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Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

Abstract— The odd nucleoside 4‐thiouridine, which is present in position 8 of 70% of E. coli tRNAs, possesses unusual spectroscopic properties which make it suitable for intramolecular energy transfer studies. Both its luminescence excitation spectrum and the action spectrum (230–380 nm) for the 8–13 link formation have been established in native E. coli tRNA at room temperature. The spectra are identical and present a new unexpected peak around 260 nm. At this wavelength, they are amplified by a factor of nine as compared with the absorption and excitation spectra of the free nucleoside in aqueous solution.The origin of this new peak is discussed and it is concluded that energy transfer does occur from the common nucleosides to the 4‐thiouridine residue. Using the values of the nucleosides to 4‐thiouridine distances inferred from the sets of atomic coordinates obtained on yeast tRNAphe crystals, a satisfactory account of our finding can be obtained assuming singlet‐singlet energy transfer. The efficiency of the mechanism is probably favoured by a good overlap between the emission spectra of the common nucleosides and the absorption spectrum of 4‐thiouridine.

Abstract— The odd nucleoside 4‐thiouridine, which is present in position 8 of 70% of E. coli tRNAs, possesses unusual spectroscopic properties which make it suitable for intramolecular energy transfer studies. Both its luminescence excitation spectrum and the action spectrum (230–380 nm) for the 8–13 link formation have been established in native E. coli tRNA at room temperature. The spectra are identical and present a new unexpected peak around 260 nm. At this wavelength, they are amplified by a factor of nine as compared with the absorption and excitation spectra of the free nucleoside in aqueous solution.The origin of this new peak is discussed and it is concluded that energy transfer does occur from the common nucleosides to the 4‐thiouridine residue. Using the values of the nucleosides to 4‐thiouridine distances inferred from the sets of atomic coordinates obtained on yeast tRNAphe crystals, a satisfactory account of our finding can be obtained assuming singlet‐singlet energy transfer. The efficiency of the mechanism is probably favoured by a good overlap between the emission spectra of the common nucleosides and the absorption spectrum of 4‐thiouridine.

Abstract An international workshop was held in Richland, Washington, United States of America, in October, 1980 to discuss progress on development of the acid digestion process for treating combustible nuclear waste. The workshop was attended by participants from nine member countries of the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The status of the acid digestion development programs of various countries is discussed in this paper. The acid digestion process has been developed and demonstrated on an engineering scale in several countries and appears to be especially applicable to treatment of combustible wastes containing high levels of transuranic contamination, where there is potential for recovering the transuranic radionuclides. Because the process takes place at a relatively low temperature, the plutonium contained in the residue is in a form that can be readily recovered using standard leaching techniques. The process is adaptable to a wide variety of combustible wastes, such as cellulosics, plastics, rubber materials, and ion exchange resin. While the process has been developed and demonstrated on an engineering scale primarily for transuranic contaminated wastes, the process is also adaptable to beta-gamma wastes such as reactor ion exchange resins.

Abstract An international workshop was held in Richland, Washington, United States of America, in October, 1980 to discuss progress on development of the acid digestion process for treating combustible nuclear waste. The workshop was attended by participants from nine member countries of the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The status of the acid digestion development programs of various countries is discussed in this paper. The acid digestion process has been developed and demonstrated on an engineering scale in several countries and appears to be especially applicable to treatment of combustible wastes containing high levels of transuranic contamination, where there is potential for recovering the transuranic radionuclides. Because the process takes place at a relatively low temperature, the plutonium contained in the residue is in a form that can be readily recovered using standard leaching techniques. The process is adaptable to a wide variety of combustible wastes, such as cellulosics, plastics, rubber materials, and ion exchange resin. While the process has been developed and demonstrated on an engineering scale primarily for transuranic contaminated wastes, the process is also adaptable to beta-gamma wastes such as reactor ion exchange resins.

Abstract This paper describes the point of view of a gas utility regarding systems for cooling and heating by solid sorption. Indeed, the context is favorable to the emergence of such systems first, of course, due to the regulatory constraints on certain refrigerant fluids, but also for their specific technical characteristics (the storage capacity, for example). The gas utilities have in fact shown an increasingly keen interest in all types of sorption systems, as a way of diversifying natural gas utilization, particularly in the summer. After a review of that context, this paper highlights the advantages of solid sorption and describes the criteria for choosing an installation in air conditioning and cooling production applications. Finally, it discusses the difficulties likely to be encountered in developing sorption systems, as well as the prospects for the future.

Abstract This paper describes the point of view of a gas utility regarding systems for cooling and heating by solid sorption. Indeed, the context is favorable to the emergence of such systems first, of course, due to the regulatory constraints on certain refrigerant fluids, but also for their specific technical characteristics (the storage capacity, for example). The gas utilities have in fact shown an increasingly keen interest in all types of sorption systems, as a way of diversifying natural gas utilization, particularly in the summer. After a review of that context, this paper highlights the advantages of solid sorption and describes the criteria for choosing an installation in air conditioning and cooling production applications. Finally, it discusses the difficulties likely to be encountered in developing sorption systems, as well as the prospects for the future.

Abstract This paper deals with an optimization of the Stirling engine regenerator’s. Firstly, different materials are experimented (Stainless Steel, Copper, aluminum and Monel 400). The engine performances and the state of each material after 15 h of use are considered. The Stainless steel was the material that best satisfies these two conditions. Five regenerators in stainless steel with different porosities were manufactured and experimented (95%, 90%, 85%, 80% and 75%). Porosity that gives the best trade-off between maximizing the engine brake power, maximizing the heat transfer and minimizing the pressure drops, was retained. Thus, the regenerator in stainless steel with porosity of 85% was considered as the most suitable matrix maximizing the Stirling engine performances and minimizing heat and friction losses.