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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/

    This climate change impact data (future scenarios on temperature-induced GDP losses) and climate change mitigation cost data (REMIND model scenarios) is published under doi: 10.5281/zenodo.3541809 and used in this paper: Ueckerdt F, Frieler K, Lange S, Wenz L, Luderer G, Levermann A (2018) The economically optimal warming limit of the planet. Earth System Dynamics. https://doi.org/10.5194/esd-10-741-2019 Below the individual file contents are explained. For further questions feel free to write to Falko Ueckerdt (ueckerdt@pik-potsdam.de). Climate change impact data File 1: Data_rel-GDPpercapita-changes_withCC_per-country_all-RCP_all-SSP_4GCM.csv Content: Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, RCP (and a zero-emissions scenario), SSP and 4 GCMs (spanning a broad range of climate sensitivity). Negative (positive) values indicate losses (gains) due to climate change. For figure 1a of the paper, this data was aggregated for all countries. File 2: Data_rel-GDPpercapita-changes_withCC_per-country_all-SSP_4GCM_interpolated-for-REMIND-scenarios.csv Content: Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, SSP and 4 GCMs (spanning a broad range of climate sensitivity). The RCP (and a zero-emissions scenario) are interpolated to the temperature pathways of the ten REMIND model scenarios used for climate change mitigation costs. Hereby the set of scenarios for climate impacts and climate change mitigation are consistent and can be combined to total costs of climate change (for a broad range of mitigation action). File 3: Data_rel-GDPpercapita-changes_withCC_per-country_SSP2_12GCM_interpolated-for-REMIND-scenarios.csv Content: Same as file 2, but only for the SSP2 (chosen default scenario for the study) and for all 12 GCMs. Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, SSP-2 and 12 GCMs (spanning a broad range of climate sensitivity). The RCP (and a zero-emissions scenario) are interpolated to the temperature pathways of the ten REMIND model scenarios used for climate change mitigation costs. Hereby the set of scenarios for climate impacts and climate change mitigation are consistent and can be combined to total costs of climate change (for a broad range of mitigation action). In addition, reference GDP and population data (without climate change) for each country until 2100 was downloaded from the SSP database, release Version 1.0 (March 2013, https://tntcat.iiasa.ac.at/SspDb/, last accessed 15Nov 2019). Climate change mitigation cost data The scenario design and runs used in this paper have first been conducted in [1] and later also used in [2]. File 4: REMIND_scenario_results_economic_data.csv File 5: REMIND_scenarios_climate_data.csv Content: A broad range of climate change mitigation scenarios of the REMIND model. File 4 contains the economic data of e.g. GDP and macro-economic consumption for each of the countries and world regions, as well as GHG emissions from various economic sectors. File 5 contains the global climate-related data, e.g. forcing, concentration, temperature. In the scenario description “FFrunxxx” (column 2), the code “xxx” specifies the scenario as follows. See [1] for a detailed discussion of the scenarios. The first dimension specifies the climate policy regime (delayed action, baseline scenarios): 1xx: climate action from 2010 5xx: climate action from 2015 2xx climate action from 2020 (used in this study) 3xx climate action from 2030 4x1 weak policy baseline (before Paris agreement) The second dimension specifies the technology portfolio and assumptions: x1x Full technology portfolio (used in this study) x2x noCCS: unavailability of CCS x3x lowEI: lower energy intensity, with final energy demand per economic output decreasing faster than historically observed x4x NucPO: phase out of investments into nuclear energy x5x Limited SW: penetration of solar and wind power limited x6x Limited Bio: reduced bioenergy potential p.a. (100 EJ compared to 300 EJ in all other cases) x6x noBECCS: unavailability of CCS in combination with bioenergy The third dimension specifies the climate change mitigation ambition level, i.e. the height of a global CO2 tax in 2020 (which increases with 5% p.a.). xx1 0$/tCO2 (baseline) xx2 10$/tCO2 xx3 30$/tCO2 xx4 50$/tCO2 xx5 100$/tCO2 xx6 200$/tCO2 xx7 500$/tCO2 xx8 40$/tCO2 xx9 20$/tCO2 xx0 5$/tCO2 For figure 1b of the paper, this data was aggregated for all countries and regions. Relative changes of GDP are calculated relative to the baseline (4x1 with zero carbon price). [1] Luderer, G., Pietzcker, R. C., Bertram, C., Kriegler, E., Meinshausen, M. and Edenhofer, O.: Economic mitigation challenges: how further delay closes the door for achieving climate targets, Environmental Research Letters, 8(3), 034033, doi:10.1088/1748-9326/8/3/034033, 2013a. [2] Rogelj, J., Luderer, G., Pietzcker, R. C., Kriegler, E., Schaeffer, M., Krey, V. and Riahi, K.: Energy system transformations for limiting end-of-century warming to below 1.5 °C, Nature Climate Change, 5(6), 519–527, doi:10.1038/nclimate2572, 2015.

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    ZENODO
    Dataset . 2019
    License: CC BY
    Data sources: Datacite
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    ZENODO
    Dataset . 2019
    License: CC BY
    Data sources: ZENODO
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    ZENODO
    Dataset . 2019
    License: CC BY
    Data sources: Datacite
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      ZENODO
      Dataset . 2019
      License: CC BY
      Data sources: Datacite
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      ZENODO
      Dataset . 2019
      License: CC BY
      Data sources: ZENODO
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      ZENODO
      Dataset . 2019
      License: CC BY
      Data sources: Datacite
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Hussain, Mir Zaman; Robertson, G.Philip; Basso, Bruno; Hamilton, Stephen K.;

    Leaching dataset of dissolved organic carbon (DOC) and nitrogen (DON), nitrate (NO3+) and ammonium (NH4+) were collected from 6 cropping treatments (corn, switchgrass, miscanthus, native grass mix, restored prairie and poplar) established in the Bioenergy Cropping System Experiment (BCSE) which is a part of Great Lakes Bioenergy Research Center (www.glbrc.org) and Long Termn Ecological Research (LTER) program (www.lter.kbs.msu.edu). The site is located at the W.K. Kellogg Biological Station (42.3956° N, 85.3749° W and 288 m above sea level), 25 km from Kalamazoo in southwestern Michigan, USA. Prenart soil water samplers made of Teflon and silica (http://www.prenart.dk/soil-water-samplers/) were installed in blocks 1 and 2 of the BCSE (Fig. S1), and Eijkelkamp soil water samplers made of ceramic (http://www.eijkelkamp.com) were installed in blocks 3 and 4 (there were no soil water samplers in block 5). All samplers were installed at 1.2 m depth at a 45° angle from the soil surface, approximately 20 cm into the unconsolidated sand of the 2Bt2 and 2E/Bt horizons. Beginning in 2009, soil water was sampled at weekly to biweekly intervals during non-frozen periods (April to November) by applying 50 kPa of vacuum for 24 hours, during which water was collected in glass bottles. During the 2009 and 2010 sampling periods we obtained fewer soil water samples from blocks 1 and 2 where Prenart lysimeters were installed. We observed no consistent differences between the two sampler types in concentrations of the analytes reported here. Depending on the volume of leachate collected, water samples were filtered using either 0.45 µm pore size, 33-mm-dia. cellulose acetate membrane filters when volumes were <50 ml, or 0.45 µm, 47-mm-dia. Supor 450 membrane filters for larger volumes. Samples were analyzed for NO3-, NH4+, total dissolved nitrogen (TDN), and DOC. The NO3- concentration was determined using a Dionex ICS1000 ion chromatograph system with membrane suppression and conductivity detection; the detection limit of the system was 0.006 mg NO3--N L-1. The NH4+ concentration in the samples was determined using a Thermo Scientific (formerly Dionex) ICS1100 ion chromatograph system with membrane suppression and conductivity detection; the detection limit of the system was similar. The DOC and TDN concentrations were determined using a Shimadzu TOC-Vcph carbon analyzer with a total nitrogen module (TNM-1); the detection limit of the system was ~0.08 mg C L-1 and ~0.04 mg N L-1. DON concentrations were estimated as the difference between TDN and dissolved inorganic N (NO3- + NH4+) concentrations. The NH4+ concentrations were only measured in the 2013-2015 crop-years, but they were always small relative to NO3- and thus their inclusion or lack of it was inconsequential to the DON estimation. Leaching rates were estimated on a crop-year basis, defined as the period from planting or emergence of the crop in the year indicated through the ensuing year until the next year’s planting or emergence. For each sampling point, the concentration was linearly interpolated between sampling dates during non-freezing periods (April through November). The concentrations in the unsampled winter period (December through March) were also linearly interpolated based on the preceding November and subsequent April samples. Solute leaching (kg ha-1) was calculated by multiplying the daily solute concentration in pore-water (mg L -1) by the modeled daily drainage rates (m3 ha-1) from the overlying soil. The drainage rates were obtained using the SALUS (Systems Approach for Land Use Sustainability) model (Basso and Ritchie, 2015). SALUS simulates yield and environmental outcomes in response to weather, soil, management (planting dates, plant population, irrigation, nitrogen fertilizer application, tillage), and crop genetics. The SALUS water balance sub-model simulates surface run-off, saturated and unsaturated water flow, drainage, root water uptake, and evapotranspiration during growing and non-growing seasons (Basso and Ritchie, 2015). Drainage amounts and rates simulated by SALUS have been validated with measurements using large monolith lysimeters at a nearby site at KBS (Basso and Ritchie, 2005). On days when SALUS predicted no drainage, the leaching was assumed to be zero. The volume-weighted mean concentration for an entire crop-year was calculated as the sum of daily leaching (kg ha-1) divided by the sum of daily drainage rates (m3 ha-1). Weather data for the model were collected at the nearby KBS LTER meteorological station (lter.kbs.msu.edu). Leaching losses of dissolved organic carbon (DOC) and nitrogen (DON) from agricultural systems are important to water quality and carbon and nutrient balances but are rarely reported; the few available studies suggest linkages to litter production (DOC) and nitrogen fertilization (DON). In this study we examine the leaching of DOC, DON, NO3-, and NH4+ from no-till corn (maize) and perennial bioenergy crops (switchgrass, miscanthus, native grasses, restored prairie, and poplar) grown between 2009 and 2016 in a replicated field experiment in the upper Midwest U.S. Leaching was estimated from concentrations in soil water and modeled drainage (percolation) rates. DOC leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) among cropping systems averaged 15.4 and 4.6, respectively; N fertilization had no effect and poplar lost the most DOC (21.8 and 6.9, respectively). DON leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) under corn (the most heavily N-fertilized crop) averaged 4.5 and 1.0, respectively, which was higher than perennial grasses (mean: 1.5 and 0.5, respectively) and poplar (1.6 and 0.5, respectively). NO3- comprised the majority of total N leaching in all systems (59-92%). Average NO3- leaching (kg N ha-1 yr-1) under corn (35.3) was higher than perennial grasses (5.9) and poplar (7.2). NH4+ concentrations in soil water from all cropping systems were relatively low (<0.07 mg N L-1). Perennial crops leached more NO3- in the first few years after planting, and markedly less after. Among the fertilized crops, the leached N represented 14-38% of the added N over the study period; poplar lost the greatest proportion (38%) and corn was intermediate (23%). Requiring only one third or less of the N fertilization compared to corn, perennial bioenergy crops can substantially reduce N leaching and consequent movement into aquifers and surface waters. readme files are given that describe the data table

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    ZENODO
    Dataset . 2020
    License: CC 0
    Data sources: ZENODO
    DRYAD
    Dataset . 2020
    License: CC 0
    Data sources: Datacite
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      ZENODO
      Dataset . 2020
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      DRYAD
      Dataset . 2020
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  • Authors: Chan, Gabriel; Heeter, Jenny; Xu, Kaifeng;

    This data set is no longer current – The most current data and all historical data sets can be found at https://data.nrel.gov/submissions/244 This database represents a list of community solar projects identified through various sources as of Dec 2021. The list has been reviewed but errors may exist and the list may not be comprehensive. Errors in the sources e.g. press releases may be duplicated in the list. Blank spaces represent missing information. NREL invites input to improve the database including to - correct erroneous information - add missing projects - fill in missing information - remove inactive projects. Updated information can be submitted to the contact(s) located on the current data set page linked at the top.

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    Authors: Minx, Jan C.; Lamb, William F.; Andrew, Robbie M.; Canadell, Josep G.; +13 Authors

    Comprehensive and reliable information on anthropogenic sources of greenhouse gas emissions is required to track progress towards keeping warming well below 2°C as agreed upon in the Paris Agreement. Here we provide a dataset on anthropogenic GHG emissions 1970-2019 with a broad country and sector coverage. We build the dataset from recent releases from the “Emissions Database for Global Atmospheric Research” (EDGAR) for CO2 emissions from fossil fuel combustion and industry (FFI), CH4 emissions, N2O emissions, and fluorinated gases and use a well-established fast-track method to extend this dataset from 2018 to 2019. We complement this with information on net CO2 emissions from land use, land-use change and forestry (LULUCF) from three available bookkeeping models.

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    ZENODO
    Dataset . 2021
    License: CC BY
    Data sources: Datacite
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    ZENODO
    Dataset . 2021
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    ZENODO
    Dataset . 2021
    License: CC BY
    Data sources: Datacite
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      ZENODO
      Dataset . 2021
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      ZENODO
      Dataset . 2021
      License: CC BY
      Data sources: Datacite
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      ZENODO
      Dataset . 2021
      License: CC BY
      Data sources: Datacite
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    QTDIAN - Quantification of Technological DIffusion and sociAl constraiNts - is a toolbox of qualitative and quantitative descriptions of socio-technical and political aspects of the energy transition that influence the overall potential, the rate of energy-related technology and service diffusion and the design of the future energy system. The output of QTIDIAN is empirically founded datasets of social and political drivers and barriers of the transition, both in the form of raw data describing past and current developments and manipulated to constitute consistent quantifications of the storylines. Here you can download the data for six QTDIAN themes: Socially feasible scaling of energy technologies Policy preferences & dynamics Barriers to infrastructural development (wind energy, grid development) Citizen energy Private energy demand Further information on the QTDIAN modelling toolbox and the data can be found in the SENTINEL Deliverable 2.3 and Deliverable 2.4: S��sser, D., al Rakouki, H., & Lilliestam, J.(2021). The QTDIAN modelling toolbox���Quantification of social drivers and constraints of the diffusion of energy technologies. Deliverable 2.3. Sustainable Energy Transitions Laboratory (SENTINEL) project. Potsdam: Institute for Advanced Sustainability Studies (IASS). S��sser, D., Pickering, B., Chatterjee, S., Oreggioni, G., Stavrakas, V., & Lilliestam, J.(2021). Integration of socio-technological transition constraints into energy demand and systems models. Deliverable 2.5. Sustainable Energy Transitions Laboratory (SENTINEL) project. Potsdam: Institute for Advanced Sustainability Studies (IASS).

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    ZENODO
    Dataset . 2022
    License: CC BY
    Data sources: Datacite
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    ZENODO
    Dataset . 2022
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    Smithsonian figshare
    Dataset . 2021
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      ZENODO
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      ZENODO
      Dataset . 2022
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      ZENODO
      Dataset . 2021
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      ZENODO
      Dataset . 2022
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      Smithsonian figshare
      Dataset . 2021
      License: CC BY
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Dunn, Jessica; Slattery, Margaret; Kendall, Alissa; Ambrose, Hanjiro; +1 Authors

    Batteries have the potential to significantly reduce greenhouse gas emissions from on-road transportation. However, environmental and social impacts of producing lithium-ion batteries, particularly cathode materials, and concerns over material criticality are frequently highlighted as barriers to widespread electric vehicle adoption. Circular economy strategies, like reuse and recycling, can reduce impacts and secure regional supplies. To understand the potential for circularity, we undertake a dynamic global material flow analysis of pack-level materials that includes scenario analysis for changing battery cathode chemistries and electric vehicle demand. Results are produced regionwise and through the year 2040 to estimate the potential global and regional circularity of lithium, cobalt, nickel, manganese, iron, aluminum, copper, and graphite, although the analysis is focused on the cathode materials. Under idealized conditions, retired batteries could supply 60% of cobalt, 53% of lithium, 57% of manganese, and 53% of nickel globally in 2040. If the current mix of cathode chemistries evolves to a market dominated by NMC 811, a low cobalt chemistry, there is potential for 85% global circularity of cobalt in 2040. If the market steers away from cathodes containing cobalt, to an LFP-dominated market, cobalt, manganese, and nickel become less relevant and reach circularity before 2040. For each market to benefit from the recovery of secondary materials, recycling and manufacturing infrastructure must be developed in each region. This data was collected through various sources, including from EV Volumes, International Energy Agency, Argonne National Lab, and published articles. A model was created with R to process the data.  R is required to open the models.

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    ZENODO
    Dataset . 2023
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    Smithsonian figshare
    Dataset . 2021
    License: CC BY NC
    DRYAD
    Dataset . 2023
    License: CC 0
    Data sources: Datacite
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      ZENODO
      Dataset . 2023
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      Smithsonian figshare
      Dataset . 2021
      License: CC BY NC
      DRYAD
      Dataset . 2023
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  • Authors: Craig Kennedy; John Glenn; Natalie La Balme; Pierangelo Isernia; +2 Authors

    The aim of this study was to identify the attitudes of the public in the United States and in 12 European countries towards foreign policy issues and transatlantic issues. The survey concentrated on issues such as: United States and European Union (EU) leadership and relations, favorability towards certain countries, institutions and people, security, cooperation and the perception of threat including issues of concern with Afghanistan, Iran, and Russia, energy dependence, economic downturn, and global warming, Turkey and Turkish accession to the EU, promotion of democracy in other countries, and the importance of economic versus military power. Several questions asked of respondents pertained to voting and politics including whether they discussed political matters with friends and whether they attempted to persuade others close to them to share their views on politics which they held strong opinions about, vote intention, their assessment of the current United States President and upcoming presidential election, political party attachment, and left-right political self-placement. Demographic and other background information includes age, gender, race, ethnicity, religious affiliation and participation, age when stopped full-time education and stage at which full-time education completed, occupation, number of people aged 18 years and older living in the household, type of locality, region of residence, prior travel to the United States or Europe, and language of interview. computer-assisted personal interview (CAPI); computer-assisted telephone interview (CATI); paper and pencil interview (PAPI)The original data collection was carried out by TNS, Fait et Opinion -- Brussels on request of the German Marshall Fund of the United States.The codebook and setup files for this collection contain characters with diacritical marks used in many European languages.A split ballot was used for one or more questions in this survey. The variable SPLIT defines the separate groups.For data collection, the computer-assisted face-to-face interview was used in Poland, the paper and pencil interview was used in Bulgaria, Romania, Slovakia and Turkey, and the computer-assisted telephone interview was used in all other countries.Additional information on the Transatlantic Trends Survey is provided on the Transatlantic Trends Web site. (1) Multistage random sampling was implemented in the countries using face-to-face interviewing. Sampling points were selected according to region, and then random routes were conducted within these sampling points. Four callbacks were used for each address. The birthday rule was used to randomly select respondents within a household. (2) Random Digit Dialing was implemented in the countries using telephone interviewing. Eight callbacks were used for each telephone number. The birthday rule was used to randomly select respondents within a household. The adult population aged 18 years and over in 13 countries: Bulgaria, France, Germany, Italy, the Netherlands, Poland, Portugal, Romania, Slovakia, Spain, Turkey, the United Kingdom, and the United States. Smallest Geographic Unit: country Response Rates: The total response rate for all countries surveyed is 23 percent. Please refer to the "Technical Note" in the ICPSR codebook for additional information about response rate. Please refer to the "Technical Note" in the ICPSR codebook for further information about weighting. Datasets: DS1: Transatlantic Trends Survey, 2008

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  • Authors: Muehlegger, Erich; Rapson, David;

    Decarbonization of the transportation sector is particularly difficult due to its near-complete reliance on refined fossil fuels at present. In this paper, we describe the energy needs of the main transportation sectors worldwide: road transportation, aviation and maritime shipping. There is a growing commitment to electrification as the dominant decarbonization pathway. While deep electrification is promising (if by no means a certainty) for road transportation in wealthy countries, it will face steep obstacles in other sectors and in the developing world. Transportation decarbonization will require decoupling emissions from economic growth, highlighting the need for both accelerated technology innovation as well as creativity and cooperation in governance. The menu of policy options is replete with grim tradeoffs, particularly as the primacy of energy security and reliability (over emissions abatement) has once again been demonstrated in Europe and elsewhere. Aggregated vehicle ownership, emissions and electricity generate data for Countries and regions, worldwide.

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    Authors: Everall, Jordan; Ueckerdt, Falko;

    Material compiled for analysis in this paper: Ueckerdt F, Bauer C, Dirnaichner A, Everall J, Sacchi R, Luderer R (2021) Potential and risks of hydrogen-based e-fuels in climate change mitigation. Nature Climate Change. The material includes: 1) a spreadsheet file with technoeconomic data 2) an R Markdown script which is the source code for an interactive dashboard used to visualise (1) 3) a README file to assist with navigation of the data in (1) 1) The spreadsheet data contains CAPEX, efficiency and other supplementary data for small to large scale electrolysers for current, and future years. Data was collected based on a Literature Review of a variety of academic and industry sources conducted during the course of the title paper development. The data are differentiated by several categories including electrolysis method, source publication year and literature type. Care was taken to avoid recycled cost values, and to focus on the currency of the data, with values included to indicate the oldest reference year of any cited literature. 2) The R Markdown script in combination with the spreadsheet data is used as a basis for an interactive dashboard which can be run with an R installation and the supporting packages, or viewed online at https://h2.pik-potsdam.de/H2Dash/

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    ZENODO
    Dataset . 2021
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    ZENODO
    Dataset . 2021
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    ZENODO
    Dataset . 2021
    License: CC BY
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      Dataset . 2021
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      ZENODO
      Dataset . 2021
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  • Authors: Yinghui, Ren; Wenzhong, Shen; Jiachao, Bai;

    Six nitroguanidyl-functionalized nitrogen-rich compounds were synthesized and characterized by EA, FT-IR, 1H NMR and 13C NMR. In addition, the crystal structures of ANPTz, CABNG and FANG were further determined by X-ray single crystal diffractometer. The thermal decomposition behaviours were studied by DSC-TG-FTIR-MS coupling technique and the results showed that all the compounds had good thermal stability, among which ANPTz had the best thermal stability (Td=211.03 ℃). In addition, HCN, CO2, H2O and NO2 were released during thermal decomposition process. The self-accelerating decomposition temperature (TSADT) and thermal explosion critical temperature (Tb) were calculated to evaluate thermal safety, and the relative order was as follows: FANG (TSADT=198.68 ℃, Tb=209.97 ℃)> ANPTz (TSADT=194.12 ℃, Tb=208.63 ℃)> BANTz (TSADT=182.52 ℃, Tb=207.54 ℃)> AANG (TSADT=180.04 ℃, Tb=188.35 ℃)> CABNG (TSADT=176.80 ℃, Tb=187.32 ℃)> MABNG (TSADT=173.61 ℃, Tb=184.29 ℃). The results indicated that FANG had the acceptable sensitivity (IS=7.84 J), good detonation performance (D=8320 m·s-1, P=30.02 GPa), and the significant catalytic effect (the decomposition temperature of RDX decreased by 8.31 ℃). Six nitroguanidyl-functionalized nitrogen-rich compounds were synthesized and characterized by EA, FT-IR, 1H NMR and 13C NMR. In addition, the crystal structures of ANPTz, CABNG and FANG were further determined by X-ray single crystal diffractometer. The thermal decomposition behaviours were studied by DSC-TG-FTIR-MS coupling technique and the results showed that all the compounds had good thermal stability, among which ANPTz had the best thermal stability (Td=211.03 ℃). In addition, HCN, CO2, H2O and NO2 were released during thermal decomposition process. The self-accelerating decomposition temperature (TSADT) and thermal explosion critical temperature (Tb) were calculated to evaluate thermal safety, and the relative order was as follows: FANG (TSADT=198.68 ℃, Tb=209.97 ℃)> ANPTz (TSADT=194.12 ℃, Tb=208.63 ℃)> BANTz (TSADT=182.52 ℃, Tb=207.54 ℃)> AANG (TSADT=180.04 ℃, Tb=188.35 ℃)> CABNG (TSADT=176.80 ℃, Tb=187.32 ℃)> MABNG (TSADT=173.61 ℃, Tb=184.29 ℃). The results indicated that FANG had the acceptable sensitivity (IS=7.84 J), good detonation performance (D=8320 m·s-1, P=30.02 GPa), and the significant catalytic effect (the decomposition temperature of RDX decreased by 8.31 ℃).

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/

    This climate change impact data (future scenarios on temperature-induced GDP losses) and climate change mitigation cost data (REMIND model scenarios) is published under doi: 10.5281/zenodo.3541809 and used in this paper: Ueckerdt F, Frieler K, Lange S, Wenz L, Luderer G, Levermann A (2018) The economically optimal warming limit of the planet. Earth System Dynamics. https://doi.org/10.5194/esd-10-741-2019 Below the individual file contents are explained. For further questions feel free to write to Falko Ueckerdt (ueckerdt@pik-potsdam.de). Climate change impact data File 1: Data_rel-GDPpercapita-changes_withCC_per-country_all-RCP_all-SSP_4GCM.csv Content: Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, RCP (and a zero-emissions scenario), SSP and 4 GCMs (spanning a broad range of climate sensitivity). Negative (positive) values indicate losses (gains) due to climate change. For figure 1a of the paper, this data was aggregated for all countries. File 2: Data_rel-GDPpercapita-changes_withCC_per-country_all-SSP_4GCM_interpolated-for-REMIND-scenarios.csv Content: Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, SSP and 4 GCMs (spanning a broad range of climate sensitivity). The RCP (and a zero-emissions scenario) are interpolated to the temperature pathways of the ten REMIND model scenarios used for climate change mitigation costs. Hereby the set of scenarios for climate impacts and climate change mitigation are consistent and can be combined to total costs of climate change (for a broad range of mitigation action). File 3: Data_rel-GDPpercapita-changes_withCC_per-country_SSP2_12GCM_interpolated-for-REMIND-scenarios.csv Content: Same as file 2, but only for the SSP2 (chosen default scenario for the study) and for all 12 GCMs. Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, SSP-2 and 12 GCMs (spanning a broad range of climate sensitivity). The RCP (and a zero-emissions scenario) are interpolated to the temperature pathways of the ten REMIND model scenarios used for climate change mitigation costs. Hereby the set of scenarios for climate impacts and climate change mitigation are consistent and can be combined to total costs of climate change (for a broad range of mitigation action). In addition, reference GDP and population data (without climate change) for each country until 2100 was downloaded from the SSP database, release Version 1.0 (March 2013, https://tntcat.iiasa.ac.at/SspDb/, last accessed 15Nov 2019). Climate change mitigation cost data The scenario design and runs used in this paper have first been conducted in [1] and later also used in [2]. File 4: REMIND_scenario_results_economic_data.csv File 5: REMIND_scenarios_climate_data.csv Content: A broad range of climate change mitigation scenarios of the REMIND model. File 4 contains the economic data of e.g. GDP and macro-economic consumption for each of the countries and world regions, as well as GHG emissions from various economic sectors. File 5 contains the global climate-related data, e.g. forcing, concentration, temperature. In the scenario description “FFrunxxx” (column 2), the code “xxx” specifies the scenario as follows. See [1] for a detailed discussion of the scenarios. The first dimension specifies the climate policy regime (delayed action, baseline scenarios): 1xx: climate action from 2010 5xx: climate action from 2015 2xx climate action from 2020 (used in this study) 3xx climate action from 2030 4x1 weak policy baseline (before Paris agreement) The second dimension specifies the technology portfolio and assumptions: x1x Full technology portfolio (used in this study) x2x noCCS: unavailability of CCS x3x lowEI: lower energy intensity, with final energy demand per economic output decreasing faster than historically observed x4x NucPO: phase out of investments into nuclear energy x5x Limited SW: penetration of solar and wind power limited x6x Limited Bio: reduced bioenergy potential p.a. (100 EJ compared to 300 EJ in all other cases) x6x noBECCS: unavailability of CCS in combination with bioenergy The third dimension specifies the climate change mitigation ambition level, i.e. the height of a global CO2 tax in 2020 (which increases with 5% p.a.). xx1 0$/tCO2 (baseline) xx2 10$/tCO2 xx3 30$/tCO2 xx4 50$/tCO2 xx5 100$/tCO2 xx6 200$/tCO2 xx7 500$/tCO2 xx8 40$/tCO2 xx9 20$/tCO2 xx0 5$/tCO2 For figure 1b of the paper, this data was aggregated for all countries and regions. Relative changes of GDP are calculated relative to the baseline (4x1 with zero carbon price). [1] Luderer, G., Pietzcker, R. C., Bertram, C., Kriegler, E., Meinshausen, M. and Edenhofer, O.: Economic mitigation challenges: how further delay closes the door for achieving climate targets, Environmental Research Letters, 8(3), 034033, doi:10.1088/1748-9326/8/3/034033, 2013a. [2] Rogelj, J., Luderer, G., Pietzcker, R. C., Kriegler, E., Schaeffer, M., Krey, V. and Riahi, K.: Energy system transformations for limiting end-of-century warming to below 1.5 °C, Nature Climate Change, 5(6), 519–527, doi:10.1038/nclimate2572, 2015.

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    Authors: Hussain, Mir Zaman; Robertson, G.Philip; Basso, Bruno; Hamilton, Stephen K.;

    Leaching dataset of dissolved organic carbon (DOC) and nitrogen (DON), nitrate (NO3+) and ammonium (NH4+) were collected from 6 cropping treatments (corn, switchgrass, miscanthus, native grass mix, restored prairie and poplar) established in the Bioenergy Cropping System Experiment (BCSE) which is a part of Great Lakes Bioenergy Research Center (www.glbrc.org) and Long Termn Ecological Research (LTER) program (www.lter.kbs.msu.edu). The site is located at the W.K. Kellogg Biological Station (42.3956° N, 85.3749° W and 288 m above sea level), 25 km from Kalamazoo in southwestern Michigan, USA. Prenart soil water samplers made of Teflon and silica (http://www.prenart.dk/soil-water-samplers/) were installed in blocks 1 and 2 of the BCSE (Fig. S1), and Eijkelkamp soil water samplers made of ceramic (http://www.eijkelkamp.com) were installed in blocks 3 and 4 (there were no soil water samplers in block 5). All samplers were installed at 1.2 m depth at a 45° angle from the soil surface, approximately 20 cm into the unconsolidated sand of the 2Bt2 and 2E/Bt horizons. Beginning in 2009, soil water was sampled at weekly to biweekly intervals during non-frozen periods (April to November) by applying 50 kPa of vacuum for 24 hours, during which water was collected in glass bottles. During the 2009 and 2010 sampling periods we obtained fewer soil water samples from blocks 1 and 2 where Prenart lysimeters were installed. We observed no consistent differences between the two sampler types in concentrations of the analytes reported here. Depending on the volume of leachate collected, water samples were filtered using either 0.45 µm pore size, 33-mm-dia. cellulose acetate membrane filters when volumes were <50 ml, or 0.45 µm, 47-mm-dia. Supor 450 membrane filters for larger volumes. Samples were analyzed for NO3-, NH4+, total dissolved nitrogen (TDN), and DOC. The NO3- concentration was determined using a Dionex ICS1000 ion chromatograph system with membrane suppression and conductivity detection; the detection limit of the system was 0.006 mg NO3--N L-1. The NH4+ concentration in the samples was determined using a Thermo Scientific (formerly Dionex) ICS1100 ion chromatograph system with membrane suppression and conductivity detection; the detection limit of the system was similar. The DOC and TDN concentrations were determined using a Shimadzu TOC-Vcph carbon analyzer with a total nitrogen module (TNM-1); the detection limit of the system was ~0.08 mg C L-1 and ~0.04 mg N L-1. DON concentrations were estimated as the difference between TDN and dissolved inorganic N (NO3- + NH4+) concentrations. The NH4+ concentrations were only measured in the 2013-2015 crop-years, but they were always small relative to NO3- and thus their inclusion or lack of it was inconsequential to the DON estimation. Leaching rates were estimated on a crop-year basis, defined as the period from planting or emergence of the crop in the year indicated through the ensuing year until the next year’s planting or emergence. For each sampling point, the concentration was linearly interpolated between sampling dates during non-freezing periods (April through November). The concentrations in the unsampled winter period (December through March) were also linearly interpolated based on the preceding November and subsequent April samples. Solute leaching (kg ha-1) was calculated by multiplying the daily solute concentration in pore-water (mg L -1) by the modeled daily drainage rates (m3 ha-1) from the overlying soil. The drainage rates were obtained using the SALUS (Systems Approach for Land Use Sustainability) model (Basso and Ritchie, 2015). SALUS simulates yield and environmental outcomes in response to weather, soil, management (planting dates, plant population, irrigation, nitrogen fertilizer application, tillage), and crop genetics. The SALUS water balance sub-model simulates surface run-off, saturated and unsaturated water flow, drainage, root water uptake, and evapotranspiration during growing and non-growing seasons (Basso and Ritchie, 2015). Drainage amounts and rates simulated by SALUS have been validated with measurements using large monolith lysimeters at a nearby site at KBS (Basso and Ritchie, 2005). On days when SALUS predicted no drainage, the leaching was assumed to be zero. The volume-weighted mean concentration for an entire crop-year was calculated as the sum of daily leaching (kg ha-1) divided by the sum of daily drainage rates (m3 ha-1). Weather data for the model were collected at the nearby KBS LTER meteorological station (lter.kbs.msu.edu). Leaching losses of dissolved organic carbon (DOC) and nitrogen (DON) from agricultural systems are important to water quality and carbon and nutrient balances but are rarely reported; the few available studies suggest linkages to litter production (DOC) and nitrogen fertilization (DON). In this study we examine the leaching of DOC, DON, NO3-, and NH4+ from no-till corn (maize) and perennial bioenergy crops (switchgrass, miscanthus, native grasses, restored prairie, and poplar) grown between 2009 and 2016 in a replicated field experiment in the upper Midwest U.S. Leaching was estimated from concentrations in soil water and modeled drainage (percolation) rates. DOC leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) among cropping systems averaged 15.4 and 4.6, respectively; N fertilization had no effect and poplar lost the most DOC (21.8 and 6.9, respectively). DON leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) under corn (the most heavily N-fertilized crop) averaged 4.5 and 1.0, respectively, which was higher than perennial grasses (mean: 1.5 and 0.5, respectively) and poplar (1.6 and 0.5, respectively). NO3- comprised the majority of total N leaching in all systems (59-92%). Average NO3- leaching (kg N ha-1 yr-1) under corn (35.3) was higher than perennial grasses (5.9) and poplar (7.2). NH4+ concentrations in soil water from all cropping systems were relatively low (<0.07 mg N L-1). Perennial crops leached more NO3- in the first few years after planting, and markedly less after. Among the fertilized crops, the leached N represented 14-38% of the added N over the study period; poplar lost the greatest proportion (38%) and corn was intermediate (23%). Requiring only one third or less of the N fertilization compared to corn, perennial bioenergy crops can substantially reduce N leaching and consequent movement into aquifers and surface waters. readme files are given that describe the data table

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    ZENODO
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  • Authors: Chan, Gabriel; Heeter, Jenny; Xu, Kaifeng;

    This data set is no longer current – The most current data and all historical data sets can be found at https://data.nrel.gov/submissions/244 This database represents a list of community solar projects identified through various sources as of Dec 2021. The list has been reviewed but errors may exist and the list may not be comprehensive. Errors in the sources e.g. press releases may be duplicated in the list. Blank spaces represent missing information. NREL invites input to improve the database including to - correct erroneous information - add missing projects - fill in missing information - remove inactive projects. Updated information can be submitted to the contact(s) located on the current data set page linked at the top.

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    Authors: Minx, Jan C.; Lamb, William F.; Andrew, Robbie M.; Canadell, Josep G.; +13 Authors

    Comprehensive and reliable information on anthropogenic sources of greenhouse gas emissions is required to track progress towards keeping warming well below 2°C as agreed upon in the Paris Agreement. Here we provide a dataset on anthropogenic GHG emissions 1970-2019 with a broad country and sector coverage. We build the dataset from recent releases from the “Emissions Database for Global Atmospheric Research” (EDGAR) for CO2 emissions from fossil fuel combustion and industry (FFI), CH4 emissions, N2O emissions, and fluorinated gases and use a well-established fast-track method to extend this dataset from 2018 to 2019. We complement this with information on net CO2 emissions from land use, land-use change and forestry (LULUCF) from three available bookkeeping models.

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    QTDIAN - Quantification of Technological DIffusion and sociAl constraiNts - is a toolbox of qualitative and quantitative descriptions of socio-technical and political aspects of the energy transition that influence the overall potential, the rate of energy-related technology and service diffusion and the design of the future energy system. The output of QTIDIAN is empirically founded datasets of social and political drivers and barriers of the transition, both in the form of raw data describing past and current developments and manipulated to constitute consistent quantifications of the storylines. Here you can download the data for six QTDIAN themes: Socially feasible scaling of energy technologies Policy preferences & dynamics Barriers to infrastructural development (wind energy, grid development) Citizen energy Private energy demand Further information on the QTDIAN modelling toolbox and the data can be found in the SENTINEL Deliverable 2.3 and Deliverable 2.4: S��sser, D., al Rakouki, H., & Lilliestam, J.(2021). The QTDIAN modelling toolbox���Quantification of social drivers and constraints of the diffusion of energy technologies. Deliverable 2.3. Sustainable Energy Transitions Laboratory (SENTINEL) project. Potsdam: Institute for Advanced Sustainability Studies (IASS). S��sser, D., Pickering, B., Chatterjee, S., Oreggioni, G., Stavrakas, V., & Lilliestam, J.(2021). Integration of socio-technological transition constraints into energy demand and systems models. Deliverable 2.5. Sustainable Energy Transitions Laboratory (SENTINEL) project. Potsdam: Institute for Advanced Sustainability Studies (IASS).

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      ZENODO
      Dataset . 2022
      License: CC BY
      Data sources: Datacite
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      Smithsonian figshare
      Dataset . 2021
      License: CC BY
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Dunn, Jessica; Slattery, Margaret; Kendall, Alissa; Ambrose, Hanjiro; +1 Authors

    Batteries have the potential to significantly reduce greenhouse gas emissions from on-road transportation. However, environmental and social impacts of producing lithium-ion batteries, particularly cathode materials, and concerns over material criticality are frequently highlighted as barriers to widespread electric vehicle adoption. Circular economy strategies, like reuse and recycling, can reduce impacts and secure regional supplies. To understand the potential for circularity, we undertake a dynamic global material flow analysis of pack-level materials that includes scenario analysis for changing battery cathode chemistries and electric vehicle demand. Results are produced regionwise and through the year 2040 to estimate the potential global and regional circularity of lithium, cobalt, nickel, manganese, iron, aluminum, copper, and graphite, although the analysis is focused on the cathode materials. Under idealized conditions, retired batteries could supply 60% of cobalt, 53% of lithium, 57% of manganese, and 53% of nickel globally in 2040. If the current mix of cathode chemistries evolves to a market dominated by NMC 811, a low cobalt chemistry, there is potential for 85% global circularity of cobalt in 2040. If the market steers away from cathodes containing cobalt, to an LFP-dominated market, cobalt, manganese, and nickel become less relevant and reach circularity before 2040. For each market to benefit from the recovery of secondary materials, recycling and manufacturing infrastructure must be developed in each region. This data was collected through various sources, including from EV Volumes, International Energy Agency, Argonne National Lab, and published articles. A model was created with R to process the data.  R is required to open the models.

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    ZENODO
    Dataset . 2023
    License: CC 0
    Data sources: ZENODO
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    Smithsonian figshare
    Dataset . 2021
    License: CC BY NC
    DRYAD
    Dataset . 2023
    License: CC 0
    Data sources: Datacite
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      ZENODO
      Dataset . 2023
      License: CC 0
      Data sources: ZENODO
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      Smithsonian figshare
      Dataset . 2021
      License: CC BY NC
      DRYAD
      Dataset . 2023
      License: CC 0
      Data sources: Datacite
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  • Authors: Craig Kennedy; John Glenn; Natalie La Balme; Pierangelo Isernia; +2 Authors

    The aim of this study was to identify the attitudes of the public in the United States and in 12 European countries towards foreign policy issues and transatlantic issues. The survey concentrated on issues such as: United States and European Union (EU) leadership and relations, favorability towards certain countries, institutions and people, security, cooperation and the perception of threat including issues of concern with Afghanistan, Iran, and Russia, energy dependence, economic downturn, and global warming, Turkey and Turkish accession to the EU, promotion of democracy in other countries, and the importance of economic versus military power. Several questions asked of respondents pertained to voting and politics including whether they discussed political matters with friends and whether they attempted to persuade others close to them to share their views on politics which they held strong opinions about, vote intention, their assessment of the current United States President and upcoming presidential election, political party attachment, and left-right political self-placement. Demographic and other background information includes age, gender, race, ethnicity, religious affiliation and participation, age when stopped full-time education and stage at which full-time education completed, occupation, number of people aged 18 years and older living in the household, type of locality, region of residence, prior travel to the United States or Europe, and language of interview. computer-assisted personal interview (CAPI); computer-assisted telephone interview (CATI); paper and pencil interview (PAPI)The original data collection was carried out by TNS, Fait et Opinion -- Brussels on request of the German Marshall Fund of the United States.The codebook and setup files for this collection contain characters with diacritical marks used in many European languages.A split ballot was used for one or more questions in this survey. The variable SPLIT defines the separate groups.For data collection, the computer-assisted face-to-face interview was used in Poland, the paper and pencil interview was used in Bulgaria, Romania, Slovakia and Turkey, and the computer-assisted telephone interview was used in all other countries.Additional information on the Transatlantic Trends Survey is provided on the Transatlantic Trends Web site. (1) Multistage random sampling was implemented in the countries using face-to-face interviewing. Sampling points were selected according to region, and then random routes were conducted within these sampling points. Four callbacks were used for each address. The birthday rule was used to randomly select respondents within a household. (2) Random Digit Dialing was implemented in the countries using telephone interviewing. Eight callbacks were used for each telephone number. The birthday rule was used to randomly select respondents within a household. The adult population aged 18 years and over in 13 countries: Bulgaria, France, Germany, Italy, the Netherlands, Poland, Portugal, Romania, Slovakia, Spain, Turkey, the United Kingdom, and the United States. Smallest Geographic Unit: country Response Rates: The total response rate for all countries surveyed is 23 percent. Please refer to the "Technical Note" in the ICPSR codebook for additional information about response rate. Please refer to the "Technical Note" in the ICPSR codebook for further information about weighting. Datasets: DS1: Transatlantic Trends Survey, 2008

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  • Authors: Muehlegger, Erich; Rapson, David;

    Decarbonization of the transportation sector is particularly difficult due to its near-complete reliance on refined fossil fuels at present. In this paper, we describe the energy needs of the main transportation sectors worldwide: road transportation, aviation and maritime shipping. There is a growing commitment to electrification as the dominant decarbonization pathway. While deep electrification is promising (if by no means a certainty) for road transportation in wealthy countries, it will face steep obstacles in other sectors and in the developing world. Transportation decarbonization will require decoupling emissions from economic growth, highlighting the need for both accelerated technology innovation as well as creativity and cooperation in governance. The menu of policy options is replete with grim tradeoffs, particularly as the primacy of energy security and reliability (over emissions abatement) has once again been demonstrated in Europe and elsewhere. Aggregated vehicle ownership, emissions and electricity generate data for Countries and regions, worldwide.

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    Authors: Everall, Jordan; Ueckerdt, Falko;

    Material compiled for analysis in this paper: Ueckerdt F, Bauer C, Dirnaichner A, Everall J, Sacchi R, Luderer R (2021) Potential and risks of hydrogen-based e-fuels in climate change mitigation. Nature Climate Change. The material includes: 1) a spreadsheet file with technoeconomic data 2) an R Markdown script which is the source code for an interactive dashboard used to visualise (1) 3) a README file to assist with navigation of the data in (1) 1) The spreadsheet data contains CAPEX, efficiency and other supplementary data for small to large scale electrolysers for current, and future years. Data was collected based on a Literature Review of a variety of academic and industry sources conducted during the course of the title paper development. The data are differentiated by several categories including electrolysis method, source publication year and literature type. Care was taken to avoid recycled cost values, and to focus on the currency of the data, with values included to indicate the oldest reference year of any cited literature. 2) The R Markdown script in combination with the spreadsheet data is used as a basis for an interactive dashboard which can be run with an R installation and the supporting packages, or viewed online at https://h2.pik-potsdam.de/H2Dash/

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    ZENODO
    Dataset . 2021
    License: CC BY
    Data sources: Datacite
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    ZENODO
    Dataset . 2021
    License: CC BY
    Data sources: ZENODO
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    ZENODO
    Dataset . 2021
    License: CC BY
    Data sources: Datacite
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      ZENODO
      Dataset . 2021
      License: CC BY
      Data sources: Datacite
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      ZENODO
      Dataset . 2021
      License: CC BY
      Data sources: ZENODO
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      ZENODO
      Dataset . 2021
      License: CC BY
      Data sources: Datacite
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  • Authors: Yinghui, Ren; Wenzhong, Shen; Jiachao, Bai;

    Six nitroguanidyl-functionalized nitrogen-rich compounds were synthesized and characterized by EA, FT-IR, 1H NMR and 13C NMR. In addition, the crystal structures of ANPTz, CABNG and FANG were further determined by X-ray single crystal diffractometer. The thermal decomposition behaviours were studied by DSC-TG-FTIR-MS coupling technique and the results showed that all the compounds had good thermal stability, among which ANPTz had the best thermal stability (Td=211.03 ℃). In addition, HCN, CO2, H2O and NO2 were released during thermal decomposition process. The self-accelerating decomposition temperature (TSADT) and thermal explosion critical temperature (Tb) were calculated to evaluate thermal safety, and the relative order was as follows: FANG (TSADT=198.68 ℃, Tb=209.97 ℃)> ANPTz (TSADT=194.12 ℃, Tb=208.63 ℃)> BANTz (TSADT=182.52 ℃, Tb=207.54 ℃)> AANG (TSADT=180.04 ℃, Tb=188.35 ℃)> CABNG (TSADT=176.80 ℃, Tb=187.32 ℃)> MABNG (TSADT=173.61 ℃, Tb=184.29 ℃). The results indicated that FANG had the acceptable sensitivity (IS=7.84 J), good detonation performance (D=8320 m·s-1, P=30.02 GPa), and the significant catalytic effect (the decomposition temperature of RDX decreased by 8.31 ℃). Six nitroguanidyl-functionalized nitrogen-rich compounds were synthesized and characterized by EA, FT-IR, 1H NMR and 13C NMR. In addition, the crystal structures of ANPTz, CABNG and FANG were further determined by X-ray single crystal diffractometer. The thermal decomposition behaviours were studied by DSC-TG-FTIR-MS coupling technique and the results showed that all the compounds had good thermal stability, among which ANPTz had the best thermal stability (Td=211.03 ℃). In addition, HCN, CO2, H2O and NO2 were released during thermal decomposition process. The self-accelerating decomposition temperature (TSADT) and thermal explosion critical temperature (Tb) were calculated to evaluate thermal safety, and the relative order was as follows: FANG (TSADT=198.68 ℃, Tb=209.97 ℃)> ANPTz (TSADT=194.12 ℃, Tb=208.63 ℃)> BANTz (TSADT=182.52 ℃, Tb=207.54 ℃)> AANG (TSADT=180.04 ℃, Tb=188.35 ℃)> CABNG (TSADT=176.80 ℃, Tb=187.32 ℃)> MABNG (TSADT=173.61 ℃, Tb=184.29 ℃). The results indicated that FANG had the acceptable sensitivity (IS=7.84 J), good detonation performance (D=8320 m·s-1, P=30.02 GPa), and the significant catalytic effect (the decomposition temperature of RDX decreased by 8.31 ℃).

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