter Ansatz unter Verwendung von mit Bernsteinsäureanhydrid modifizierter Cellulose in der Ugi Vierkomponenten-Reaktion war jedoch erfolgreich. In diesem Fall wurden modifizierte Cellulosederivate mit hohem Molekulargewicht (193-242 kDa) erhalten, diese zeigten hohe Tg-Werte zwischen 99 und 116°C. Die Tg-Werte konnten durch einen einfachen Austausch der einzelnen Komponenten verändert werden. Um den Anwendungsbereich der Multikomponenten-Reaktionen zu erweitern, wurde anschließend die Passerini Vierkomponenten-Reaktion eingeführt. Der Schlüsselschritt in diesem Ansatz war das in-situ gebildete Carbonat-Ion im CO2 schaltbaren Lösungsmittelsystem, das die direkte Einführung von CO2 in die synthetisierte Verbindung ermöglichte. Dieser Ansatz, der eine Möglichkeit zur Fixierung von CO2 zur Herstellung nützlicher Verbindungen darstellt, ermöglicht auch den direkten Einsatz von verschiedenen Alkoholen (primär, sekundär, aromatisch, allylisch). Da viele Kohlenhydrate Hydroxygruppen enthalten, könnte diese Reaktion in der Zukunft neue Möglichkeiten für deren Modifikation eröffnen.

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    Doctoral thesis . 2019
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      https://dx.doi.org/10.5445/ir/...
      Doctoral thesis . 2019
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: M. Aaboud; G. Aad; B. Abbott; J. Abdallah; +196 Authors

    Multi-particle cumulants and corresponding Fourier harmonics are measured for azimuthal angle distributions of charged particles in $pp$ collisions at $\sqrt{s}$ = 5.02 and 13 TeV and in $p$+Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV, and compared to the results obtained for low-multiplicity Pb+Pb collisions at $\sqrt{s_{NN}}$ = 2.76 TeV. These measurements aim to assess the collective nature of particle production. The measurements of multi-particle cumulants confirm the evidence for collective phenomena in $p$+Pb and low-multiplicity Pb+Pb collisions. On the other hand, the $pp$ results for four-particle cumulants do not demonstrate collective behaviour, indicating that they may be biased by contributions from non-flow correlations. A comparison of multi-particle cumulants and derived Fourier harmonics across different collision systems is presented as a function of the charged-particle multiplicity. For a given multiplicity, the measured Fourier harmonics are largest in Pb+Pb, smaller in $p$+Pb and smallest in $pp$ collisions. The $pp$ results show no dependence on the collision energy, nor on the multiplicity. The European physical journal / C 77(6), 428 (2017). doi:10.1140/epjc/s10052-017-4988-1 Published by Springer, Berlin

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    Article . 2017
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