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| openaire: EC/H2020/963646/EU//HELIOS Lithium titanate oxide (LTO) batteries have been under intensive research due to their stability, safety, and rapid charging characteristics. Nevertheless, uncertainties as to LTO-batteries behavior when used as a raw material in battery recycling still exist. This study provides a grave-to-gate life cycle inventory for a hydrometallurgical battery recycling process in which Li-battery waste materials nickel manganese cobalt (NMC), LTO, and graphite were used as feed. The simulation showed that NMC cathode materials and lithium from both battery waste fractions could be recovered. In contrast, the titanium present within LTO cannot be recovered by the recycling process. Nevertheless, the life cycle assessment (LCA) of the process demonstrated clear benefits of recycling battery materials, highlighted by the decrease in global warming potential, acidification, eutrophication, and ozone depletion potential. Additionally, two routes for hazardous waste management were simulated to ascertain the environmental impacts of hazardous waste management within the recycling process. Peer reviewed

Decentralized multi-energy systems (MESs) are a key element of a future low-carbon energy supply. Here, we address the crucial role of grid-connected and off-grid MESs in achieving a low-carbon future, particularly relevant for regions like the Mediterranean with high renewable energy potential and carbon-intensive grid networks, using a mixed integer linear program for optimal economic and environmental MES design considering location-specific regulations. The results reveal that substantial cost (up to 30%, potentially saving 1.6 million) and greenhouse gas (GHG) emission reductions can be reached in Mediterranean regions with sufficient solar and wind energy resources currently relying on fossil fuel-based generators. However, our case study shows that the actual cost and emission reductions are most likely limited due to location-specific regulations (limiting cost savings to 0.8 million), especially those that constrain solar photovoltaic and onshore wind. Off-grid energy systems might be suitable decarbonization options in Mediterranean regions, to avoid absorbing current GHG-intensive power from the local power grid, under marginal cost increase (15%) compared to grid-connected cost optimization. However, off-grid MESs require substantial upfront investments and exhibit some environmental trade-offs, especially on material utilization, which could be overcome by balanced autonomy. Overall, truly sustainable and secure decentralized energy systems can only be reached by considering life cycle environmental impacts, social acceptance, and regulations during the design phase. Applied Energy, 377 ISSN:0306-2619 ISSN:1872-9118

Publisher Copyright: © 2024 The Authors Ammonia is increasingly recognized as a viable alternative fuel that could significantly reduce greenhouse gas emissions without requiring major modifications to existing engine technologies. However, its high auto-ignition temperature, slow flame speed, and narrow flammability range present significant barriers, particularly under high-speed combustion conditions. This review explores the potential of ammonia as a sustainable fuel for internal combustion engines, focusing on its advantages and challenge. The review draws on a wide range of studies, from NH3 production, application, to the combustion mechanisms, that explore various strategies for enhancing NH₃ combustion in both spark ignition and compression ignition engines. Fundamentals and key approaches discussed include using hydrogen and hydrocarbon fuels as combustion promoters, which have been shown to improve ignition and flame propagation. Literature on fuel injection strategies, such as port fuel injection, direct injection, and dual-fuel injection, are examined to highlight their influence on NH₃-air mixing and combustion efficiency. Furthermore, the review delves into advanced ignition technologies, such as low-temperature plasma ignition, turbulent jet ignition, and laser ignition, which are explored for the potential to overcome the ignition difficulties associated with NH₃. After a comprehensive analysis based on the literature, the intelligent liquid-gas twin-fluid co-injection system (iTFI) emerges as a promising approach, offering improved combustion stability and efficiency through better fuel-air mixture preparation. By synthesizing the existing research, this review outlines the progress made in NH₃ combustion and identifies areas where further study is needed to fully realize its potential as a sustainable fuel. Peer reviewed