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Ammonia increases buffer capacity of methanogenic medium in mesophilic anaerobic reactor thus increasing the stability of anaerobic digestion process. Optimal ammonia concentration ensures sufficient buffer capacity while not inhibiting the process. It was found out in this paper that this optimum depends on the quality of anaerobic sludge under investigation. The optimal concentrations for methanogens were 2.1, 2.6 and 3.1 g/L of ammonia nitrogen in dependence on inoculum origin. High ammonia nitrogen concentration (4.0 g/L) inhibited methane production, while low ammonia nitrogen concentration (0.5 g/L) caused low methane yield, loss of biomass (as VSS) and loss of the aceticlastic methanogenic activity. It was found out that negative effect of low ammonia nitrogen concentration on biomass is caused not only by low buffer capacity but also by insufficiency of nitrogen as nutrient. It was also found out that anaerobic sludge with higher ammonia nitrogen concentration (4.2 g/L) tolerates even concentration of volatile fatty acids (160 mmol/L) which causes inhibition of the process with low ammonia nitrogen concentration (0.2 g/L).

This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

Given the significant amount of installed generation-capacity based on wind power, and also due to current economic downturn, the subsidies and incentives that have been widely used by wind-power producers to recover their investment costs have decreased and are even expected to disappear in the near future. In these conditions, wind-power producers need to develop offering strategies to make their investments profitable counting solely on the market. This paper proposes a multi-stage risk-constrained stochastic complementarity model to derive the optimal offering strategy of a wind-power producer that participates in both the day-ahead and the balancing markets. Uncertainties concerning wind-power productions, market prices, demands' bids, and rivals' offers are efficiently modeled using a set of scenarios. The conditional-value-at-risk metric is used to model the profit risk associated with the offering decisions. The proposed model is recast as a tractable mixed-integer linear programming program solvable using available branch-and-cut algorithms. Results of a case study are reported and discussed to show the effectiveness and applicability of the proposed approach.

AbstractIn this work, the drying step for cathodes based on carbon‐coated LiFePO4 prepared in the temperature range of 60–120 °C has been investigated in detail. The microstructure of the cathode shows a homogeneous distribution of the active material and conductive additive particles independent of the drying temperature. However, the results of impedance spectroscopy and cycling voltammetry are affected by the drying temperature. The solvent evaporation temperature, therefore, affects the polymer binder distribution and its characteristics, which include the polar phase content of the polymer and its affinity with the other components of the cathode. The discharge capacity value after 50 cycles is 120 and 81 mAh g−1 for the samples dried at 80 and 60 °C, respectively, which show the best and worst battery performance, respectively. It was concluded that carbon‐coated LiFePO4 cathodes should be prepared at drying temperatures between 80 and 100 °C for optimized performance.

Thirty four crude extracts of Panamanian plants, from nine species of Celastraceae and Lamiaceae, were assayed for xanthine oxidase (XO) inhibitory activity. The enzymatic activity was estimated by measuring the increase in absorbance at 290 nm due to uric acid formation. Eighty five percent of the crude extracts were found to possess XO inhibitory activity at 50 micrograms/ml and all the extracts of the species from Lamiaceae were active even at 1 micrograms/ml. The ethanol extracts of Hyptis obtusiflora Presl ex Benth. (Lamiaceae) and H. lantanaefolia Poit. (Lamiaceae) exhibited the highest activity with an inhibition of approximately 40% at 1 micrograms/ml.

This paper describes anaerobic thermophilic sludge digestion (55 °C) in a continuously stirred tank reactor (CSTR) on a pilot-plant scale (150 L). The experimental protocol was defined to examine the effect of the increase in the organic loading rate on the efficiency of the digester and to report on its steady-state performance. The reactor was subjected to a programme of steady-state operation over a range of solids retention times (SRTs) of 75, 40, 27, 20 and 15 days and organic loading rates (OLR) in the range 0.4–2.2 kg VS/(m3 day). The digester was fed with raw sludge (containing approximately 35 kg/m3 volatile solids (VS)) once daily during the 75-day SRT period, twice daily during the 40-day SRT period and three times a day during the 27-, 20- and 15-day SRT periods. The reactor was initially operated with an organic loading rate of 0.4 kg VS/(m3 day) and an SRT of 75 days. The volatile solids removal efficiency in the reactor was found to be 73%, while the volumetric methane production rate produced in the digester reached 0.02 m3/(m3 day). Over a 338-day operating period, an OLR of 2.2 kg VS/(m3 day) was achieved with 49.1% VS removal efficiency in the pilot sludge digester, at which time the volumetric methane production rate content of biogas produced in the digester reached 0.4 m3/(m3 day). The chemical oxygen demand (COD) mass balance obtained indicated that COD used for methane generation increased when the SRT was decreased or when the influent organic loading rate was increased. This implies that the amount of COD used in the anabolism route decreased with SRT due the microbial population becoming adapted to new operational conditions and more COD being used to generate methane.

[EN] The objective of this article is to compare the behaviour of the most representative domestic hot water systems (DHW) in single-family buildings. The study evaluates the energy consumption, equivalent CO2 emissions and cost for each system over a 15-year life period. This analysis is carried out in four cli- matic zones across Europe to observe the influence of climatic conditions on the results. The four climatic zones are located in the cities of Athens, Madrid, London and Berlin. The analysed systems are: a) natural gas-fired instantaneous water heaters, b) electric storage water heater, c) solar thermal system with gas- fired instantaneous, d) solar thermal system with electric storage water heater, e) air-source heat pump, f) photovoltaic system with electric storage water heater, and g) photovoltaic system with air-source heat pump. This range of technologies covers the most likely solutions to be implemented across domestic buildings in Europe.The heat pump system (HPWH) with PV considering self-consumption shows the lowest environmen- tal impact in all zones, but is not an attractive investment in the coldest zones due to lower natural gas prices. Thermal solar systems have a high purchase and maintenance costs which do not compensate their energy savings. The PV HPWH system has a greater reduction of emissions and a lower cost than HPWH across a 15-year life. The gas boiler system has the lowest cost in a 15-year period in the coldest areas, despite having a greater environmental impact than the heat pump.(c) 2023 Elsevier B.V. All rights reserved.