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Hot water heat stores with stratification are a common technology used in solar energy systems and reuse of waste heat. Adding a PCM module at the top of the water tank would give the system higher storage density, and compensate heat loss in the top layer. The work presented here includes experimental results and numerical simulation of the system using an explicit finite-difference method. Experiments and simulations were carried out using different cylindrical PCM modules. With only 1/16 of the volume of the store being PCM, 3/16 of water at the top of the store was held warm for 50% to 200% longer and the average energy density was increased by 20% to 45%. Furthermore, these 3/16 of water were reheated by the heat from the module after being cooled down in only 20 min.

Phosphorus was recovered from the ash obtained after combustion at different temperatures (600 °C, 750 °C, 900 °C) and gasification (obtained at 820 °C using a mixture of air and steam as fluidizing agent) of char from sewage sludge fast pyrolysis carried out at 530 ºC. Depending on the extraction conditions (type of acid, extraction time and acid concentration) phosphorus yields of 90% to 100% are reached. Char ash seems to be a renewable resource of phosphorus. It could be an alternative to rock phosphate for fertilizers production. The combination of these processes contributes to the integral exploitation of sewage sludge. Proceedings of the 21st European Biomass Conference and Exhibition, 3-7 June 2013, Copenhagen, Denmark, pp. 500-505

Abstract A heat pump coupled to thermal energy storage (TES) tanks is experimentally tested under simulated summer conditions and the results are presented in this paper. The cold TES tank is used for shifting the cooling load of a small house-like structure. The study evaluates the thermal behaviour of the TES tank for cold storage and the application of the system for space cooling. For the analysis, two different configurations of the tanks are compared: a water tank and a PCM tank. The PCM tank is filled with a commercial macro-encapsulated PCM, which has a phase change temperature of 10 °C. The results point out that the PCM tank is able to supply 14.5% more cold and to maintain the indoor temperature within comfort 20.65% longer than the water tank. However, it needs 4.55 times longer to charge the tank.

This paper presents a preliminary study of the characterization of real waste from slaughterhouses as well as their rendering products (protein and fat) through different pyrolytic techniques: thermogravimetric analysis (TG), analytical pyrolysis in a pyroprobe equipment and hydrothermal liquefaction process (HTL). The experiments have allowed a deeper knowledge about the thermal behavior of these wastes under different conditions: slow pyrolysis up to 800°C (TG), flash pyrolysis at 500°C and room pressure (pyroprobe) and slow pyrolysis at 290°C and 110-130bar (HTL batch reactor). Experiments with each one of the materials (real waste, PAP and fat) as well as some mixtures have been performed. Gas chromatography and mass spectrometry techniques were used to identify the pyrolytic products obtained. The results indicate that fatty acids and fatty esters are the major group obtained in the pyrolysis of fat samples, followed by aliphatic hydrocarbons. In the case of PAP pyrolysis, heterocyclic aromatic compounds, which includes typical products coming from protein degradation, is the major group obtained. Oxygenated aliphatics are also obtained in high amounts. In the case of the HTL experiments, significant glycerine amounts were detected in the aqueous phase. The yield of biocrude obtained under HTL conditions is about 30%, with a high proportion of nitrogenated compounds (amides, pyrrole and pyridine derivatives). Generation of amides is much higher under HTL conditions than in the analytical pyrolysis runs while the proportion of acids is reduced.

In order to apply the EU Water Framework Directive for temporary streams, it is important to quantify the space–time development of different aquatic states. We report on research on the development of aquatic states for temporary streams in the Evrotas basin, Greece. The SIMGRO regional hydrological model was used in a GIS framework to generate flow time series for the Evrotas River and all major tributaries. Five flow phases were distinguished: flood conditions, riffles, connected pools, isolated pools and dry bed conditions. Thresholds based on local hydraulic characteristics were identified per stream reach and flow phase, enabling the frequency of flow phases per month and the average frequencies for all streams to be derived. Three historical scenarios within the 20th century, marking periods of major changes in water management, were investigated. Additionally, a climate scenario for the 2050s was analysed. Simulations revealed that low flows are now much lower, mainly because more groundwater is abstracted for irrigation. The consequence is that stretches of the river fall dry during several months, causing the ecological status to deteriorate.

Artículos en revistas As outlined in the Paris Agreement on climate change, efforts to mitigate and adapt to climate change will require new modes of development of the energy sector including the transformation and expansion of power systems to low-carbon and more resilient designs. However, there is a need for more systematic tools to support decision-making processes in the context of climate change impacts and adaptation strategies for the energy and power sectors. For instance, quantitative approaches should be developed and implemented for the assessment of the impacts and hedging strategies associated with the uncertainties inherent to energy and power planning problems. This study addresses the development and implementation of an integrated model-based system analysis, which uses general circulation models, global sensitivity analysis, and stochastic optimization techniques, for the optimal design and planning of the Colombian power system in view of submitted climate pledges and climate change adaptation. It was found that during the 2015 to 2029 time frame, climate change will likely reduce the capacity factor of hydropower generation by 5.5-17.1%. Additionally, it was established that the independent effects of three key uncertain parameters, i.e., capacity factor of hydropower generation, gas prices, and emission reduction target, account for ~96% of the variance in the total cost for the required expansion and operation of the power system. Furthermore, when uncertainty is taken into account, the optimal expansion strategy consists of rescheduling of investments in hydropower plants and investing more in carbon management technologies and renewable power plants to compensate for the uncertainty in hydropower generation, climate policy, and gas prices. info:eu-repo/semantics/publishedVersion

Abstract Tars and alkali ashes from biomass gasification processes currently constitute one of the major problems in biomass valorisation, generating clogging of filters and issues related with the purity of syngas production. To date, these waste residues find no useful applications and they are generally disposed upon generation in the gasification process. A detailed analysis of these residues pointed out the presence of high quantities of Ca (>30 wt%). TG experiments indicated that a treatment under air at moderate temperatures (400–800°C) decomposed the majority of carbon species, while XRD indicated the presence of a crystalline CaO phase. CaO enriched valorized materials turned out to be good heterogeneous catalysts for biodiesel production from vegetable oils, providing moderate to good activities (50%–70% after 12 h) to fatty acid methyl esters in the transesterification of sunflower oil with methanol.