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The adenine nucleotide translocation in mitochondria has previously been established as an exchange between exogenous and endogenous adenine nucleotides across the inner membrane. The specificity and the control of the exchange are examined with the following major results: The adenine nucleotide translocation is relatively specific for exogenous ADP and ATP, AMP being nearly inactive. Among other nucleotides tested, only dADP and dATP exchange with a noticeable activity. In the controlled state ADP exchanges 2–4 times faster than ATP. If simultaneously added, ADP and ATP compete for the exchange, with ADP being about tenfold more active than ATP. The specificity of the exit of adenine nucleotides in the exchange is similar to the specificity of the entrance with the difference that ADP and ATP are released with equal activity in proportion to their intramitochondrial content. AMP is released only after a slow conversion to ADP. Therefore the short time exchange is limited by the endogenous content of ADP plus ATP. The exchange is influenced by the metabolic state of the mitochondria. The ATP exchange is more variable than the ADP exchange. Two effects are elucidated: (a) the influence of the metabolic state on the relative content of AMP which inhibits both the ADP and ATP exchange (b) the coupling of the energy transfer system which inhibits only the ATP exchange. An example for case (a) is the inhibition of the ADP and ATP exchange by arsenate and an example for case (b) is the strong increase of the ATP exchange on uncoupling. The following effects are relevant to the mechanism of the control of the exchange by ATP. The stimulation of the ATP exchange by uncoupler has the same concentration dependence as the uncoupling of oxidative phosphorylation (Km [CCP] = 0.08 μM, where CCP = carbonyl‐cyanide‐phenylhydrazone). Oligomycin does not abolish the uncoupler effect on the ATP exchange. “Endogenous uncoupling” on aging of mitochondria also stimulates the ATP exchange. Valinomycin plus K+ only slightly stimulate the ATP exchange. Anaerobiosis stimulates the ATP exchange to a smaller extent than uncoupling.In competition with ADP the effects of energy transfer on ATP exchange are more strongly revealed. On uncoupling the more than tenfold preference for ADP is fully abolished. It is concluded that basically the exchange for ADP and ATP has equal specificity in forward and reverse reaction. In the controlled state a superimposed force makes the specificity asymmetric and inhibits the entrance of ATP. This control of the ATP exchange is concluded to be based on the anionic character of the adenine nucleotides. Thus the ATP4‐ex–ADP3‐in exchange is inhibited unless the charge difference is compensated for by an uncoupler stimulated H+ movement across the membrane. Furthermore an electric potential gradient appears to be effective in the controlled state which is abolished on uncoupling.

Currently used analytical tools and indicators of macroeconomic development of the country do not adequately reflect environmental concerns. We need to improve the methodological basis of macroeconomic statistics of the natural environment and its relationships with agriculture to obtain more reliable information about the condition of a particular region. The paper proposes the formulation of macroeconomic accounts from the municipal level to aggregated information at the level of region and country. For example, the assets accounts for land cover and soil resources are developed according to cartographic survey of the Borovsk district of Kaluga region. In general, the developed base map is enough to make most accounts (balance sheet) assets land and soil resources. However, for a more complete and comprehensive reflection of soil resources in physical terms it is recommended to add indicators of soil properties that represent the physical, chemical and biological characteristics of soil, like porosity, structure, pH level and microbial biomass.

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The paper presents an experimental study on the formation process of burden surface texture on the blast furnace throat and its influence on the radial distribution of gas flow. The study was performed with the application of blast furnaces equipped with a bell-type charging device using radio-isotope means for the control of burden surface texture (profile) and burden surface level, i.e., gamma locators for burden surface texture. The study was carried out under the conditions of an operating blast furnace in an iron and steel plant using a unique GEOTAPS system for automated control of geometric and temperature parameters of burden material surface on the blast furnace throat. The influence of the surface texture on the gas flow distribution was also investigated. The possibility of a self-stabilization effect for burden surface texture and gas flow in an operating blast furnace under suitable conditions was experimentally proven. As a result of the experimental study performed, four ways of energy-saving technology implementation were determined for the control of blast furnace melting based on the data on the burden surface texture and previously unknown regularities of surface layer formation of burden material on the throat of an operating blast furnace with a bell-type charging device. The main idea of the paper is the development of automated control for the radial distribution of burden material and gas flow using actual or predicted surface texture parameters as important intermediate factors that both describe the process and have a significant simultaneous influence on it.

Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

Progressive urban density affects city centers especially and results in growing congestion, lack of parking spaces, and increasing environmental costs of transportation, causing increased air pollutant emissions and noise. These phenomena reduce the attractiveness of the city and result in a degradation of the quality of life for its residents. In light of these phenomena, there is a clear need for intelligent management of urban space using new technologies that would be complementary to existing intelligent transportation systems. Expanding information resources obtained from mobile cameras will have a positive impact on increasing the efficiency of transportation management and use of limited space in city centers. It will also have an impact on reducing external transport costs and increasing the quality of logistics services provided in the city. The main aim of the paper is to develop a concept of a transport management system in cities using mobile vision systems mounted on unmanned aerial vehicles. The model will concern the cases of lane occupation by freight vehicles and the analysis of parking spaces in the city in order to improve their management. The results of the developed model will contribute to the automation of the parking space management process and increase the efficiency of the use of city parking space resources.

Abstract. Flooding in the Amazon basin is frequently attributed to modes of large-scale climate variability, but little attention is paid to how these modes influence the timing and duration of floods despite their importance to early warning systems and the significant impacts that these flood characteristics can have on communities. In this study, river discharge data from the Global Flood Awareness System (GloFAS 2.1) and observed data at 58 gauging stations are used to examine whether positive or negative phases of several Pacific and Atlantic indices significantly alter the characteristics of river flows throughout the Amazon basin (1979–2015). Results show significant changes in both flood magnitude and duration, particularly in the north-eastern Amazon for negative El Niño–Southern Oscillation (ENSO) phases when the sea surface temperature (SST) anomaly is positioned in the central tropical Pacific. This response is not identified for the eastern Pacific index, highlighting how the response can differ between ENSO types. Although flood magnitude and duration were found to be highly correlated, the impacts of large-scale climate variability on these characteristics are non-linear; some increases in annual flood maxima coincide with decreases in flood duration. The impact of flood timing, however, does not follow any notable pattern for all indices analysed. Finally, observed and simulated changes are found to be much more highly correlated for negative ENSO phases compared to the positive phase, meaning that GloFAS struggles to accurately simulate the differences in flood characteristics between El Niño and neutral years. These results have important implications for both the social and physical sectors working towards the improvement of early warning action systems for floods.