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The optical properties of strongly doped semiconductor nanocrystals depend strongly on the carrier density of the nanocrystals. These characteristics can be exploited for the design of innovative optical devices based on ultrafast switching potentially in the THz modulation bandwidth. In this study, the optical response of one‐dimensional photonic crystals incorporating colloidal nanoparticles of a highly doped semiconductor such as indium tin oxide (ITO) is investigated, taking into consideration the angular dependence of the photonic band gap and the position dependence of the photonic band gap on the light‐induced tunability of the ITO doping.

Abstract Grid forming control of converter interfaced generation (CIG) requires some form of energy storage to be coupled with the generation. Energy storage systems (ESSs) can be coupled to the CIG either on the DC or the AC side of the power converter. When placed on the DC side, the ESS can provide damping of the variability in the generation but would require significant modification to the wind turbine hardware. The solution with an ESS connected to the AC side is simpler to implement with existing wind turbines but fails to provide damping of the CIG generation. This paper proposes a grid forming control strategy, based on virtual synchronous generator (VSG) control, which allows the ESS installed at the AC-side of the converter to have the same features and dynamic behaviour as those obtained from placement on the DC-side of the converter. In addition, the proposed control can also limit the exchanged power of the ESS within its rating for a safe operation. The proposed control is validated via a detailed Electro-Magnetic Transient (EMT) model and its impact on the grid is quantified via the case study of the All-Island Irish transmission system. Simulation results show that only a small ESS capacity can ensure that the frequency variance satisfies the grid code requirement even in the situation of a very high CIG penetration.

Abstract The feasibility of reusing waste materials as an inexpensive sorbent to remove volatile organic compounds from gaseous waste streams has been demonstrated. Ashes from wood-chips were tested as sorbent materials for VOCs removal with a PTR-ToF-MS instrument. Both scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) and BET analysis were used to identify the structural characteristics, elemental composition and surface area of the tested ashes respectively. Most of the tentatively identified compounds were less strongly adsorbed by wet ash: thiols, siloxanes, carbonyl compounds and terpenes. Hydrogen sulfide and alcohols show improving removal performance in wet conditions. These results are related to the water solubility properties. Siloxanes were tentatively identified and monitored with PTR-ToF-MS. This demonstrates how this instrument is a suitable tool for simultaneously providing a multitude of analysis for rapid in situ monitoring of fuel contaminants. Considering the low cost, and the recycling of environmental pollutants, wood ashes are a possible choice for VOCs removal from biogas.

Consider a situation where spatial heterogeneity leads to a cline, a gradual transition in dominance of two competing species. We first prove, in the context of a simplified competition–diffusion model, that there exists a stationary solution showing that the two species coexist in a transition zone. What happens then if, owing to climate change, the environmental profile moves with constant speed in space? We show here that, when the speed with which the environmental condition shifts exceeds the Fisher invasion speed of the advancing species, an expanding gap will form. We raise the question of whether such a phenomenon has been or can be observed.

Here we present unequivocal experimental proof that microscale cofactor- and membrane-less, direct electron transfer based enzymatic fuel cells do produce significant amounts of electrical energy in human lachrymal liquid (tears). 100 μm diameter gold wires, covered with 17 nm gold nanoparticles, were used to fashion three-dimensional nanostructured microelectrodes, which were biomodified with Corynascus thermophilus cellobiose dehydrogenase and Myrothecium verrucaria bilirubin oxidase as anodic and cathodic bioelements, respectively. The following characteristics of miniature glucose/oxygen biodevices operating in human tears were registered: 0.57 V open-circuit voltage, about 1 μW cm(-2) maximum power density at a cell voltage of 0.5 V, and more than 20 h operational half-life. Theoretical calculations regarding the maximum recoverable electrical energy can be extracted from the biofuel and the biooxidant, glucose and molecular oxygen, each readily available in human lachrymal liquid, fully support our belief that biofuel cells can be used as electrical power sources for so called smart contact lenses.

We studied thallium (Tl) isotope fractionation in white mustard grown hydroponically at different Tl doses. Thallium isotope signatures in plants indicated preferential incorporation of the light 203Tl isotope during Tl uptake from the nutrient solution. Negative isotope fractionation was even more pronounced in dependence on how much the available Tl pool decreased. This finding corresponds to the concept of isotope overprinting related to a high contamination level in the growing media (solution or soil). Regarding Tl translocation in plants, we observed a large Tl isotope shift with an enrichment in the heavy 205Tl isotope in the shoots relative to the roots in treatments with low/moderate solution Tl concentrations (0.01/0.05 mg Tl/L), with the corresponding α205/203Tl fractionation factors of ˜1.007 and 1.003, respectively. This finding is probably a consequence of specific (plant) reactions of Tl replacing K in its cycle. The formation of the S-coordinated Tl(I) complexes, potentially affecting both Tl accumulation and Tl isotope fractionation in plants, however, was not proven in our plants, since we did not have indication for that on the basis of X-ray absorption spectroscopy, suggesting that Tl was mainly present as free/hydrated Tl+ ion or chemically bound to O-containing functional groups.

Wireless Sensor Networks (WSN) are a key component of the Internet of Things (IoT) revolution. WSN nodes are in general battery-powered, thereby and efficient usage of their energy budget is of paramount importance to avoid performance degradation in IoT applications. To this end, this chapter proposes techniques to manage the WSN nodes’ power consumption. The aim of the first technique is to minimize the transmitted power for a given quality of service requirement at the receiver side. To this end, a power control is considered at each WSN node as well as the use of multiple distributed access points at the receiver side. The second technique to reduce the WSN energy consumption is energy harvesting (EH). Namely, the use of artificial light EH is considered to extend the WSN lifetime. Thus, an experimental setup based on a photovoltaic cell, a boost converter and a commercial WSN node is presented. It is shown that under certain settings it is possible to extend the WSN node’s lifetime without bound, when the transmission time period is above a certain threshold.