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The principles of pulse electrolysis modes selection and their effect on the size distribution of the powder electrolytic copper in electrolyte with additions of water-soluble polymers, polyvinylpyrrolidone (PVP) and polyacrylamide (PAA) are considered in the paper. The research conducted with use of chronopotentiometry and potential transients as well as a simulation model of the electrocrystallisation process showed that the values of pulse duration were greater than the transient time of electroactive species and the pause duration equal to the linear part of potential transient was optimum to obtain a powder with a predominant fraction of nanoscale particles . PVP and PAA additives help to reduce the average particle size in the nanoscale fraction copper powder particles to 25-40 nm. Selected current pulse mode effect corresponds to the reduction of the emergence of new centers of crystallization probability and the adatoms on the surface of the cathode movement probability.

Economic emancipation depends on energy accessibility, affordability, and sustainability for now and for future generations, mainly because of the crucial role played by energy services. For the trend to continue there is an urgent need to secure clean, modern, affordable, reliable, and sustainable energy sources for all people and all societies, while reducing emissions from greenhouse gasses and other carbon footprints linked with energy. All energy resources, whether renewable or nonrenewable, are harvested from the environment and as a result impact the environment. The paper highlights the need to explore energy resources in a sustainable manner. The study further evaluates existing metrics to track and ascertain energy sustainability in a sustainable development context. In methodological terms, the authors conduct a literature review to enable the authors to arrive with best suggestions. Several factors were considered as pragmatic steps needed to achieve energy sustainability. Energy access, energy sustainability indicators, and innovation were appraised to aid energy sustainability for now and for future generations.

Understanding the emergence and subsequent spread of human infectious diseases is a critical global challenge, especially for high-impact zoonotic and vector-borne diseases. Global climate and land-use change are likely to alter host and vector distributions, but understanding the impact of these changes on the burden of infectious diseases is difficult. Here, we use a Bayesian spatial model to investigate environmental drivers of one of the most important diseases in Africa, Rift Valley fever (RVF). The model uses a hierarchical approach to determine how environmental drivers vary both spatially and seasonally, and incorporates the effects of key climatic oscillations, to produce a continental risk map of RVF in livestock (as a proxy for human RVF risk). We find RVF risk has a distinct seasonal spatial pattern influenced by climatic variation, with the majority of cases occurring in South Africa and Kenya in the first half of an El Niño year. Irrigation, rainfall and human population density were the main drivers of RVF cases, independent of seasonal, climatic or spatial variation. By accounting more subtly for the patterns in RVF data, we better determine the importance of underlying environmental drivers, and also make space- and time-sensitive predictions to better direct future surveillance resources. This article is part of the themed issue ‘One Health for a changing world: zoonoses, ecosystems and human well-being’.

Despite economic development and social improvements, millions of family farmers in Ethiopia are still struggling with food insecurity. Lack of technology adoption by family farmers is often considered as the root cause for low agricultural productivity and persistence of food insecurity. Based on a study of family farms in southwestern Ethiopia, we show the complex nexus between family farming, food insecurity, and agricultural productivity. We collected qualitative and quantitative data through 300 sample household interviews; expert interviews with elders and village chairmen, agricultural extension agents, farmers’ cooperative heads, as well as experts in NGOs, research institutes, and state agencies; and on-farm observations with in-depth interviews and discussions with individual farmers. Our findings illustrate that everyday experiences, culture, knowledge, and priorities of farmers coupled with ecological and political factors play crucial roles—and need more consideration than the classic ‘lack of technology’ theorem.

Granulocyte colony-stimulating factor (G-CSF) has immunomodulating properties that could be beneficial for adjunctive treatment of severe infections. Cytokine release from stimulated whole blood and expression of neutrophil surface and apoptosis markers in response to G-CSF were studied in human volunteers under physiologic conditions and after ethanol pretreatment. Levels of interleukin (IL)-1 receptor antagonist and soluble tumor necrosis factor (TNF) receptor-1 were significantly increased after G-CSF, whereas TNF-alpha and IL-10 concentrations were reduced, and IL-1beta and IL-8 remained unchanged. There was a significant inhibition of neutrophil apoptosis and increased expression of complement regulatory protein CD55 without changes in CD11b, CD14, and CD59 expression. These effects were well preserved after ethanol pretreatment, which per se led to an increase in apoptosis and decreased CD55 expression. Thus, G-CSF treatment was associated with a reduction of the proinflammatory cytokine response and enhanced neutrophil survival in vivo, suggesting a therapeutic potential of G-CSF for severe infections in the nonneutropenic host.

This paper presents estimates of the economic benefit of air quality improvements in Europe that occur as a side effect of GHG emission reductions. We consider three climate policy scenarios that reach radiative forcing levels in 2100 of three Representative Concentration Pathways (RCPs). These targets are achieved by introducing a global uniform tax on all GHG emissions in the Integrated Assessment Model WITCH, assuming both full as well as limited technological flexibility. The resulting consumption patterns of fossil fuels are used to estimate the physical impacts and the economic benefits of pollution reductions on human health and on key assets by implementing the most advanced version of the ExternE methodology with its Impact Pathway Analysis. We find that the mitigation scenario compatible with 2°C reduces total pollution costs in Europe by 76%. Discounted ancillary benefits are more than €2.5 trillion between 2015 and 2100. The monetary value of reduced pollution is equal to €22 per abated ton of CO2 in Europe. Less strict climate policy scenarios generate overall smaller, but still considerable, local benefits (14 € or 18 € per abated ton of CO2). Without discounting, the ancillary benefits are in a range of €36 to €50 per ton of CO2 abated. Cumulative ancillary benefits exceed the cumulative additional cost of electricity generation in Europe. Each European country alone would be better off if the mitigation policy was implemented, although the local benefits in absolute terms vary significantly across the countries. We can identify the relative losers and winners of ancillary benefits in Europe. In particular, we find that large European countries contribute to as much as they benefit from ancillary benefits. The scenarios with limited technology flexibility do deliver results that are similar to the full technology flexibility scenario.

Perspective on recent improvements in experiment and theory towards realizing lithium metal electrodes with liquid electrolytes.