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Abstract In an effort to minimise electricity consumption and greenhouse gases emissions, the heating, ventilation and air-conditioning sector has focused its attention on developing alternative solutions to electrically-driven vapour-compression cooling. Liquid desiccant air-conditioning systems represent an energy-efficient and more environmentally friendly alternative technology for dehumidification and cooling, particularly in those cases with high latent loads to maintain indoor air quality and comfort conditions. This technology is considered particularly efficient in hot and humid climates. As a matter of fact, the choice of the desiccant solution influences the overall performance of the system. The current paper reviews the working principle of liquid desiccant systems, focusing on the thermodynamic properties of the desiccant solutions and describes an evaluation of the reference thermodynamic properties of different desiccant solutions to identify which thermodynamic, physical, transport property influences the liquid desiccant process and to what extent. The comparison of these thermodynamic properties for the commonly used desiccants is conducted to estimate which fluid could perform most favourably in the system. The economic factors and the effect of different applications and climatic conditions on the system performance are also described. The paper is intended to be the first step in the evaluation of alternative desiccant fluids able to overcome the problems related to the use of the common desiccant solutions, such as crystallization and corrosion to metals. Ionic liquids seem a promising alternative working fluid in liquid desiccant air-conditioning systems and their characteristics and cost are discussed.

Abstract In the past, most studies considered solar as a drawback to road pavement, especially the asphalt pavement. Not only its radiation causes the asphalt aging, simultaneously with high temperature, asphalt pavement contributes to the urban heat island (UHI) effect. In recent, as the world becomes more supportive towards implementing sustainable energy as the alternatives to the scarcity of non-renewable resources, utilizing the abundant solar radiation as the main source of energy has gradually attracted attention from both industries and academia with its potentials, including solar application on roads. Nevertheless, more researches have focused on the potential energy collection with less consideration to simultaneously overcome the side effects of abundant solar radiation on its lifecycle. This study found the necessity to review a comprehensive correlation between solar radiation and asphalt pavement from both positive and negative effects. The negative effects included asphalt aging and its effects on surroundings i.e. UHI effect. Meanwhile, the positive effects included exhaust purification and solar energy conversion into other forms of energy that can be used by humans using pavement solar heat collection for winter snowmelt, thermoelectric technology and photoelectric technology to convert solar energy into electrical energy. The cases in various application scenarios were analysed and summarized and the existing problems in the current research were proposed in this paper. Also, the reflection on the transformation of road design concept from “avoiding harm” to “seeking profit” was included. Finally, a new concept of “solar-road harmonious symbiosis” for future road application was proposed based on a comprehensive review of previous published works. It is also the new suggestion to scholars on the treatment of solar diseases on roads to prolong its symbiosis functions.

Abstract The present work focuses on the numerical simulation of Moderate or Intense Low oxygen Dilution combustion condition, using the Partially-Stirred Reactor model for turbulence-chemistry interactions. The Partially-Stirred Reactor model assumes that reactions are confined in a specific region of the computational cell, whose mass fraction depends both on the mixing and the chemical time scales. Therefore, the appropriate choice of mixing and chemical time scales becomes crucial to ensure the accuracy of the numerical simulation prediction. Results show that the most appropriate choice for mixing time scale in Moderate or Intense Low oxygen Dilution combustion regime is to use a dynamic evaluation, in which the ratio between the variance of mixture fraction and its dissipation rate is adopted, rather than global estimations based on Kolmogorov or integral mixing scales. This is supported by the validation of the numerical results against experimental profiles of temperature and species mass fractions, available from measurements on the Adelaide Jet in Hot Co-flow burner. Different approaches for chemical time scale evaluation are also compared, using the species formation rates, the reaction rates and the eigenvalues of the formation rate Jacobian matrix. Different co-flow oxygen dilution levels and Reynolds numbers are considered in the validation work, to evaluate the applicability of Partially-Stirred Reactor approach over a wide range of operating conditions. Moreover, the influence of specifying uniform and non-uniform boundary conditions for the chemical scalars is assessed. The present work sheds light on the key mechanisms of turbulence-chemistry interactions in advanced combustion regimes. At the same time, it provides essential information to advance the predictive nature of computational tools used by scientists and engineers, to support the development of new technologies.

Abstract With the increase of energy consumption and wastes generation due to human activities, anaerobic digestion (AD), a technology which turns wastes into bio-energy, is receiving more and more attention in the world. It is well known that there are at least three stages involved in anaerobic digestion, i.e., hydrolysis, acidification, and methanogenesis. Until now, however, the advances in enhancing acidification and methanogenesis have not been reviewed. This review provides a comprehensive overview of the methods reported to enhance each step involved in anaerobic digestion. More important, enzymes are the key to anaerobic digestion, and the strategies for improving enzyme activity are summarized. As electron transfer has been reported to play an important role in anaerobic digestion, the research progress of the approaches for the acceleration of direct interspecies electron transfer in methane production is also introduced. In addition, the recent advances in increasing the reduction of carbon dioxide to methane, which has been widely observed in methanogenesis step, are reviewed. Furthermore, the techno-economic assessment of anaerobic digestion is made, and the key points for future studies are proposed.

Abstract Integrating low-carbon technologies (e.g. heat pumps, photovoltaic systems) in buildings influences the stability of the low-voltage grid, which therefore often requires to be reinforced. This article proposes a techno-economic methodology to identify the reinforcements needed to maintain grid stability at the lowest life-cycle cost. Novel contributions include the consideration of three-phase connection of low-carbon technologies as a reinforcement option and the fact that we study to what extent grid reinforcements can mitigate voltage unbalance issues. Additionally, to reduce computing time, a dummy island approach is used, whereby one feeder is modelled in detail and the remainder of the distribution island is represented by an aggregated load. Finally, random repetitions are proposed, to consider uncertainties related to building properties, occupants and the location of low-carbon technologies in the feeders. The methodology is applied to investigate the integration of heat pumps and photovoltaic systems in typical Belgian rural and urban grids. For the rural grid, heat pumps may lead to significant reinforcement costs (up to 1230 €/dwelling), mainly due to voltage stability problems. For the urban grid, heat pump and photovoltaic integration causes low reinforcement cost (

Abstract This study aimed to investigate the applicability of the solar heating system in different geographical regions with different meteorological conditions, of which parabolic trough solar collectors (PTCs) were operated with the absorption heat pumps (AHP) and oil/water heat exchanger (OWHE) at medium and low operating temperature respectively. The heat transfer model for PTCs was constructed with a lumped parameter method and validated by experimental results. The thermal performance of the system was evaluated by the index of primary energy ratio (PER). The results showed that on overcast days with low direct normal irradiance (DNI), the operation of the PTC + AHP/OWHE system was not cost-effective. On cloudy days with high DNI lasting for a short period (e.g. 2 h), the operation of the PTC + OWHE system was better than that of the PTC + AHP system as the latter needed more preheating energy before the system operation. While on sunny days with high DNI lasting for a longer period (e.g. 8 h), the PTC + AHP system was suggested to be operated as it owned higher PER values. Besides, the solar energy distributions in China could be divided into four categories, i.e. rich (S1), relatively rich (S2), available (S3) and absent (S4). In S1 region the PTC + AHP system was suggested to be operated. In S4 region the PTC + AHP/OWHE system was not suggested to be operated. While in S2 and S3 region, whether the operation of the PTC + AHP/OWHE system was suggested depending on the meteorological conditions. With these findings the developing strategy of the solar heating system in different geographical regions can be devised and the operating strategy on a specific day with different weather conditions can be developed, which is helpful to guide the application of solar energy and improve the energy structure in domestic heating.

Abstract The correlation between effectiveness of multiple operating parameters is a complicated issue and significant to the safe operation of solid oxide fuel cell/gas turbine (SOFC/GT) hybrid system. This paper presents a numerical analysis on biogas-fueled SOFC/GT hybrid system with a recirculation process using combustor exhaust gas. With consideration of safety constraints for critical components (fuel cell thermal crack, reformer carbon deposition, turbine blade overheat), the interaction mechanism of recirculation ratio, steam/carbon ratio and fuel/air ratio is studied from the perspective of thermodynamic analysis. Results show that the recirculation process could increase the electrical efficiency of system from 58.18% to 62.8%. However, for the safety consideration of SOFC, the acceptable recirculation ratio should be controlled between 0.17 and 0.32. Meanwhile, there exists a minimum point of turbine inlet temperature at the recirculation ratio of 0.3. With recirculation ratio switched from 0.1 to 0.3, impact of steam/carbon ratio variation on SOFC temperature gradient shrinks from 52.5% to 17.9% of the reference value. On the other hand, effect of fuel/air ratio variation on SOFC temperature gradient is promoted from 20.8% to 44.3% of the reference value, due to that oxidation reaction of biogas becomes a dominant factor. Based on these results, a parametric comparison is carried out to quantitatively describe the impact of recirculation process on the effectiveness of other parameters. Short discussion is conducted on parameter selection to acquire higher system efficiency and sufficient safety range, in which case the total output power of 176.8 kW and electrical efficiency of 61.78% could be achieved.

Abstract The automotive operating protocols is a comprehensive expression of a country or a region’s road, climatic environment and driving habits. It is the foundation of energy consumption, test method and limit method for automobile products. It has direct impact on R & D, production and government access management of enterprises. For fuel cells vehicles, the lifetime is one of the main factors restricting their commercialization. Furthermore, the lifetime evaluation methods and its standard specifications of vehicular proton exchange membrane fuel cell are the critical factors to its technological development, but there is no authoritative recognized life evaluation method and test protocols so far. A logical fuel cell durability test protocol is the fundamental for developing the fuel cell life evaluation methods. A review on the state-of-art in the world for fuel cell accelerated test protocols was given, the research circumstances of different universities and research institutions in China, America, the European Union, Japan and so on are analyzed and summarized in detail. Then the essential characteristics and applicable environments of a comprehensive and effective durability test protocol are summarized based on the analysis and demonstration of the existing durability test protocols in literature. The work in this paper focuses on the research of durability test protocols of the fuel cell stack for the first time. The final conclusion will provide theoretical basis for establishing fuel cell durability test specifications and proposing life evaluation methods, and make a contribution to the long life research of vehicular fuel cells.