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Abstract From the sustainable perspective, the optimum thickness calculations of the buildings envelope insulation materials published in scientific journals suffer a number of notable shortcomings. The most relevant are the short amortization time periods and the prevalence of economic criterion. The work presented shows that an increase from 20 to 50 years in the amortization time period involves, in some cases, to double the value of the optimum thickness. Moreover, the thicknesses calculated applying energetic or environmental criteria for the optimization give, in some cases, results 10 times higher than the ones obtained using the economic argument. The type of insulation materials (especially their different characteristics at the manufacturing stage) and the calculation conditions (e.g. Degree-Days zone) also affect optimum thicknesses determination.

In order to make adequate projections on the consequences of climate change stressors on marine organisms, it is important to know how impacts of these stressors are affected by the presence of other species. Here we assessed the direct effects of ocean warming (OW) and acidification (OA) along with non-consumptive effects (NCEs) of a predatory crab and/or a predatory snail on the habitat-forming mussel Perumytilus purpuratus. Mussels were exposed for 10-14 weeks to contrasting pCO2 (500 and 1400 μatm) and temperature (15 and 20 °C) levels, in the presence/absence of cues from one or two predator species. We compared mussel traits at sub-organismal (nutritional status, metabolic capacity-ATP production-, cell stress condition via HSP70 expression) and organismal (survival, oxygen consumption, growth, byssus biogenesis, clearance rates, aggregation) levels. OA increased the mussels' oxygen consumption; and OA combined with OW increased ATP demand and the use of carbohydrate reserves. Mussels at present-day pCO2 levels had the highest protein content. Under OW the predatory snail cues induced the highest cell stress condition on the mussels. Temperature, predator cues and the interaction between them affected mussel growth. Mussels grew larger at the control temperature (15 °C) when crab and snail cues were present. Mussel wet mass and calcification were affected by predator cues; with highest values recorded in crab cue presence (isolated or combined with snail cues). In the absence of predator cues in the trails, byssus biogenesis was affected by OA, OW and the OA × OW and OA × predator cues interactions. At present-day pCO2 levels, more byssus was recorded with snail than with crab cues. Clearance rates were affected by temperature, pCO2 and the interaction between them. The investigated stressors had no effects on mussel aggregation. We conclude that OA, OW and the NCEs may lead to neutral, positive or negative consequences for mussels.

The immobilisation of the iron-oxidising bacteria Thiobacillus ferrooxidans on nickel alloy fibre as support is described. This matrix showed promise for application in iron oxidation under strongly acidic conditions. The influence on the colonisation process of T. ferrooxidans exerted by the initial pH of the medium and by temperature has also been studied. Results showed that immobilisation of T. ferrooxidans cells was affected by changes of temperature between 30 degrees C and 40 degrees C and in pH from 1.4 to 2.0.

Artículos en revistas In this paper we propose a methodology to approximate closed loop capacity equilibria using only open loop capacity equilibrium models. In the closed loop model, generation companies choose capacities that maximize their individual profit in the first stage while the second stage represents the conjecturedprice- response market equilibrium. In the open loop model, firms simultaneously choose capacities and quantities to maximize their individual profit, while each firm conjectures a price response to its output decisions. The closed loop equilibrium model is an equilibrium problem with equilibrium constraints, which belongs to a class of problems that is very hard to solve. The open loop equilibrium model is much easier to solve, however, it is also less realistic. With the approximation scheme proposed in this paper, we are able to solve the closed loop model reasonably well when market behavior is closer to oligopoly than to perfect competition by smartly employing open loop models which reduces the computational time by two orders of magnitude. We achieve this by transforming the open loop equilibrium problem into an equivalent convex quadratic optimization problem which can be solved efficiently. Finally, a case study is presented in order to validate the proposed approximation scheme. info:eu-repo/semantics/publishedVersion

Artículos en revistas Forecasting industrial end-use natural gas consumption is an important prerequisite for efficient system operation and a basis for planning decisions. This paper presents a novel prediction model that provides forecasting in a medium-term horizon (1–3 years) with a very high resolution (days) based on a decomposition approach. The forecast is obtained by the combination of three different components: one that captures the trend of the time series, a seasonal component based on the Linear Hinges Model, and a transitory component to estimate daily variations using explanatory variables. The flexibility of the model allows describing demand patterns in a very wide range of historical profiles. Furthermore, the proposed method combines a very simple representation of the forecasting model, which allows the expert to integrate judgmental analysis and adjustment of the statistical forecast, with accuracy and high computational efficiency. Realistic case studies are provided. info:eu-repo/semantics/publishedVersion

Artículos en revistas It is shown how a standard nonlinear programming approach can be applied to solve a sophisticated version of the static optimal mix problem in generation planning. The model presented includes technical minima of thermal capacity, detailed operating models of storage-hydro and pumped-hydro units, a realistic model of capital costs for hydro plants, operating reserve and minimum demand constraints, and capacity already in existence. The model formulation is in a format that can be directly handled by the well-known MINOS code and can be efficiently solved. The use of a general-purpose nonlinear optimization program results in a great flexibility, making it possible to modify the model formulation easily or to adapt it to the characteristics of a particular electric system. A realistic application to the Spanish generation system is presented info:eu-repo/semantics/publishedVersion

Low emission and green hydrogen as a carbon-free energy carrier has attracted worldwide attention in decarbonizing the energy system and meeting the Paris agreement target of limiting warming to 2 °C or below. This study investigates the contribution of different hydrogen pathways to the energy transition and sheds light on adopting different decarbonization scenarios for Quebec, Canada, while including biogenic emissions from forest-based biomass consumption. We assess various alternative policy scenarios using a TIMES model for North America (NATEM), a bottom-up techno-economic approach. This study examines the role of various hydrogen pathways in Quebec's energy transition by considering different net-zero policy scenarios and an additional set of “green” scenarios, which prohibit the use of fossil fuel-based hydrogen. The results show that varying the penetration of hydrogen provides a key trade-off between reliance on direct air capture, reliance on carbon storage, reliance on wind and solar buildout, the inter-sector allocation of residual emissions, and the overall cost of achieving emission targets. In particular, the use of hydrogen in the industrial sector, a sector known to be difficult to decarbonize, reduces industrial emissions and reliance on direct air capture (DAC). Clustering industrial plants to use captured CO2 as a feedstock for synthetic fuel production may not reduce industrial GHG emissions by 2050, but it offers the opportunity to use captured CO2 instead of sequestering it in deep saline aquifers. Even though increasing industrial green hydrogen penetration increases marginal GHG abatement costs in the green net-zero scenario by 2050, it further minimizes industrial GHG emissions and the need for DAC among all net-zero scenarios by 2050. Hydrogen plays a significant role in achieving ambitious net-zero emission target, especially where electrification is not feasible, or electricitystorage is required.

Artículos en revistas There has been total unanimity about the vital importance of reliability of supply since the beginning of the electricity sector deregulation process. This paper describes the procedure proposed by Pérez-Arriaga et al. [2005. White paper for the reform of the regulatory scheme of the power generation in Spain. For the Ministry of Industry, Tourism and Trade of Spain (in Spanish)] to improve upon the current scheme to guarantee a reasonable reserve margin, the capacity payment mechanism. This alternative design introduces improvements aimed at guaranteeing at least a minimum capacity reserve margin, as well as at providing a strong incentive for generating units to be available when needed, namely, in situations when supply is likely to be insufficient to meet the total demand. info:eu-repo/semantics/publishedVersion