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In this paper, the performances of two iron-based syngas-fueled chemical looping (SCL) systems for hydrogen (H2) and electricity production, with carbon dioxide (CO2) capture, using different reactor configurations were evaluated and compared. The first investigated system was based on a moving bed reactor configuration (SCL-MB) while the second used a fluidized bed reactor configuration (SCL-FB). Two modes of operation of the SCL systems were considered, namely, the H2 production mode, when H2 was the desired product from the system, and the combustion mode, when only electricity was produced. The SCL systems were modeled and simulated using Aspen Plus software. The results showed that the SCL system based on a moving bed reactor configuration is more efficient than the looping system with a fluidized bed reactor configuration. The H2 production efficiency of the SCL-MB system was 11 % points higher than that achieved in the SCL-FB system (55.1 % compared to 44.0 %). When configured to produce only electricity, the net electrical efficiency of the SCL-MB system was 1.4 % points higher than that of the SCL-FB system (39.9 % compared to 38.5 %). Further, the results showed that the two chemical looping systems could achieve >99 % carbon capture efficiency and emit ~2 kg CO2/MWh, which is significantly lower than the emission rate of conventional coal gasification-based plants for H2 and/or electricity generation with CO2 capture.

Diesel engine exhausts from a common rail 3.0 L F1C diesel engine were analyzed at two different load conditions of the WLTC testing cycle downstream of both the diesel particulate filter (DPF) and selective catalytic reactor (SCR) to verify their effect on the characteristics of carbon particulate matter. An array of chemical, physical and spectroscopic techniques (gas chromatography coupled with mass spectrometry (GC-MS), mobility analyzer, UV-Visible absorption and fluorescence spectroscopy) was applied for characterizing polycyclic aromatic hydrocarbons (PAH), heavy aromatic compounds and soot, constituting the particulate matter (PM) sampled from the exhaust. The engine was operated in half load (HL) (188 Nm, representing the more common condition for engine in urban traffic) and full load (FL) (452 Nm, representing the best performance of the engine operation) conditions, at the same engine speed (2000 rpm). Soot formation was enhanced in HL condition, with respect to FL, but, just because of the much lower soot amount, the after-treatment systems in this last condition resulted to be less efficient in the soot abatement. Indeed, the abatement through DPF was about 40% lower in the FL condition with respect to HL condition, and any significant further concentration decrease was found after SCR, in both conditions. By contrast, PAH concentration after DPF abatement was found to be higher in the HL with respect to FL condition. A further PAH concentration decrease of about 30% was found after the SCR in the HL condition whereas in FL the reduction was only about 5-6%. Also the heavy aromatic compounds having molecular weight above the GC-MS detection limit (300 u), were mitigated by SCR. Therefore, SCR did not cause a further soot reduction, whereas it was effective in largely reducing PAH and heavy aromatics emissions, especially in the lower temperature condition featuring the half-load condition, when combustion efficiency is worse. Moreover, SCR system reduced the emission of small particles probably due to an enhanced agglomeration of particles, with beneficial effect on the harmfulness to human health.

The search for affordable high performance electrode materials in photoelectrochemical hydrogen production by solar water splitting is an ongoing quest. Hematite is a photoanode material with an electronic band gap suitable for efficient absorption of visible light in a photoelectrochemical cell (PEC). Although its poor electronic structure makes hematite a controversial candidate for PEC, it remains promising because it is an earth abundant, chemically stable and low cost material – necessary prerequisites for PEC to become a competitive cost-efficient solar fuel economy. In addition to reviewing some recent PEC research on hematite and its relevant physical and chemical characteristics, we show how hematite obtained by a low cost synthesis can be refined by hydrothermal treatment and further functionalized by coating with phycocyanin, a light harvesting protein known for photosynthesis in blue-green algae.

Solar Energy Materials and Solar Cells, 116 + (2013) 176-181. doi:10.1016/j.solmat.2013.04.019

The transition to a low carbon future is starting to affect landscapes around the world. In order for this landscape transformation to be sustainable, renewable energy technologies should not cause critical trade-offs between the provision of energy and that of other ecosystem services such as food production. This literature review advances the body of knowledge on sustainable energy transition with special focus on ecosystem services-based approaches and methods. Two key issues emerge from this review: only one sixth of the published applications on the relation between renewable energy and landscape make use of the ecosystem service framework. Secondly, the applications that do address ecosystem services for landscape planning and design lack efficient methods and spatial reference systems that accommodate both cultural and regulating ecosystem services. Future research efforts should be directed to further advancing the spatial reference systems, the use of participatory mapping and landscape visualizations tools for cultural ecosystem services and the elaboration of landscape design principles.

A water-soluble organic redox couple (TT−/DTT) and new organic dyes (D45 and D51) have been developed for aqueous dye-sensitized solar cells (DSCs). An optimal efficiency of 3.5% was obtained using the D51 dye and an optimized electrolyte composition. The highest IPCE value obtained was 68% at 460 nm.

The study tested the use of a trommel screen originally designed for compost materials to reject oversize particles from hog fuel, processed from several sources and by two different comminution devices. The experiment consisted in screening material previously comminuted by a convertible crusher, designed to use both hammers and knives. Three different feedstock types were used, and namely: discarded pallets, logs and branches from park maintenance. Each feedstock type came in two different qualities, depending on the tool used for comminution, i.e. hammers or knives. Trommel screen productivity varied between 4.2 t h-1, and 5.2 t h-1 of oven dry material. Screening hog fuel derived from pallets was 30% and 40% less productive than screening fuel derived from logs and branches, respectively. Screening cost varied from 16.2 EUR t-1 dry material in the case of branches, to 19.9 EUR t-1 oven dry material for pallets. Screening allowed an increase of fuel quality only when applied to pallet-derived hog fuel.

A full understanding of the elementary processes taking place in dye-sensitised solar cells requires an accurate description of the electronic structure of the dyes, the semiconductor surface, the electrolyte and their interactions. This review describes how electronic structure calculations have contributed to the field since its first steps and what methodologies have been adopted to study the charge transfer processes at the interface. Not all properties are equally predictable with electronic structure methods, and this work highlights the main success areas (e.g. the rationalization of the optical properties of the dyes), the recent developments (e.g. the improved description of the dye–semiconductor interaction) and the key challenges for the future (e.g. the calculation of charge recombination rate).