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Diesel engine exhausts from a common rail 3.0 L F1C diesel engine were analyzed at two different load conditions of the WLTC testing cycle downstream of both the diesel particulate filter (DPF) and selective catalytic reactor (SCR) to verify their effect on the characteristics of carbon particulate matter. An array of chemical, physical and spectroscopic techniques (gas chromatography coupled with mass spectrometry (GC-MS), mobility analyzer, UV-Visible absorption and fluorescence spectroscopy) was applied for characterizing polycyclic aromatic hydrocarbons (PAH), heavy aromatic compounds and soot, constituting the particulate matter (PM) sampled from the exhaust. The engine was operated in half load (HL) (188 Nm, representing the more common condition for engine in urban traffic) and full load (FL) (452 Nm, representing the best performance of the engine operation) conditions, at the same engine speed (2000 rpm). Soot formation was enhanced in HL condition, with respect to FL, but, just because of the much lower soot amount, the after-treatment systems in this last condition resulted to be less efficient in the soot abatement. Indeed, the abatement through DPF was about 40% lower in the FL condition with respect to HL condition, and any significant further concentration decrease was found after SCR, in both conditions. By contrast, PAH concentration after DPF abatement was found to be higher in the HL with respect to FL condition. A further PAH concentration decrease of about 30% was found after the SCR in the HL condition whereas in FL the reduction was only about 5-6%. Also the heavy aromatic compounds having molecular weight above the GC-MS detection limit (300 u), were mitigated by SCR. Therefore, SCR did not cause a further soot reduction, whereas it was effective in largely reducing PAH and heavy aromatics emissions, especially in the lower temperature condition featuring the half-load condition, when combustion efficiency is worse. Moreover, SCR system reduced the emission of small particles probably due to an enhanced agglomeration of particles, with beneficial effect on the harmfulness to human health.

Sustainability assessment and rating systems are intended to foster more sustainable design, construction, operation, maintenance and disassembly/deconstruction promoting and making possible a better integration of environment, societal, and cost concerns with other traditional decision criteria. The use of improved and building technologies can contribute considerably to better environmental cycle and then to the sustainability of the constructions. It is widely recognised in the of Building Sustainability Assessment that Life Cycle Assessment (LCA) is a much preferable method for evaluating the environmental pressure caused by materials, Building assemblies and the whole life-cycle of a building. Nevertheless, LCA tools are not extensively used in building design and most of building sustainability assessment and systems are not comprehensive or consistently LCA-based. Reasons for this failure above all related to the huge variety and amount of material flows and processes of building’s Lifecycle and to the complexity of the stages of a LCA. This paper will present the difficulties and possible solutions to integrate more accurate environmental methods in rating systems. In this context, the paper will also present the work that is being carried out in the development of the Portuguese Building Sustainability Assessment system (SBTool PT)

AbstractThe protic ionic liquid (PIL) N‐butylimidazolium trifluoromethanesulfonate ([BIm][TfO]) was obtained for the first time and incorporated into a sol–gel‐derived di‐ureasil matrix with a concentration of X=5, 10, and 30 %, where X is the ratio of the mass of PIL per mass of poly(oxyethylene). Four years after their synthesis, the resulting quasi‐anhydrous electrolytes remained amorphous, homogeneous, flexible, and thermally stable below 200 °C. SEM/EDS data revealed the presence of the PIL at the surface of the xerogels with X>5 %, demonstrating that this type of morphological characterization is mandatory to avoid misleading ionic conductivity values. The highest ionic conductivity was produced in the washed sample with X=30 % (3.5×10−5 and 2.1×10−3 S cm−1 at 25 and 170 °C, respectively). The present family of electrolytes yielded higher conductivities than the N‐ethylimidazolium trifluoromethanesulfonate‐based analogues introduced earlier by our group and may thus be considered as promising candidates for applications in fuel cells.

Abstract This work assesses the impacts of aggressive driving behavior on pollutants emissions and energy consumption at a city level. Furthermore, it performs an economic analysis considering the potential avoided emissions and fuel savings and discusses potential policy measures to address this topic. The results showed that aggressive driving significantly impacts energy consumption and emissions, with energy consumption increasing by more than ∼200% and emissions by 330% for aggressive driving compared to non-aggressive driving (in MJ/km and in g/km, respectively). This increment was found to be even higher for diesel vehicles than for gasoline vehicles. On the contrary, gasoline vehicles showed higher percentages of increase for most emissions (CO, NOx and NO). Results also revealed that aggressive driving impacts are higher for local streets when examining the city level. Moreover, the economic analysis showed that significant cost reductions may be achieved by avoiding aggressive driving, reaching up to 52.5 k€ on a daily basis. In conclusion, this study is of particular relevance to policy makers and urban planners, enabling to obtain a comprehensive overview of the impacts of aggressive driving behaviors at a city level and providing new insights to perform further developments and to assess the feasibility of the implementation of policy measures.

Wood biomass is turned into industrial fuel through chipping. The efficiency of chipping depends on many factors, including chipper knife wear. Chipper knife wear was determined through a long-term follow-up study, conducted at a waste wood recycling yard. Knife wear determined a sharp drop of productivity (>20%) and a severe decay in product quality. Dry sharpening with a grinder mitigated this effect, but it could not replace proper wet sharpening. Increasing the frequency of wet sharpening sessions determined a moderate increase of knife depreciation cost, but it could drastically enhance machine performance and reduce biomass processing cost. Since benefits largely exceed costs, increasing the frequency of wet sharpening sessions may be an effective measure for reducing overall chipping cost. If the main goal of a chipper operator is to increase productivity and/or decrease fuel consumption, then managing knife wear should be a primary target. (C) 2014 Elsevier Ltd. All rights reserved.

Abstract Portugal’s performance concerning the Refuse Derived Fuel (RDF) strategy, with particular focus on perspectives for the Northern Region based on the current status of integrated municipal waste management systems in that region, was evaluated. Legal documents, official reports and the market were analyzed. The 2015 national installed capacity of waste treatment technologies, from which the high calorific value fraction (HCVF) for RDF production is obtained, is not far from what was predicted for 2013. However, only around 11% of the HCVF had such destiny and the amount of effectively produced RDF was only 30% of the material sent to RDF production (around 30 kt). In Northern Portugal, no RDF production plant was in operation in 2015; the amount of HCVF was estimated to range from 105 to 204 kt for 2015 and around 2.4 times more is expected in 2020. The strategy laydown for RDF failed so far, and thus, low diversion of waste from landfills is observed, mostly due to low landfill taxes and low HCVF quality, resulting in RDF being non-competitive with the imported higher quality product from countries with very high landfilling fees. Moreover, co-incineration and dedicated recovery solutions are scarce. In the Northern region, the HCVF may be treated in the existing municipal waste incinerator or the RDF might be recovered in new dedicated plants, receiving also non-hazardous waste fractions from other origin. Overall, to ensure a sustainable municipal waste management, the intensification of the reuse, preparation for reuse and recycling of waste components from source segregated collection must be significantly promoted.

The olive oil mill wastewater (OMW) is a by-product (with a high organic load) derived from the production of the olive oil. The OMW steam reforming (OMWSR) process was studied herein, aiming to decrease the environmental damage of such effluents; simultaneously, the waste is economically and energetically valorized with the H-2 production. Several Ni-containing catalysts were prepared and tested to compare their performances for the OMWSR using a synthetic OMW effluent; still, stability tests were also carried out. The materials were extensively characterized: thermogravimetric analysis, temperature programmed oxidation/reduction, temperature-programmed desorption of CO2/NH3, chemisorption of H-2, inductively coupled plasma optical emission spectrometry and physical adsorption-desorption of N-2 at-196 & DEG;C. Amongst the materials tested, the Ni-Ru/SiO2 sample stood out, exhibiting high catalytic performance: at 400 & DEG;C, the H-2 yield (> 8 mol(H2)& BULL;mol(OMW)(-1)) and conversion of total organic carbon (asymptotic to 75%) were high during all the 24 h of the long-term test, with only a small deactivation being noticed.

The transition to a low carbon future is starting to affect landscapes around the world. In order for this landscape transformation to be sustainable, renewable energy technologies should not cause critical trade-offs between the provision of energy and that of other ecosystem services such as food production. This literature review advances the body of knowledge on sustainable energy transition with special focus on ecosystem services-based approaches and methods. Two key issues emerge from this review: only one sixth of the published applications on the relation between renewable energy and landscape make use of the ecosystem service framework. Secondly, the applications that do address ecosystem services for landscape planning and design lack efficient methods and spatial reference systems that accommodate both cultural and regulating ecosystem services. Future research efforts should be directed to further advancing the spatial reference systems, the use of participatory mapping and landscape visualizations tools for cultural ecosystem services and the elaboration of landscape design principles.