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This work is a small effort in the production of an eco-friendly natural based antibacterial and anti-inflammatory finished cotton fabrics using the ethanolic extracts (Ex) of the sea grass Halophila stipulacea (H. stipulacea) and marine macroalgae [Colbomenia sinuosa (C. sinuosa) and Ulva fasciata (U. fasciata)]. The extracts were phytochemically screened for their constituents. These extracts were used to finish cotton fabrics by a variety of methods. Concerning this, fabrics (F) were singly treated with ethanolic extracts (ExF) of these marine organisms by the dip technique and the extract encapsulated with sodium alginate or meypro gum. The encapsulated fabric (EnF) was further finished individually with citric acid (CA), (EnF/CA) and mono-tert-butyl ether of glycerol (MTBG) binder (EnF/Bin) by the pad-dry-cure technique. The fabrics so-finished were evaluated for their antibacterial and anti-inflammatory activities without washing (control) and after different washing cycles. The results obtained showed that, both EnF/CA and EnF/Bin inhibit the bacterial growth by about 90% after 10 washing cycles for both Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The anti-inflammatory activity, the potency% reached to 88.3% for the fabric encapsulated with microcapsules of sodium alginate/H. stipulacea sea grass and the EnF/CA.

The global water shortage alert has been upgraded to a higher risk level. Consequently, a sustainable approach for ecofriendly, energy efficient water desalination is required for agricultural and municipal water reuse. In this study, an energy-efficient biological desalination process was used to treat chloride anions, which are the most abundant anion salt in seawater. Three algal species were studied: Scenedismus arcuatusa (S. arcuatusa), Chlorella vulgaris (C. vulgaris), and Spirulina maxima (Sp. maxima), under different operating conditions (saline concentrations, contact time, high light intensity, and CO2 supply), and two kinetic models were used. It was identified that under a high light intensity and CO2 supply, S. arcuatusa enhanced chloride removal from 32.42 to 48.93%; the daily bioaccumulation capacity (Qe), according to the kinetic models, was enhanced from 124 to 210 mg/g/day; and the net biomass production was enhanced from 0.02 to 0.740 g/L. The EDX analysis proved that salt bioaccumulation may be attributed to the replacement of Ca2+ and Mg2+ with Na+ and K+ through algal cells. The study’s findings provide promising data that can be used in the search for novel energy-efficient alternative ecofriendly desalination technologies based on algae biological systems with biomass byproducts that can be reused in a variety of ways.

AbstractFormation of electrogenic microbial biofilm on the electrode is critical for harvesting electrical power from wastewater in microbial biofuel cells (MFCs). Although the knowledge of bacterial community structures in the biofilm is vital for the rational design of MFC electrodes, an in-depth study on the subject is still awaiting. Herein, we attempt to address this issue by creating electrogenic biofilm on modified graphite anodes assembled in an air–cathode MFC. The modification was performed with reduced graphene oxide (rGO), polyaniline (PANI), and carbon nanotube (CNTs) separately. To accelerate the growth of the biofilm, soybean-potato composite (plant) powder was blended with these conductive materials during the fabrication of the anodes. The MFC fabricated with PANI-based anode delivered the current density of 324.2 mA cm−2, followed by CNTs (248.75 mA cm−2), rGO (193 mA cm−2), and blank (without coating) (151 mA cm−2) graphite electrodes. Likewise, the PANI-based anode supported a robust biofilm growth containing maximum bacterial cell densities with diverse shapes and sizes of the cells and broad metabolic functionality. The alpha diversity of the biofilm developed over the anode coated with PANI was the loftiest operational taxonomic unit (2058 OUT) and Shannon index (7.56), as disclosed from the high-throughput 16S rRNA sequence analysis. Further, within these taxonomic units, exoelectrogenic phyla comprising Proteobacteria, Firmicutes, and Bacteroidetes were maximum with their corresponding level (%) 45.5, 36.2, and 9.8. The relative abundance of Gammaproteobacteria, Clostridia, and Bacilli at the class level, while Pseudomonas, Clostridium, Enterococcus, and Bifidobacterium at the genus level were comparatively higher in the PANI-based anode.

The freshwater environment suffers from a combination of stressors; pollution and global warming. Multiple effects of copper sulfate, cadmium chloride, and lead nitrate Pb were studied on Nile tilapia under three temperatures ranges, compared to bioremediation using effective microorganisms (EMs). The fish were divided into eight groups, with each group exposed to three temperatures (24, 28, and 32°C). Water physicochemical parameters were measured, and fish hematological, physiological, and biochemical changes were considered. Water quality parameters revealed a significant increase in both electrical conductivity and total dissolved solids in the EM/Cu fish group in the Cu fish group at 32°C. The chemical oxygen demand levels indicated a remarkable fluctuation with a slight decrease in the control group (at 28°C) while reduced in the control and EM. The results were highly significant incomplete blood cells, total red blood cell count, hemoglobin concentration (Hb), hematocrit, mean corpuscular Hb, mean corpuscular Hb concentration, and total protein (g/dl) in the EM group and control group. It can be concluded that using EM in fish farms (1:1000) could help fish adapt to different temperatures and reduce the effects of toxic pollutants.

Abstract Background Nanomaterials have emerged as a fascinating class of materials in high demand for a variety of practical applications. They are classified based on their composition, dimensions, or morphology. For the synthesis of nanomaterials, two approaches are used: top-down approaches and bottom-up approaches. Main body of the abstract Nanoscale materials and structures have the potential to be used in the production of newly developed devices with high efficiency, low cost, and low energy demand in a variety of applications. There are several contributions in renewable energy conversion and storage in the energy sector, such as solar photovoltaic systems, fuel cells, solar thermal systems, lithium-ion batteries, and lighting. Furthermore, nanofluid-based solar collectors are a new generation of solar collectors based on the use of nanotechnology. It has the potential to increase collector efficiency by up to 30%. Short conclusion Graphene and graphene derivatives are known as more efficient energy-saving materials, with the ability to maximize heat transfer efficiency and save up to 30% of energy in water desalination. Silver nanoparticles (Ag NPs) are a powerful antibacterial material that can kill a wide variety of microorganisms. They are commonly used in water treatment and are incorporated into polyethersulfone (PES) microfiltration membranes. The use of an Ag-PES membrane improved the antibiofouling performance of PES membranes. From the industrial application of nanotechnology, applications of TiO2-based nanocoatings that can be used as dust-repellent coatings for solar panels improve their efficiency and reduce the amount of required maintenance. Furthermore, the nanoscale dimension of these particles facilitates their movement in various body parts, resulting in serious diseases such as cancer and organ damage. As a result, it is suggested to focus in our incoming research on the disposal of nanomaterial waste and their safe application.

AbstractHexavalent chromium [Cr(VI)] is one of the most carcinogenic and mutagenic toxins, and is commonly released into the environemt from different industries, including leather tanning, pulp and paper manufacturing, and metal finishing. This study aimed to investigate the performance of dual chamber microbial fuel cells (DMFCs) equipped with a biocathode as alternative promising remediation approaches for the biological reduction of hexavalent chromium [Cr(VI)] with instantaneous power generation. A succession batch under preliminary diverse concentrations of Cr(VI) (from 5 to 60 mg L−1) was conducted to investigate the reduction mechanism of DMFCs. Compared to abiotic-cathode DMFC, biotic-cathode DMFC exhibited a much higher power density, Cr(VI) reduction, and coulombic efficiency over a wide range of Cr(VI) concentrations (i.e., 5–60 mg L−1). Furthermore, the X-ray photoelectron spectroscopy (XPS) revealed that the chemical functional groups on the surface of biotic cathode DMFC were mainly trivalent chromium (Cr(III)). Additionally, high throughput sequencing showed that the predominant anodic bacterial phyla were Firmicutes, Proteobacteria, and Deinococcota with the dominance of Clostridiumsensu strict 1, Enterobacter, Pseudomonas, Clostridiumsensu strict 11 and Lysinibacillus in the cathodic microbial community. Collectively, our results showed that the Cr(VI) removal occurred through two different mechanisms: biosorption and bioelectrochemical reduction. These findings confirmed that the DMFC could be used as a bioremediation approach for the removal of Cr(VI) commonly found in different industrial wastewater, such as tannery effluents. with simultaneous bioenergy production.

Microbial fuel cells (MFCs) have significant interest in the research community due to their ability to generate electricity from biodegradable organic matters. Anode materials and their morphological structures play a crucial role in the formation of electroactive biofilms that enable the direct electron transfer. In this work, modified electrodes with nanomaterials, such as multiwalled carbon nanotubes (MWCNTs), reduced graphene oxide (rGO), Al2O3/rGO or MnO2/MWCNTs nanocomposites were synthesized, characterized and utilized to support the growth of electrochemically active biofilms. The MFC's performance is optimized using anode-respiring strains isolated from biofilm-anode surface, while the adjusted operation is conducted with the consortium of (Enterobacter sp.). Besides the formation of matured biofilm on its surface, MnO2/MWCNTs nanocomposite produced the highest electrical potential outputs (710 mV) combined with the highest power density (372 mW/m2). Thus, a correlation between the anode nanostructured materials and the progression of the electrochemically active biofilms formation is presented, allowing new thoughts for enhancing the MFC's performance for potential applications ranging from wastewater treatment to power sources.

Over the past 4 decades, the increasing amounts of excess sludge from municipal wastewater treatment plants (WWTPs) represent a challenge toward achieving the sustainability of the drinking water and sanitation sector in Egypt, resulting in a serious environmental pollution due to the uncontrolled use of non-stabilized sludge. Here, we report a comprehensive overview on the current situation of excess sludge production, management, and disposal in Egypt. Owing to the technologies used for wastewater treatment in Egypt that mainly consist of activated sludge based-technologies, about 2.1 million tons of dry solids is produced annually. The majority of WWTPs in Egypt lack proper sludge stabilization facilities, except for the WWTPs in high living standards governorates (e.g., Cairo, Alexandria, and Giza). Therefore, about 85% of the non-stabilized sludge is improperly disposed and directly used for agricultural purposes. Despite the importance of managing the use of non- and/or partially-treated sludge, especially for agricultural purposes, the national legislations for sludge disposal/reuse in Egypt are incomplete and, in practice, they are not reinforced. In order to evaluate the most sustainable scenario for sludge management in Egypt, a qualitative decision-support system (DSS) was used. The DSS framework was refined and estimated, based on several evaluating categories, and used to guide the decision process towards achieving sustainable management of municipal wastewater sludge in Egypt. The results reveals that “sludge-to-energy” through anaerobic digestion is the most sustainable scenario for sludge disposal and management in Egypt. The anaerobic digestion-based technology seems to offer advantages of interest at affordable costs, such as the production of renewable energy, stabilized soil conditioners, and fertilizers for agricultural purposes.