• Energy Research
• natural sciences close
• IT close
• ES close
• EU close

IntroductionWith the much-needed transformation from linear to more circular resource flows, it is imperative for enterprises to understand their financial prospects. Transforming towards Product-as-a-Service (PaaS) with circular elements introduces new considerations that must be addressed to ensure profitability and sustainability. However, there is a lack of comprehensive financial assessments based on empirical cases to guide companies in assessing the lucrativeness of their transformations. This paper addresses this gap by proposing a simple-to-use and flexible financial assessment model for PaaS, helping practitioners identify the conditions necessary for financial viability from both provider and user perspectives.MethodsGrounded in transdisciplinary research, this study focuses on a construction machine manufacturer's transformation from a traditional one-off sales business model to PaaS. The transformation is analysed through the development of a life cycle costing financial assessment model that addresses relevant cost drivers.ResultsUsing discounting methods, the model can help practitioners generate scenarios to identify feasible solutions for profitable PaaS setups. Additionally, the paper presents an analytical procedure to identify conditions for a financially viable PaaS. The procedure includes scenario-based analysis that accounts for systemic changes often necessary for successfully realising PaaS.DiscussionBy following the proposed procedure, along with the financial assessment model, manufacturers can streamline their financial assessments to identify necessary changes. For the analysed case company, the modelling results indicate that it must redesign its products for PaaS to outperform its previous business model.

Abstract Three-dimensional (3D) metal halide perovskite solar cells (PSCs) have a power conversion efficiency that is now comparable with conventional silicon solar cells. For PSC applications to succeed in the market, long-term reliability under open-air conditions is essential. Recent experiments have shown that two-dimensional (2D) perovskites seem to exhibit good stability due to the presence of hydrophobic organic spacers, but 2D PSCs are incapable of generating and transporting a large amount of charge due to their extended optical bandgaps. Mixed dimensional perovskites with dimension lies between 2D and 3D recently became a promising candidate to sustain long-term stability and high performances concurrently to address this obstacle. The current research article presents the finding of simulation-based studies performed on novel device architecture consisting of ITO/Nb-Ti2O3/3D Perovskite/2D Perovskite/Spiro-OMeTAD/Au. Using optical simulation features of SCAPS, absorption of light is computed in the proposed device. The computational results show that the thickness of the 2D perovskite layer badly affects the solar cell parameters. A thin 2D perovskite behaves as a capped coating that avoids the deterioration of 3D perovskite in open-air environments. The effect of a multivalent defect in the 3D perovskite layer is mathematically modelled, and their impact on overall performance parameters are analyzed. The findings are compared to the same configuration results, except where the absorber layer’s multivalent defect has been substituted by a neutral defect of the same defect density of about (1011 cm−3). Results show that the multivalent defect leads to an underestimation of the efficiency by 4.2%.

Historical exploitation of the Mediterranean Sea and the absence of rigorous baselines makes it difficult to evaluate the current health of the marine ecosystems and the efficacy of conservation actions at the ecosystem level. Here we establish the first current baseline and gradient of ecosystem structure of nearshore rocky reefs at the Mediterranean scale. We conducted underwater surveys in 14 marine protected areas and 18 open access sites across the Mediterranean, and across a 31-fold range of fish biomass (from 3.8 to 118 g m(-2)). Our data showed remarkable variation in the structure of rocky reef ecosystems. Multivariate analysis showed three alternative community states: (1) large fish biomass and reefs dominated by non-canopy algae, (2) lower fish biomass but abundant native algal canopies and suspension feeders, and (3) low fish biomass and extensive barrens, with areas covered by turf algae. Our results suggest that the healthiest shallow rocky reef ecosystems in the Mediterranean have both large fish and algal biomass. Protection level and primary production were the only variables significantly correlated to community biomass structure. Fish biomass was significantly larger in well-enforced no-take marine reserves, but there were no significant differences between multi-use marine protected areas (which allow some fishing) and open access areas at the regional scale. The gradients reported here represent a trajectory of degradation that can be used to assess the health of any similar habitat in the Mediterranean, and to evaluate the efficacy of marine protected areas.

<p>Historical weather data represent an extremely precious resource for agro-meteorology for studying evolutionary dynamics and for predictive purposes, to address agronomical and management choices, that have economic, social and environmental effect. The study of climatic variability and its consequences starts from the observation of variations over time and the identification of the causes, on the basis of historical series of meteorological observations. The availability of long-lasting, complete and accurate datasets is a fundamental requirement to predict and react to climate variability. Inter-annual climate changes deeply affect grapevine productive cycle determining direct impact on the onset and duration of phenological stages and, ultimately, on the grape harvest and yield. Indeed, climate variables, such as air temperature and precipitation, affect evapotranspiration rates, plant water requirements, and also the vine physiology. In this respect, the observed increase in the number of warm days poses a threat to grape quality as it creates a situation of imbalance at maturity, with respect to sugar content, acidity and phenolic and aromatic ripeness.</p><p>A study was conducted to investigate the relationships between climate variables and harvest onset dates to assess the responses of grapevine under a global warming scenario. The study was carried out in the “Monferrato” area, a rainfed hillslope vine-growing area of NW Italy. In particular, the onset dates of harvest of different local wine grape varieties grown in the Vezzolano Experimental Farm (CNR-IMAMOTER) and in surrounding vineyards (affiliated to the Terre dei Santi Cellars) were recorded from 1962 to 2019 and then related to historical series of climate data by means of regression analysis. The linear regression was performed based on the averages of maximum and minimum daily temperatures and sum of precipitation (1962–2019) calculated for growing and ripening season, together with a bioclimatic heat index for vineyards, the Huglin index. The climate data were obtained from two data series collected in the Experimental farm by a mechanical weather station (1962-2002) and a second series recorded (2002-2019) by an electro-mechanical station included in Piedmont Regional Agro-meteorological Network. Finally, a third long-term continuous series covering the period from 1962 to 2019, provided by Italian Meteorological Society was considered in the analysis.</p><p>The results of the study highlighted that inter-annual climate variability, with a general positive trend of temperature, significantly affects the ripening of grapes with a progressive anticipation of the harvest onset dates. In particular, all the considered variables excepted precipitation, resulted negatively correlated with the harvest onset date reaching a high level of significance (up to P< 0.001). Best results have been obtained for maximum temperature and Huglin index, especially by using the most complete dataset. The change ratios obtained using datasets including last 15 years were greater (in absolute terms) than results limited to the period 1962-2002, and also correlations have greater level of significance. The results indicated clearly the relationships between the temperature trend and the gradual anticipation of harvest and the importance of having long and continuous historical weather data series available.</p>