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A novel unified feature-scale model for inductive plasma etching is presented. The semi-empirical model simplifies simulations by considering only surface reactions and ignoring those in the reactor. The model gives an accurate description of passivation layers which form on sidewalls during etch processes, by treating them as independent materials. This allows them to be explicitly included in subsequent etch steps, resulting in a more accurate description of the physical process. Therefore, novel gate stack geometries for advanced nodes can be modelled more rigorously, enabling a better understanding of the complex chemical and physical processes taking place during the gate stack etching sequence. The model was applied in the analysis of a gate stack geometry for CMOS devices of a 14nm process and compared to experimental results, which are in good agreement.

Abstract Woody species' requirements and environmental sensitivity change from seedlings to adults, a process referred to as ontogenetic shift. Such shifts can be increased by climate change. To assess the changes in the difference of temperature experienced by seedlings and adults in the context of climate change, it is essential to have reliable climatic data over long periods that capture the thermal conditions experienced by the individuals throughout their life cycle. Here we used a unique cross‐European database of 2,195 pairs of resurveyed forest plots with a mean intercensus time interval of 37 years. We inferred macroclimatic temperature (free‐air conditions above tree canopies—representative of the conditions experienced by adult trees) and microclimatic temperature (representative of the juvenile stage at the forest floor, inferred from the relationship between canopy cover, distance to the coast and below‐canopy temperature) at both surveys. We then address the long‐term, large‐scale and multitaxa dynamics of the difference between the temperatures experienced by adults and juveniles of 25 temperate tree species. We found significant, but species‐specific, variations in the perceived temperature (calculated from presence/absence data) between life stages during both surveys. Additionally, the difference of the temperature experienced by the adult versus juveniles significantly increased between surveys for 8 of 25 species. We found evidence of a relationship between the difference of temperature experienced by juveniles and adults over time and one key functional trait (i.e. leaf area). Together, these results suggest that the temperatures experienced by adults versus juveniles became more decoupled over time for a subset of species, probably due to the combination of climate change and a recorded increase of canopy cover between the surveys resulting in higher rates of macroclimate than microclimate warming. Synthesis. We document warming and canopy‐cover induced changes in the difference of the temperature experienced by juveniles and adults. These findings have implications for forest management adaptation to climate change such as the promotion of tree regeneration by creating suitable species‐specific microclimatic conditions. Such adaptive management will help to mitigate the macroclimate change in the understorey layer.

AbstractGlobal impact models represent process-level understanding of how natural and human systems may be affected by climate change. Their projections are used in integrated assessments of climate change. Here we test, for the first time, systematically across many important systems, how well such impact models capture the impacts of extreme climate conditions. Using the 2003 European heat wave and drought as a historical analogue for comparable events in the future, we find that a majority of models underestimate the extremeness of impacts in important sectors such as agriculture, terrestrial ecosystems, and heat-related human mortality, while impacts on water resources and hydropower are overestimated in some river basins; and the spread across models is often large. This has important implications for economic assessments of climate change impacts that rely on these models. It also means that societal risks from future extreme events may be greater than previously thought.

Abstract Background:Eukaryotic organisms, like the model yeast S. cerevisiae, have linear chromosomes that facilitate organization and protection of nuclear DNA. A recent work described a stepwise break/repair method that enabled fusion of the sixteen chromosomes of S. cerevisiae into a single large chromosome. Construction of this strain resulted in the removal of 30 of 32 telomeres, over 300kb of subtelomeric DNA, and 107 subtelomeric ORFs. Despite these changes, characterization of the single chromosome strain uncovered modest phenotypes compared to a reference strain.Results:This study further characterized the single chromosome strain and found that it exhibited a longer lag phase, increased doubling time, and lower final biomass concentration compared with a reference strain when grown on YPD. These phenotypes were amplified when ethanol was added to the medium or used as the sole carbon source. RNAseq analysis showed poor induction of genes involved in diauxic shift, ethanol metabolism, and fatty-acid ß-oxidation during growth on ethanol compared to the reference strain. Enzyme-constrained metabolic modeling identified decreased flux through the enzymes that are encoded by these poorly induced genes as a likely cause of diminished biomass accumulation. The diminished growth on ethanol for the single chromosome strain was rescued by nicotinamide, an inhibitor of sirtuin family deacetylases, which have been shown to silence gene expression in heterochromatic regions. Conclusions:Our results indicate that sirtuin-mediated silencing in the single chromosome strain interferes with growth on non-fermentable carbon sources. We propose that the removal of subtelomeric DNA that would otherwise be bound by sirtuins leads to silencing at other loci in the single chromosome strain. Further, we hypothesize that the poorly induced genes in the single chromosome strain during ethanol growth could be silenced by sirtuins in wildtype S. cerevisiae during growth on glucose.

The development of industrial infrastructure in the Beijing–Tianjin–Hebei(BTH) region has been accompanied by a disorderly expansion of industrial zones and other inappropriate development. Accurate industrial heat source classification data become important to evaluate the policies of industrial restructuring and air quality improvement. In this study, a new classification of industrial heat source objects model based on active fire point density segmentation and spatial topological correlation analysis in the BTH Region was proposed. First, industrial heat source objects were detected with an active fire point density segmentation method using NPP-VIIRS active fire/hotspot data. Then, industrial heat source objects were classified into five categories based on a spatial topological correlation analysis method using POI data. Then, identification and classification results were manually validated based on Google Earth imagery. Finally, we evaluated the factors influencing the number of industrial heat sources based on an OLS regression model. A total of 493 industrial heat source objects were identified in this study with an identification accuracy of 96.14%(474/493). Compared with results for nighttime fires, the number of industrial heat source objects that were identified was higher, and the spatial coverage was greater; the minimum size of the detected objects was also smaller. Based on the function of the identified industrial heat source objects, the objects in the BTH region were then divided into five categories: cement plants (21.73%), steel plants (53.80%), coal and chemical industry (12.66%), oil and gas developments (7.81%), and other (4.01%). An analysis of their operations showed that the number of industrial heat source objects in operation in the BTH region tended to first rise and then decline during the 2012–2021 period, with the peak being reached in 2013. The results of this study will aid the rationalization of industrial infrastructure in the BTH region and, by extension, in China as a whole.