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Abstract Three-dimensional (3D) metal halide perovskite solar cells (PSCs) have a power conversion efficiency that is now comparable with conventional silicon solar cells. For PSC applications to succeed in the market, long-term reliability under open-air conditions is essential. Recent experiments have shown that two-dimensional (2D) perovskites seem to exhibit good stability due to the presence of hydrophobic organic spacers, but 2D PSCs are incapable of generating and transporting a large amount of charge due to their extended optical bandgaps. Mixed dimensional perovskites with dimension lies between 2D and 3D recently became a promising candidate to sustain long-term stability and high performances concurrently to address this obstacle. The current research article presents the finding of simulation-based studies performed on novel device architecture consisting of ITO/Nb-Ti2O3/3D Perovskite/2D Perovskite/Spiro-OMeTAD/Au. Using optical simulation features of SCAPS, absorption of light is computed in the proposed device. The computational results show that the thickness of the 2D perovskite layer badly affects the solar cell parameters. A thin 2D perovskite behaves as a capped coating that avoids the deterioration of 3D perovskite in open-air environments. The effect of a multivalent defect in the 3D perovskite layer is mathematically modelled, and their impact on overall performance parameters are analyzed. The findings are compared to the same configuration results, except where the absorber layer’s multivalent defect has been substituted by a neutral defect of the same defect density of about (1011 cm−3). Results show that the multivalent defect leads to an underestimation of the efficiency by 4.2%.

Background: Climate change has been shown to be directly linked to multiple physiological sequelae and to impact health consequences. However, the impact of climate change on mental health globally, particularly among vulnerable populations, is less well understood. Objective: To explore the mental health impacts of climate change in vulnerable populations globally. Methods: We performed an integrative literature review to identify published articles that addressed the research question: What are the mental health impacts of climate change among vulnerable populations globally? The Vulnerable Populations Conceptual Model served as a theoretical model during the review process and data synthesis. Findings/Results: One hundred and four articles were selected for inclusion in this review after a comprehensive review of 1828 manuscripts. Articles were diverse in scope and populations addressed. Land-vulnerable persons (either due to occupation or geographic location), Indigenous persons, children, older adults, and climate migrants were among the vulnerable populations whose mental health was most impacted by climate change. The most prevalent mental health responses to climate change included solastalgia, suicidality, depression, anxiety/eco-anxiety, PTSD, substance use, insomnia, and behavioral disturbance. Conclusions: Mental health professionals including physicians, nurses, physician assistants and other healthcare providers have the opportunity to mitigate the mental health impacts of climate change among vulnerable populations through assessment, preventative education and care. An inclusive and trauma-informed response to climate-related disasters, use of validated measures of mental health, and a long-term therapeutic relationship that extends beyond the immediate consequences of climate change-related events are approaches to successful mental health care in a climate-changing world.

El presente artículo surge de la necesidad de desvelar la influencia del desarrollo turístico en las dimensiones del desarrollo sostenible de la comunidad de Caibarién (Cuba). La información se obtuvo mediante revisión documental y entrevistas semi estructuradas. Los fundamentos teóricos y metodológicos que soportan el tratamiento de este trabajo se estructuran a partir de la producción científica relativa a los temas del desarrollo turístico y el turismo sostenible. Los principales resultados mostraron que la estrategia de desarrollo de Gaviota S.A en los Cayos de Villa Clara, influye indirectamente en la sostenibilidad de la comunidad de Caibarién, lo cual coincide con lo que plantea la literatura académica y presenta su pertinencia también para el caso de Cuba, cuya organización socioeconómica y política se distancia del paradigma neoliberal global. Si bien existen algunas pautas que muestran una tendencia hacia el desarrollo sostenible, aún se identifican aspectos negativos en el modelo de desarrollo turístico que habrán de ser considerados tanto en futuras investigaciones como en sus implicaciones prácticas en la industria turística de Cuba y de otras latitudes. This article arises from the need to reveal the influence of tourism development on the dimensions of sustainable development in the community of Caibarién, Cuba. The information was obtained through documentary review and semi-structured interviews. The theoretical and methodological foundations that support the treatment of the subject are structured from the scientific production related to the topics of tourism development and sustainable tourism. The main results showed that the development strategy of Gaviota SA in the Villa Clara Keys, indirectly influences the sustainability of the Caibarién community, which coincides with what is stated in the academic literature and is also relevant for the case of Cuba, whose socio-economic and political organization distances itself from the global neoliberal paradigm. Although there are elements that show a trend towards sustainable development, negative aspects were still identified as a consequence of the presence of tourism development that will have to be considered both in future research and in its practical implications in the tourism industry of the Island and of other latitudes.

The annual production of plastic waste worldwide has doubled in just two decades, with approximately 390 million tonnes of plastic waste now being generated. In this context, the construction industry must move towards the development of new, more sustainable materials made under circular economy criteria. In this work, a physico-mechanical characterisation of gypsum composites with the incorporation of high-density polyethylene (HDPE) waste, replacing 2–4–6–8–10% by volume of the original raw material, has been conducted. The results show how the incorporation of these plastic wastes improves the water resistance of the gypsum material without additions, as well as producing a decrease in thermal conductivity and greater resistance to impact. On the other hand, it has been found that, as the percentage of recycled raw material added increases, the mechanical resistance to bending and compression decreases, leading to fracture due to a lack of cohesion between the matrix and the waste. Nevertheless, in all the cases studied, mechanical strengths higher than those established by the EN 13279-2 standard were obtained. Thus, the results confirm the viability of these secondary raw materials to be used in the development of new products for sustainable building, especially in the design of prefabricated panels for false ceilings.

The appropriate control and management of reactive power is of great relevance in the electrical reliability, stability, and security of power grids. This issue is considered in order to increase system efficiency and to maintain voltage under the acceptable value range. In this regard, novel technologies as FACTS, renewable energies, among others, are varying conventional grid behavior leading to unexpected limit capacity reaching due to large reactive power flow. Thus, optimal planning of this must be considered. This paper proposes a new application for a simple and easy implementation optimization algorithm, called Rao-3, to solve the constrained non-linear optimal reactive power dispatch problem. Moreover, the integration of solar and wind energy as the most applied technologies in electric power systems are exploited. Due to the continuous variation and the natural intermittence of wind speed and solar irradiance as well as load demand fluctuation, the uncertainties which have a global concern are investigated and considered in this paper. The proposed single-objective and multi-objective deterministic/stochastic optimal reactive power dispatch algorithms are validated using three standard test power systems, namely IEEE 30-bus, IEEE 57-bus, and IEEE 118-bus. The simulation results show that the proposed optimal reactive power dispatch algorithms are superior compared with two recent algorithms (Artificial electric field algorithm (AEFA) and artificial Jellyfish Search (JS) algorithm) and other optimization algorithms used for solving the same problem.

<p>This industry-oriented paper presents an overview and in-depth analysis of previous and current situations of power system frequency response and control in Australia. The evaluation of different services provided by different electricity market players under the supervision of the Australian Energy Market Operator (AEMO) as an independent system operator provides lessons and an understanding of the current operation status with its real challenges and opportunities from frequency stability and security perspectives. Based on the evaluation of the current situation and future national planning, a number of research gaps and industrial technical issues are identified, and some perspectives on future research directions are presented to help move the power system transformation toward almost 100% renewable and more secure energy systems.</p>

This article aims to analyze the implementation of teleworking as a security practice to face the crisis resulting from the Covid-19 disease. The present paper provides both theoretical and practical results. From a theoretical standpoint, the Baruch and Nicholson approach is extended with environmental, safety, and legal factors that explain telework. From a practical perspective, a database of companies that have introduced telework as a measure to face coronavirus in a crisis context has been obtained. In short, the Covid-19 crisis demonstrates how teleworking has been used by companies to ensure their employees’ safety and to provide continuity to economic activity. Consequently, safety factors are relevant in the study of teleworking and should be considered in further research.